Jean‐Charles Buffet
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View article: Exploring the Nuclearity and Structural Motifs of Phenoxyimine Alkaline Earth Complexes
Exploring the Nuclearity and Structural Motifs of Phenoxyimine Alkaline Earth Complexes Open
The nuclearity and structural motifs of alkaline earth complexes supported by bidentate phenoxyimine ligands has been explored by modulation of the stereoelectronic profile of the ligand, the atomic number of the metal, and the synthetic p…
View article: Synthesis, characterisation, and magnetic properties of a permethylindenyl manganocene
Synthesis, characterisation, and magnetic properties of a permethylindenyl manganocene Open
The heptamethylindenyl ligand (C 9 Me 7 ; Ind*) has been used to synthesise manganese complex, (η 5 -Ind*) 2 Mn, by lithiation of the proligand and subsequent salt metathesis with MnCl 2 . The solid state Mn 2+ centre is low-spin and under…
View article: Trends in Structure and Ethylene Polymerization Reactivity of Transition-Metal Permethylindenyl-phenoxy (PHENI*) Complexes
Trends in Structure and Ethylene Polymerization Reactivity of Transition-Metal Permethylindenyl-phenoxy (PHENI*) Complexes Open
A family of ansa-permethylindenyl-phenoxy (PHENI*) transition-metal chloride complexes has been synthesized and characterized (1-7; {(η5-C9Me6)Me(R″)Si(2-R-4-R'-C6H2O)}MCl2; R,R' = Me, tBu, Cumyl (CMe2Ph); R″ = Me, nPr, Ph; M = Ti, Zr, Hf)…
View article: Bis(phenoxy-imine) Alkaline–Earth Complexes with Competing Binding Pockets
Bis(phenoxy-imine) Alkaline–Earth Complexes with Competing Binding Pockets Open
The synthesis and characterization of both monometallic and bimetallic alkaline–earth metal complexes supported by the phenoxy-imine ligand [2,7-(HC═NDipp)-1,8–O–C10H4 where Dipp = 2,6-iPr–C6H3]2– (DippL) have been reported. Though the lig…
View article: A restatement of the natural science evidence base concerning grassland management, grazing livestock and soil carbon storage
A restatement of the natural science evidence base concerning grassland management, grazing livestock and soil carbon storage Open
Approximately a third of all annual greenhouse gas emissions globally are directly or indirectly associated with the food system, and over a half of these are linked to livestock production. In temperate oceanic regions, such as the UK, mo…
View article: Phenoxy imine NOON complexes of heavy alkaline earth ions for the ring-opening polymerisation of cyclic esters
Phenoxy imine NOON complexes of heavy alkaline earth ions for the ring-opening polymerisation of cyclic esters Open
The polymerisation of lactide monomers by heavier alkaline earth complexes supported by a phenoxy-imine NOON ligand, Dipp LM(thf) x ( Dipp L = ([2,7-(CNDipp)-1,8-O-C 10 H 4 ] 2− where Dipp = 2,6- i Pr-C 6 H 3 ; M = Ca (1), Sr (2) and Ba (…
View article: Optimising the acid–base ratio of Mg–Al layered double oxides to enhance CO<sub>2</sub> capture performance: the critical role of calcination conditions
Optimising the acid–base ratio of Mg–Al layered double oxides to enhance CO<sub>2</sub> capture performance: the critical role of calcination conditions Open
We investigated the impact of calcination conditions of layered double hydroxide on the formation of layered double oxides and its relationship with CO 2 capture.
Towards designer polyolefins: highly tuneable olefin copolymerisation using a single permethylindenyl post-metallocene catalyst Open
Using a highly active permethylindenyl-phenoxy (PHENI*) titanium catalyst, high to ultra-high molecular weight ethylene–linear-α-olefin copolymers are prepared in high yields, with exceptional comonomer affinity, and predictable, tuneable …
Flame retardant phosphonate-functionalised polyethylenes Open
Non-halogenated “all-in-one” flame retardant HDPE.
Fully tuneable ethylene–propylene elastomers using a supported permethylindenyl-phenoxy (PHENI*) catalyst Open
Using a highly active supported permethylindenyl-phenoxy (PHENI*) titanium catalyst, high molecular weight ethylene–propylene (EPM) and and ethylene–propylene–diene (EPDM) elastomers are prepared with tuneable compositions using slurry-pha…
CCDC 2157739: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2157740: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2157742: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
Zirconium Permethylpentalene Amidinate Complexes: Characterization, Bonding, and Olefin Polymerization Catalysis Open
The synthesis and characterization of new zirconium permethylpentalene (form)amidinate complexes are described: Pn*Zr{N(Dipp)2CH}Cl (1), Pn* = η8-C8Me6 and Dipp = 2,6-iPr-C6H3; [Pn*Zr{N(p-tol)2CH}Cl]2 (2), p-tol = 4-Me-C6H4; [Pn*Zr{N(iPr)2…
CCDC 2157741: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2157736: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2157738: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2157737: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2164609: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2164612: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2164611: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2164608: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2164610: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
Multimetallic Permethylpentalene Hydride Complexes Open
The synthesis and characterization of group 4 permethylpentalene (Pn* = C8Me6) hydride complexes are explored; in all cases, multimetallic hydride clusters were obtained. Group 4 lithium metal hydride clusters were obtained when reacting t…
View article: A restatement of the natural science evidence base regarding the source, spread and control of <i>Campylobacter</i> species causing human disease
A restatement of the natural science evidence base regarding the source, spread and control of <i>Campylobacter</i> species causing human disease Open
Food poisoning caused by Campylobacter (campylobacteriosis) is the most prevalent bacterial disease associated with the consumption of poultry, beef, lamb and pork meat and unpasteurized dairy products. A variety of livestock industry, foo…
Tuning Polyethylene Molecular Weight Distributions Using Catalyst Support Composition Open
Bimodal polyethylene is generated from a single immobilized catalyst on a single support under a single set of reaction conditions without introducing chain transfer agents. Using rac-ethylenebis(1-indenyl)zirconium dichloride [(EBI)ZrCl2]…