Xianhui Bu
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View article: Isoreticular Tolerance and Phase Selection in the Synthesis of Multi‐Module Metal–Organic Frameworks for Gas Separation and Electrocatalytic OER
Isoreticular Tolerance and Phase Selection in the Synthesis of Multi‐Module Metal–Organic Frameworks for Gas Separation and Electrocatalytic OER Open
Although metal–organic frameworks are coordination‐driven assemblies, the structural prediction and design using metal‐ligand interactions can be unreliable due to other competing interactions. Leveraging non‐coordination interactions to d…
View article: Isoreticular Tolerance and Phase Selection in the Synthesis of Multi‐Module Metal–Organic Frameworks for Gas Separation and Electrocatalytic OER
Isoreticular Tolerance and Phase Selection in the Synthesis of Multi‐Module Metal–Organic Frameworks for Gas Separation and Electrocatalytic OER Open
Although metal–organic frameworks are coordination‐driven assemblies, the structural prediction and design using metal‐ligand interactions can be unreliable due to other competing interactions. Leveraging non‐coordination interactions to d…
View article: Multi‐Stage Optimization of Pore Size and Shape in Pore‐Space‐Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture
Multi‐Stage Optimization of Pore Size and Shape in Pore‐Space‐Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture Open
Compared to exploratory development of new structure types, pushing the limits of isoreticular synthesis on a high‐performance MOF platform may have higher probability of achieving targeted properties. Multi‐modular MOF platforms could off…
View article: Multi‐Stage Optimization of Pore Size and Shape in Pore‐Space‐Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture
Multi‐Stage Optimization of Pore Size and Shape in Pore‐Space‐Partitioned Metal–Organic Frameworks for Highly Selective and Sensitive Benzene Capture Open
Compared to exploratory development of new structure types, pushing the limits of isoreticular synthesis on a high‐performance MOF platform may have higher probability of achieving targeted properties. Multi‐modular MOF platforms could off…
View article: Ultrastable Carboxyl‐Functionalized Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation
Ultrastable Carboxyl‐Functionalized Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation Open
Isoreticular chemistry, which enables property optimization by changing compositions without changing topology, is a powerful synthetic strategy. One of the biggest challenges facing isoreticular chemistry is to extend it to ligands with s…
View article: Advancing Pore‐Space‐Partitioned Metal–Organic Frameworks with Isoreticular Cluster Concept
Advancing Pore‐Space‐Partitioned Metal–Organic Frameworks with Isoreticular Cluster Concept Open
Trigonal planar M 3 (O/OH) trimers are among the most important clusters in inorganic chemistry and are the foundational features of multiple high‐impact MOF platforms. Here we introduce a concept called isoreticular cluster series and dem…
View article: Tailorable Multi‐Modular Pore‐Space‐Partitioned Vanadium Metal‐Organic Frameworks for Gas Separation
Tailorable Multi‐Modular Pore‐Space‐Partitioned Vanadium Metal‐Organic Frameworks for Gas Separation Open
Currently, few porous vanadium metal‐organic frameworks (V‐MOFs) are known and even fewer are obtainable as single crystals, resulting in limited information on their structures and properties. Here this work demonstrates remarkable promis…
View article: Metal–organic frameworks with two different-sized aromatic ring-confined nanotraps for benchmark natural gas upgrade
Metal–organic frameworks with two different-sized aromatic ring-confined nanotraps for benchmark natural gas upgrade Open
Aromatic ring-confined bi-nanotraps, along with the coupled thermodynamic-molecular sieving effects in metal–organic framework adsorbents, give rise to benchmark performance in the separation process for natural gas upgrade.
View article: CCDC 2172343: Experimental Crystal Structure Determination
CCDC 2172343: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172341: Experimental Crystal Structure Determination
CCDC 2172341: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172342: Experimental Crystal Structure Determination
CCDC 2172342: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Multilevel-Regulated Metal–Organic Framework Platform Integrating Pore Space Partition and Open-Metal Sites for Enhanced CO<sub>2</sub> Photoreduction to CO with Nearly 100% Selectivity
Multilevel-Regulated Metal–Organic Framework Platform Integrating Pore Space Partition and Open-Metal Sites for Enhanced CO<sub>2</sub> Photoreduction to CO with Nearly 100% Selectivity Open
Rational design and regulation of atomically precise photocatalysts are essential for constructing efficient photocatalytic systems tunable at both the atomic and molecular levels. Herein, we propose a platform-based strategy capable of in…
View article: Cyclobutanedicarboxylate Metal–Organic Frameworks as a Platform for Dramatic Amplification of Pore Partition Effect
Cyclobutanedicarboxylate Metal–Organic Frameworks as a Platform for Dramatic Amplification of Pore Partition Effect Open
Ultrafine tuning of MOF structures at subangstrom or picometer levels can help improve separation selectivity for gases with subtle differences. However, for MOFs with a large enough pore size, the effect from ultrafine tuning on sorption …
View article: Multi‐Modular Design of Stable Pore‐Space‐Partitioned Metal–Organic Frameworks for Gas Separation Applications
Multi‐Modular Design of Stable Pore‐Space‐Partitioned Metal–Organic Frameworks for Gas Separation Applications Open
Pore space partition (PSP) is an effective materials design method for developing high‐performance small‐pore materials for storage and separation of gas molecules. The continued success of PSP depends on broad availability and judicious c…
View article: CCDC 2192230: Experimental Crystal Structure Determination
CCDC 2192230: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2210354: Experimental Crystal Structure Determination
CCDC 2210354: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2210327: Experimental Crystal Structure Determination
CCDC 2210327: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2192229: Experimental Crystal Structure Determination
CCDC 2192229: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2255573: Experimental Crystal Structure Determination
CCDC 2255573: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2209904: Experimental Crystal Structure Determination
CCDC 2209904: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2257299: Experimental Crystal Structure Determination
CCDC 2257299: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Simultaneous Control of Flexibility and Rigidity in Pore-Space-Partitioned Metal–Organic Frameworks
Simultaneous Control of Flexibility and Rigidity in Pore-Space-Partitioned Metal–Organic Frameworks Open
Flexi-MOFs are typically limited to low-connected (<9) frameworks. Here we report a platform-wide approach capable of creating a family of high-connected materials (collectively called CPM-220) that integrate exceptional framework flexibil…
View article: Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation
Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation Open
Multi‐module design of framework materials with multiple distinct building blocks has attracted much attention because such materials are more amenable to compositional and geometrical tuning and thus offer more opportunities for property …
View article: Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation
Solvent‐free Synthesis of Multi‐Module Pore‐Space‐Partitioned Metal‐Organic Frameworks for Gas Separation Open
Multi‐module design of framework materials with multiple distinct building blocks has attracted much attention because such materials are more amenable to compositional and geometrical tuning and thus offer more opportunities for property …
View article: CCDC 2192231: Experimental Crystal Structure Determination
CCDC 2192231: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Concurrent Enhancement of Acetylene Uptake Capacity and Selectivity by Progressive Core Expansion and Extra‐Framework Anions in Pore‐Space‐Partitioned Metal–Organic Frameworks
Concurrent Enhancement of Acetylene Uptake Capacity and Selectivity by Progressive Core Expansion and Extra‐Framework Anions in Pore‐Space‐Partitioned Metal–Organic Frameworks Open
A multi‐stage core‐expansion method is proposed here as one component of the integrative binding‐site/extender/core‐expansion ( BEC ) strategy. The conceptual deconstruction of the partitioning ligand into three editable parts draws our fo…
View article: Developing Water‐Stable Pore‐Partitioned Metal‐Organic Frameworks with Multi‐Level Symmetry for High‐Performance Sorption Applications
Developing Water‐Stable Pore‐Partitioned Metal‐Organic Frameworks with Multi‐Level Symmetry for High‐Performance Sorption Applications Open
A new perspective is proposed in the design of pore‐space‐partitioned MOFs that is focused on ligand symmetry properties sub‐divided here into three hierarchical levels: 1) overall ligand, 2) ligand substructure such as backbone or core, a…
View article: CCDC 2219634: Experimental Crystal Structure Determination
CCDC 2219634: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159094: Experimental Crystal Structure Determination
CCDC 2159094: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2159092: Experimental Crystal Structure Determination
CCDC 2159092: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …