Jan Vanbuel
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View article: Infrared spectra and structures of C60Rhn+ complexes
Infrared spectra and structures of C60Rhn+ complexes Open
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View article: Water Splitting by C<sub>60</sub>‐Supported Vanadium Single Atoms
Water Splitting by C<sub>60</sub>‐Supported Vanadium Single Atoms Open
Water splitting is an important source of hydrogen, a promising future carrier for clean and renewable energy. A detailed understanding of the mechanisms of water splitting, catalyzed by supported metal atoms or nanoparticles, is essential…
View article: Argon tagging of doubly transition metal doped aluminum clusters: The importance of electronic shielding
Argon tagging of doubly transition metal doped aluminum clusters: The importance of electronic shielding Open
The interaction of argon with doubly transition metal doped aluminum clusters, AlnTM2+ (n = 1–18, TM = V, Nb, Co, Rh), is studied experimentally in the gas phase via mass spectrometry. Density functional theory calculations on selected siz…
View article: The effect of size, charge state and composition on the binding of propene to yttrium-doped gold clusters
The effect of size, charge state and composition on the binding of propene to yttrium-doped gold clusters Open
The catalytic activity of metal clusters can be easily tuned by their size, charge state, or the introduction of dopant atoms.
View article: An octacoordinated Nb atom in the NbAl<sub>8</sub>H<sub>8</sub><sup>+</sup> cluster
An octacoordinated Nb atom in the NbAl<sub>8</sub>H<sub>8</sub><sup>+</sup> cluster Open
Combined mass spectrometry, infrared spectroscopy, and computational modelling work revealed a unique high-symmetric structure of NbAl 8 H 8 + .
View article: Reactivity of Cobalt‐Fullerene Complexes towards Deuterium
Reactivity of Cobalt‐Fullerene Complexes towards Deuterium Open
The adsorption of molecular deuterium (D 2 ) onto charged cobalt‐fullerene‐complexes Co n C 60 + ( n =1–8) is measured experimentally in a few‐collision reaction cell. The reactivity is strongly size‐dependent, hinting at clustering of the…
View article: Hydrogen Adsorption and Dissociation on Al<i><sub>n</sub></i>Rh<sub>2</sub><sup>+</sup> (<i>n</i> = 1 to 9) Clusters: Steric and Coordination Effects
Hydrogen Adsorption and Dissociation on Al<i><sub>n</sub></i>Rh<sub>2</sub><sup>+</sup> (<i>n</i> = 1 to 9) Clusters: Steric and Coordination Effects Open
The interaction of molecular hydrogen with doubly rhodium doped aluminum clusters, AlnRh2+ (n = 1 to 9), is investigated by a combination of time-of-flight mass spectrometry, infrared multiple photon dissociation spectroscopy, and density …
View article: Few-atom cluster model systems for a hydrogen economy
Few-atom cluster model systems for a hydrogen economy Open
To increase the share of renewable zero-emission energy sources, such as wind and solar power, in our energy supply, the problem of their intermittency needs to be addressed. One way to do so is by buffering excess renewable energy via the…
View article: Non‐covalent Interactions and Charge Transfer between Propene and Neutral Yttrium‐Doped and Pure Gold Clusters
Non‐covalent Interactions and Charge Transfer between Propene and Neutral Yttrium‐Doped and Pure Gold Clusters Open
The dopant and size‐dependent propene adsorption on neutral gold (Au n ) and yttrium‐doped gold (Au n −1 Y) clusters in the n= 5–15 size range are investigated, combining mass spectrometry and gas phase reactions in a low‐pressure collisio…
View article: Hydrogen Chemisorption on Doubly Vanadium Doped Aluminum Clusters
Hydrogen Chemisorption on Doubly Vanadium Doped Aluminum Clusters Open
The interaction of hydrogen with doubly vanadium doped aluminum clusters, Al n V 2 + ( n = 1–12), is studied experimentally by time-of-flight mass spectrometry and infrared multiple photon dissociation spectroscopy. The hydrogen binding ge…
View article: Altering CO binding on gold cluster cations by Pd-doping
Altering CO binding on gold cluster cations by Pd-doping Open
Pd plays a crucial role in enhancing CO adsorption strength, through both direct and indirect means.
View article: Tuning the Reactivity of Small Metal Clusters by Heteroatom Doping
Tuning the Reactivity of Small Metal Clusters by Heteroatom Doping Open
The reactivity of small metallic clusters, nanoparticles composed of a countable number of atoms (typically up to ∼100 atoms), has attracted much attention due to the fascinating properties these objects possess toward a variety of molecul…
View article: Size Dependent H<sub>2</sub> Adsorption on Al<sub><i>n</i></sub>Rh<sup>+</sup> (<i>n</i> = 1–12) Clusters
Size Dependent H<sub>2</sub> Adsorption on Al<sub><i>n</i></sub>Rh<sup>+</sup> (<i>n</i> = 1–12) Clusters Open
© 2018 American Chemical Society. The interaction of hydrogen with singly rhodium doped aluminum clusters AlnRh+ (n = 1-12) is investigated experimentally by a combination of time-of-flight mass spectrometry and infrared multiple photon di…
View article: Effect of radiative cooling on the size-dependent stability of small boron clusters
Effect of radiative cooling on the size-dependent stability of small boron clusters Open
© 2018 American Physical Society. The mass spectrum of cationic boron clusters, BN+ (N=5-20), after photoexcitation demonstrates that radiative cooling is an important, though often neglected, process in determining the relative stability …
View article: Effect of palladium doping on the stability and fragmentation patterns of cationic gold clusters
Effect of palladium doping on the stability and fragmentation patterns of cationic gold clusters Open
We analyze in detail how the interplay between electronic structure and cluster geometry determines the stability and the fragmentation channels of single Pd doped cationic Au clusters, PdAu_{N-1}^+ (N=2−20). For this purpose, a combinatio…
View article: Effects of Charge Transfer on the Adsorption of CO on Small Molybdenum‐Doped Platinum Clusters
Effects of Charge Transfer on the Adsorption of CO on Small Molybdenum‐Doped Platinum Clusters Open
The interaction of carbon monoxide with platinum alloy nanoparticles is an important problem in the context of fuel cell catalysis. In this work, molybdenum‐doped platinum clusters have been studied in the gas phase to obtain a better unde…