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View article: Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups
Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups Open
A synthetic route to the bench-stable fluorinated masked carbene reagent diethyl 2-diazo-1,1,3,3,3-pentafluoropropylphosphonate, bearing a trifluoromethyl and a difluoromethyl group is reported for the first time. Its application in CuI-ca…