James D. Watson
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View article: A Dinitrogen Complex without Donor Ligands: Isolation and Characterization of a [Mn(CO)<sub>5</sub>(η<sup>1</sup>-N<sub>2</sub>)]<sup>+</sup> Salt
A Dinitrogen Complex without Donor Ligands: Isolation and Characterization of a [Mn(CO)<sub>5</sub>(η<sup>1</sup>-N<sub>2</sub>)]<sup>+</sup> Salt Open
Dinitrogen complexes are intermediates in nitrogen fixation. Until now, all isolated molecular dinitrogen complexes have relied on ancillary ligands that are net electron donors, yielding N2 ligands carrying a clear negative par…
View article: Promoting Alkane Binding: Crystallization of a Cationic Manganese(I)‐Pentane <i>σ</i>‐Complex from Solution
Promoting Alkane Binding: Crystallization of a Cationic Manganese(I)‐Pentane <i>σ</i>‐Complex from Solution Open
Transition metal–alkane σ ‐complexes are key intermediates in C–H activation and, until now, analysis of these species has been restricted to either the solution OR the solid state. Here we present a synthetic methodology that converts Mn …
View article: Bevorzugte Alkan‐Komplexierung: Kristallisation eines kationischen Mangan(I)‐Pentan <i>σ</i>‐Komplexes aus der Lösung
Bevorzugte Alkan‐Komplexierung: Kristallisation eines kationischen Mangan(I)‐Pentan <i>σ</i>‐Komplexes aus der Lösung Open
Zusammenfassung Übergangsmetall–Alkan σ ‐Komplexe sind wichtige Intermediate der C–H Aktivierung. Bis jetzt beschränkten sich die Untersuchungen der Komplexe in kondensierter Phase entweder auf den Festkörper oder die Lösung. In diesem Art…
View article: Coordination of ethane, pentane and cyclopentane to a cationic osmium complex: comparisons in alkane binding
Coordination of ethane, pentane and cyclopentane to a cationic osmium complex: comparisons in alkane binding Open
NMR and DFT investigations into osmium-alkane σ-complexes of pentane, cyclopentane and ethane. The cyclopentane and n -pentane complexes are amongst the most stable alkane σ-complexes characterized to date.
View article: A Systematic Evaluation of Automated Mycobacterium Tuberculosis Complex Whole Genome Sequencing Analysis Pipelines
A Systematic Evaluation of Automated Mycobacterium Tuberculosis Complex Whole Genome Sequencing Analysis Pipelines Open
View article: Supplementary Table 1 from Bioactivation of Napabucasin Triggers Reactive Oxygen Species–Mediated Cancer Cell Death
Supplementary Table 1 from Bioactivation of Napabucasin Triggers Reactive Oxygen Species–Mediated Cancer Cell Death Open
Table listing the differentially expressed genes between napabucasin treated cells compared to DMSO as vehicle control
View article: Supplementary Figures 1-7 from Bioactivation of Napabucasin Triggers Reactive Oxygen Species–Mediated Cancer Cell Death
Supplementary Figures 1-7 from Bioactivation of Napabucasin Triggers Reactive Oxygen Species–Mediated Cancer Cell Death Open
Supplementary Figures 1,2,3,4,5,6,7
View article: Efficient learning of ground & thermal states within phases of matter
Efficient learning of ground & thermal states within phases of matter Open
We consider two related tasks: (a) estimating a parameterisation of a given Gibbs state and expectation values of Lipschitz observables on this state; and (b) learning the expectation values of local observables within a thermal or quantum…
View article: [Fp(CH<sub>4</sub>)]<sup>+</sup>, [η<sup>5</sup>-CpRu(CO)<sub>2</sub>(CH<sub>4</sub>)]<sup>+</sup>, and [η<sup>5</sup>-CpOs(CO)<sub>2</sub>(CH<sub>4</sub>)]<sup>+</sup>: A Complete Set of Group 8 Metal–Methane Complexes
[Fp(CH<sub>4</sub>)]<sup>+</sup>, [η<sup>5</sup>-CpRu(CO)<sub>2</sub>(CH<sub>4</sub>)]<sup>+</sup>, and [η<sup>5</sup>-CpOs(CO)<sub>2</sub>(CH<sub>4</sub>)]<sup>+</sup>: A Complete Set of Group 8 Metal–Methane Complexes Open
Here, we report the NMR spectroscopic analysis of the group 8 transition metal methane σ-complexes [η5-CpM(CO)2(CH4)][Al(OC(CF3)3)4] (M = Fe, Ru) at −90 °C in the weakly coordinating solvent 1,1,1,3,3,3-hexafluoropropane. The iron(II)–meth…
View article: Binding methane to a metal centre
Binding methane to a metal centre Open
View article: CCDC 2104761: Experimental Crystal Structure Determination
CCDC 2104761: Experimental Crystal Structure Determination Open
View article: CCDC 2104762: Experimental Crystal Structure Determination
CCDC 2104762: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2104760: Experimental Crystal Structure Determination
CCDC 2104760: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2104758: Experimental Crystal Structure Determination
CCDC 2104758: Experimental Crystal Structure Determination Open
View article: CCDC 2104759: Experimental Crystal Structure Determination
CCDC 2104759: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Functionally Altered Ruthenaindenes with Electron-Rich and Electron-Poor Substituents
Functionally Altered Ruthenaindenes with Electron-Rich and Electron-Poor Substituents Open
A series of ruthenaindene complexes containing electron-donating and -withdrawing groups were synthesized and characterized. The ruthenaindenes were synthesized from ruthenium butenynyl complexes which were formed by the treatment of Me2Ru…
View article: CCDC 1959433: Experimental Crystal Structure Determination
CCDC 1959433: Experimental Crystal Structure Determination Open
View article: CCDC 1959434: Experimental Crystal Structure Determination
CCDC 1959434: Experimental Crystal Structure Determination Open
View article: CCDC 1959463: Experimental Crystal Structure Determination
CCDC 1959463: Experimental Crystal Structure Determination Open
View article: CCDC 1959431: Experimental Crystal Structure Determination
CCDC 1959431: Experimental Crystal Structure Determination Open
View article: CCDC 1959432: Experimental Crystal Structure Determination
CCDC 1959432: Experimental Crystal Structure Determination Open
View article: CCDC 1946362: Experimental Crystal Structure Determination
CCDC 1946362: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1946356: Experimental Crystal Structure Determination
CCDC 1946356: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1946360: Experimental Crystal Structure Determination
CCDC 1946360: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1946357: Experimental Crystal Structure Determination
CCDC 1946357: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1946358: Experimental Crystal Structure Determination
CCDC 1946358: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1946355: Experimental Crystal Structure Determination
CCDC 1946355: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1946354: Experimental Crystal Structure Determination
CCDC 1946354: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1946359: Experimental Crystal Structure Determination
CCDC 1946359: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1946353: Experimental Crystal Structure Determination
CCDC 1946353: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …