Jacob S. DeHovitz
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View article: Photobiocatalytic Strategies for Organic Synthesis
Photobiocatalytic Strategies for Organic Synthesis Open
Biocatalysis has revolutionized chemical synthesis, providing sustainable methods for preparing various organic molecules. In enzyme-mediated organic synthesis, most reactions involve molecules operating from their ground states. Over the …
View article: Quaternary Charge-Transfer Complex Enables Photoenzymatic Intermolecular Hydroalkylation of Olefins
Quaternary Charge-Transfer Complex Enables Photoenzymatic Intermolecular Hydroalkylation of Olefins Open
Intermolecular C-C bond-forming reactions are underdeveloped transformations in the field of biocatalysis. Here we report a photoenzymatic intermolecular hydroalkylation of olefins catalyzed by flavin-dependent 'ene'-reductases. Radical in…
View article: CCDC 2005322: Experimental Crystal Structure Determination
CCDC 2005322: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Static to inducibly dynamic stereocontrol: The convergent use of racemic β-substituted ketones
Static to inducibly dynamic stereocontrol: The convergent use of racemic β-substituted ketones Open
Expanding the kinetic resolution purview Dynamic kinetic resolution (DKR) is a powerful method to transform a pair of mirror-image reactants into just one of the two possible mirror-image products. The key is to find a means of rapidly int…