James D. Crowley
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View article: The Potential of Ruthenium(II) Tris‐Bidentate Complexes as Multifunctional Photo‐Initiators
The Potential of Ruthenium(II) Tris‐Bidentate Complexes as Multifunctional Photo‐Initiators Open
An optically active antibacterial ruthenium(II) phenanthroline complex (tris(3,4,7,8‐tetramethyl‐1,10‐phenanthroline) ruthenium(II) dichloride), is investigated for its potential as a multifunctional photo‐initiator. Antibacterial and cyto…
View article: Single‐Step Synthesis of a Heterometallic [Cu<sub>2</sub>PdL<sub>4</sub>]<sup>2+</sup> Hybrid Metal–Organic Coordination Cage
Single‐Step Synthesis of a Heterometallic [Cu<sub>2</sub>PdL<sub>4</sub>]<sup>2+</sup> Hybrid Metal–Organic Coordination Cage Open
Traditional methods of assembling low‐symmetry heterometallic cage architectures are limited to stepwise construction and combinations of inert and labile metal ions, affording complex, anisotropic cage structures by sacrificing synthetic …
View article: Single‐Step Synthesis of a Heterometallic [Cu<sub>2</sub>PdL<sub>4</sub>]<sup>2+</sup> Hybrid Metal–Organic Coordination Cage
Single‐Step Synthesis of a Heterometallic [Cu<sub>2</sub>PdL<sub>4</sub>]<sup>2+</sup> Hybrid Metal–Organic Coordination Cage Open
Traditional methods of assembling low‐symmetry heterometallic cage architectures are limited to stepwise construction and combinations of inert and labile metal ions, affording complex, anisotropic cage structures by sacrificing synthetic …
View article: Single-step synthesis of a heterometallic [Cu2PdL4]2+ hybrid metal-organic coordination cage
Single-step synthesis of a heterometallic [Cu2PdL4]2+ hybrid metal-organic coordination cage Open
Traditional methods of assembling low-symmetry heterometallic cage architectures are limited to stepwise construction and combinations of inert and labile metal ions, affording complex, anisotropic cage structures by sacrificing synthetic …
View article: Pd(μ-L)<sub>4</sub>Pt <i>vs.</i> Pd(μ-L)<sub>4</sub>RuCl<sub>2</sub>: chlorido ancillary ligands as defining factors in the host–guest interactions of M(μ-L)<sub>4</sub>M′ heterodimetallic supramolecular architectures
Pd(μ-L)<sub>4</sub>Pt <i>vs.</i> Pd(μ-L)<sub>4</sub>RuCl<sub>2</sub>: chlorido ancillary ligands as defining factors in the host–guest interactions of M(μ-L)<sub>4</sub>M′ heterodimetallic supramolecular architectures Open
Host–guest interactions in heterodimetallic Pd(μ-L) 4 M (M = Pt, RuCl 2 ) architectures can be tuned through introduction of chlorido ligands in Pd(μ-L) 4 RuCl 2 hosts.
View article: Traumatic Complete Separation of the Anconeal Process in a 1-year-old French Bulldog with an Ununited Anconeal Process
Traumatic Complete Separation of the Anconeal Process in a 1-year-old French Bulldog with an Ununited Anconeal Process Open
A 1-year-old 13.5 kg male neutered French bulldog presented for acute left thoracic limb non-weight-bearing lameness following minor trauma. Orthopaedic examination revealed left elbow joint effusion and discomfort on elbow manipulation, p…
View article: Photochemistry of Ru(II) Triazole Complexes with 6-Membered Chelate Ligands: Detection and Reactivity of Ligand-Loss Intermediates
Photochemistry of Ru(II) Triazole Complexes with 6-Membered Chelate Ligands: Detection and Reactivity of Ligand-Loss Intermediates Open
Photochemical ligand release from metal complexes may be exploited in the development of novel photoactivated chemotherapy agents for the treatment of cancer and other diseases. Highly intriguing photochemical behavior is reported for two …
View article: Controlling Excited State Localization in Bichromophoric Photosensitizers via the Bridging Group
Controlling Excited State Localization in Bichromophoric Photosensitizers via the Bridging Group Open
A series of photosensitizers comprised of both an inorganic and an organic chromophore are investigated in a joint synthetic, spectroscopic, and theoretical study. This bichromophoric design strategy provides a means by which to significan…
View article: CCDC 2111157: Experimental Crystal Structure Determination
CCDC 2111157: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2111156: Experimental Crystal Structure Determination
CCDC 2111156: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2111155: Experimental Crystal Structure Determination
CCDC 2111155: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175044: Experimental Crystal Structure Determination
CCDC 2175044: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175042: Experimental Crystal Structure Determination
CCDC 2175042: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175043: Experimental Crystal Structure Determination
CCDC 2175043: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175045: Experimental Crystal Structure Determination
CCDC 2175045: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2175046: Experimental Crystal Structure Determination
CCDC 2175046: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Frontispiece: The Biologically Inspired Abilities of Metallosupramolecular Architectures
Frontispiece: The Biologically Inspired Abilities of Metallosupramolecular Architectures Open
This article highlights recent efforts to mimic biological systems and functions using metallosupramolecular architectures. Read more in the Review by A. C. Pearcy and J. D. Crowley (10.1002/chem.202203752).
View article: CCDC 2190168: Experimental Crystal Structure Determination
CCDC 2190168: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190169: Experimental Crystal Structure Determination
CCDC 2190169: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: The Biologically Inspired Abilities of Metallosupramolecular Architectures
The Biologically Inspired Abilities of Metallosupramolecular Architectures Open
Natural machinery such as proteins and enzymes can bind substrates and perform intricate functions on these molecules. This behaviour is mediated by highly ordered but conformationally flexible structures dictated through favourable intra‐…
View article: Exploiting reduced-symmetry ligands with pyridyl and imidazole donors to construct a second-generation stimuli-responsive heterobimetallic [PdPtL<sub>4</sub>]<sup>4+</sup> cage
Exploiting reduced-symmetry ligands with pyridyl and imidazole donors to construct a second-generation stimuli-responsive heterobimetallic [PdPtL<sub>4</sub>]<sup>4+</sup> cage Open
A new method for the assembly of a heterobimetallic [PdPtL 4 ] 4+ cage which can interact with anionic guest molecules in a specific, selective host–guest orientation is described.
View article: CCDC 2064764: Experimental Crystal Structure Determination
CCDC 2064764: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2064761: Experimental Crystal Structure Determination
CCDC 2064761: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1913711: Experimental Crystal Structure Determination
CCDC 1913711: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1913710: Experimental Crystal Structure Determination
CCDC 1913710: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Exploiting Supramolecular Interactions to Control Isomer Distributions in Reduced-Symmetry [Pd<sub>2</sub>L<sub>4</sub>]<sup>4+</sup> Cages
Exploiting Supramolecular Interactions to Control Isomer Distributions in Reduced-Symmetry [Pd<sub>2</sub>L<sub>4</sub>]<sup>4+</sup> Cages Open
High-symmetry metallosupramolecular architectures (MSAs) have been exploited for a range of applications including molecular recognition, catalysis, and drug delivery. Recently, there have been increasing efforts to enhance those applicati…
View article: CCDC 2129018: Experimental Crystal Structure Determination
CCDC 2129018: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Heterotrimetallic Double Cavity Cages: Syntheses and Selective Guest Binding
Heterotrimetallic Double Cavity Cages: Syntheses and Selective Guest Binding Open
A strategy for the generation of heterotrimetallic double cavity (DC) cages [Pd n Pt m L 4 ] 6+ ( DC1 : n =1, m =2; and DC2 : n =2, m =1) is reported. The DC cages were generated by combining an inert platinum(II) tetrapyridylaldehyde comp…
View article: Heterotrimetallic Double Cavity Cages: Syntheses and Selective Guest Binding
Heterotrimetallic Double Cavity Cages: Syntheses and Selective Guest Binding Open
A strategy for the generation of heterotrimetallic double cavity (DC) cages [Pd n Pt m L 4 ] 6+ ( DC1 : n =1, m =2; and DC2 : n =2, m =1) is reported. The DC cages were generated by combining an inert platinum(II) tetrapyridylaldehyde comp…
View article: CCDC 2065119: Experimental Crystal Structure Determination
CCDC 2065119: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …