En‐Qing Gao
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View article: Integrating Photoredox and Anion‐Binding Capabilities into a Metal–Organic Cage for Iodine Speciation and Sequestration
Integrating Photoredox and Anion‐Binding Capabilities into a Metal–Organic Cage for Iodine Speciation and Sequestration Open
The management of iodine species, notorious for their environmental persistence and health risks, requires innovative materials capable of efficient capture and conversion. Herein, we report the self‐assembly and characterization of a Zr‐b…
View article: A Hexadecacationic Metal–Organic Cage for Anchoring Sulfonates: High‐Order Binding of Di‐ and Trisulfonates and High‐Performance Removal of Perfluorosulfonates from Water
A Hexadecacationic Metal–Organic Cage for Anchoring Sulfonates: High‐Order Binding of Di‐ and Trisulfonates and High‐Performance Removal of Perfluorosulfonates from Water Open
Developing synthetic hosts capable of binding sulfonate anions or sequestering perfluorosulfonates is highly important. In this work, the self‐assembly of a tripyridinium‐tricarboxylate ligand with Cp 2 ZrCl 2 (Cp = η 5 ‐C 5 H 5 ) is repor…
View article: Engineering Cavity and Aperture Binding Sites Within a Metal–Organic Cage for Up‐ and Down‐Regulation of Catalysis
Engineering Cavity and Aperture Binding Sites Within a Metal–Organic Cage for Up‐ and Down‐Regulation of Catalysis Open
Engineering molecular recognition events into catalytic systems to precisely control the up‐ or down‐regulation of catalysis in a biomimetic fashion is a challenging goal in supramolecular chemistry. In this work, we report on the construc…
View article: External Large Foundation Model: How to Efficiently Serve Trillions of Parameters for Online Ads Recommendation
External Large Foundation Model: How to Efficiently Serve Trillions of Parameters for Online Ads Recommendation Open
Ads recommendation is a prominent service of online advertising systems and has been actively studied. Recent studies indicate that scaling-up and advanced design of the recommendation model can bring significant performance improvement. H…
View article: Chiral Pt(II)–V(V) Bimetallic Cages and Guest-Induced Allosteric Regulation of Catalytic Asymmetric Sulfoxidation
Chiral Pt(II)–V(V) Bimetallic Cages and Guest-Induced Allosteric Regulation of Catalytic Asymmetric Sulfoxidation Open
Flexible metal-organic cages can provide confined active metal sites and show promise in mimicking metalloenzymes. In this study, we synthesized two flexible chiral bimetallic coordination cages, [(PEt3)6Pt3(R,R,R-VL)2]6+ and its enantiome…
View article: Charge-transfer complexation of coordination cages for enhanced photochromism and photocatalysis
Charge-transfer complexation of coordination cages for enhanced photochromism and photocatalysis Open
Intensified host-guest electronic interplay within stable metal-organic cages (MOCs) presents great opportunities for applications in stimuli response and photocatalysis. Zr-MOCs represent a type of robust discrete hosts for such a design,…
View article: A Redox‐Active Phenothiazine‐based Pd<sub>2</sub>L<sub>4</sub>‐Type Coordination Cage and Its Isolable Crystalline Polyradical Cations
A Redox‐Active Phenothiazine‐based Pd<sub>2</sub>L<sub>4</sub>‐Type Coordination Cage and Its Isolable Crystalline Polyradical Cations Open
Polyradical cages are of great interest because they show very fascinating physical and chemical properties, but many challenges remain, especially for their synthesis and characterization. Herein, we present the synthesis of a polyradical…
View article: Coordination cages integrated into swelling poly(ionic liquid)s for guest encapsulation and separation
Coordination cages integrated into swelling poly(ionic liquid)s for guest encapsulation and separation Open
Coordination cages have been widely reported to bind a variety of guests, which are useful for chemical separation. Although the use of cages in the solid state benefits the recycling, the flexibility, dynamicity, and metal-ligand bond rev…
View article: Cobalt phthalocyanine-based conjugated polymer as efficient and exclusive electrocatalyst for CO2 reduction to ethanol
Cobalt phthalocyanine-based conjugated polymer as efficient and exclusive electrocatalyst for CO2 reduction to ethanol Open
Electrocatalytic conversion of carbon dioxide to high value-added chemicals is a promising method for solving the energy crisis and global warming. Electrochemical active metal-containing conjugated polymers have been widely studied for he…
View article: CCDC 2190475: Experimental Crystal Structure Determination
CCDC 2190475: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1965706: Experimental Crystal Structure Determination
CCDC 1965706: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1965707: Experimental Crystal Structure Determination
CCDC 1965707: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1965705: Experimental Crystal Structure Determination
CCDC 1965705: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1951814: Experimental Crystal Structure Determination
CCDC 1951814: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1951813: Experimental Crystal Structure Determination
CCDC 1951813: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1951815: Experimental Crystal Structure Determination
CCDC 1951815: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1951816: Experimental Crystal Structure Determination
CCDC 1951816: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2023250: Experimental Crystal Structure Determination
CCDC 2023250: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …