Jeremy D. Hilgar
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View article: Reversible Dinitrogen Binding by an Intermediate Spin Monovalent Chromium Complex
Reversible Dinitrogen Binding by an Intermediate Spin Monovalent Chromium Complex Open
A unique low valent 15 e- Cr(I) species, Cp*Cr(CNArDipp2)2 (2) (Cp* = Me5C5, CNArDipp2 = 2,6-(2,6-(iPr)2C6H3)2C6H3) was isolated under Ar atmosphere. It’s intermediate spin ground state (S = 3/2) was determined via Evans’s method with 1H N…
View article: Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs
Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs Open
Polymeric materials bearing Frustrated Lewis Pair (FLP) functionality are promising candidates for use as heterogeneous catalysts and adaptive materials, but synthetic access to FLP-functional polymers remains limited due to the incompatib…
View article: Silylimidazolium Hexafluorophosphate Salts as Synthetic Precursors to N-Heterocyclic Carbene Pentafluorophosphorus Adducts
Silylimidazolium Hexafluorophosphate Salts as Synthetic Precursors to N-Heterocyclic Carbene Pentafluorophosphorus Adducts Open
N-Heterocyclic carbene pentafluorophosphorus (NHC-PF5) adducts are six-coordinate phosphorus(v) compounds with emerging applications but poor synthetic accessibility. We have developed a simple and high yielding protocol for synthesizing i…
View article: Dipolar Coupling as a Mechanism for Fine Control of Magnetic States in ErCOT-Alkyl Molecular Magnets
Dipolar Coupling as a Mechanism for Fine Control of Magnetic States in ErCOT-Alkyl Molecular Magnets Open
The design of molecular magnets has progressed greatly by taking advantage of the ability to impart successive perturbations and control vibronic transitions in 4fn systems through the careful manipulation of the crystal field. Herein, we …
View article: Increasing the Strength, Hardness, and Survivability of Semiconducting Polymers by Crosslinking
Increasing the Strength, Hardness, and Survivability of Semiconducting Polymers by Crosslinking Open
Crosslinking is a ubiquitous strategy in polymer engineering to increase the thermomechanical robustness of solid polymers but has been relatively unexplored in the context of π‐conjugated (semiconducting) polymers. Notwithstanding, mechan…
View article: CCDC 2083100: Experimental Crystal Structure Determination
CCDC 2083100: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083101: Experimental Crystal Structure Determination
CCDC 2083101: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083099: Experimental Crystal Structure Determination
CCDC 2083099: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: (Cot)TbI(thf)2
(Cot)TbI(thf)2 Open
This contains the dataset for (Cot)TbI(thf)2
View article: (Cot)Dy(cnt)
(Cot)Dy(cnt) Open
This contains the dataset for (Cot)Dy(cnt)
View article: (Cot)HoI(thf)2
(Cot)HoI(thf)2 Open
The dataset contains all experimental data for (Cot)HoI(thf)2
View article: (Cot)Er(Cnt)
(Cot)Er(Cnt) Open
This contains the dataset for (Cot)Er(Cnt)
View article: (Cot)Er(Cnt)
(Cot)Er(Cnt) Open
This contains the dataset for (Cot)Er(Cnt)
View article: (Cot)Tb(transCnt)
(Cot)Tb(transCnt) Open
This contains the dataset for (Cot)Tb(transCnt)
View article: (Cot)Ho(Cnt)
(Cot)Ho(Cnt) Open
This contains the dataset for (Cot)Ho(Cnt)
View article: (Cot)TbI(thf)2
(Cot)TbI(thf)2 Open
This contains the dataset for (Cot)TbI(thf)2
View article: (Cot)Tm(Cnt)
(Cot)Tm(Cnt) Open
This contains the dataset for (Cot)Tm(Cnt)
View article: (Cot)Lu(Cnt)
(Cot)Lu(Cnt) Open
This contains the dataset for (Cot)Lu(Cnt)
View article: (Cot)Lu(BF4)(thf)_dimer
(Cot)Lu(BF4)(thf)_dimer Open
This contains the dataset for (Cot)Lu(BF4)(thf)_dimer
View article: (Cot)Lu(Cnt)
(Cot)Lu(Cnt) Open
This contains the dataset for (Cot)Lu(Cnt)
View article: (Cot)HoI(thf)2
(Cot)HoI(thf)2 Open
The dataset contains all experimental data for (Cot)HoI(thf)2
View article: (Cot)Lu(BF4)(thf)_dimer
(Cot)Lu(BF4)(thf)_dimer Open
This contains the dataset for (Cot)Lu(BF4)(thf)_dimer
View article: (Cot)Ho(Cnt)
(Cot)Ho(Cnt) Open
This contains the dataset for (Cot)Ho(Cnt)
View article: (Cot)Tb(Cnt)
(Cot)Tb(Cnt) Open
This contains the dataset for (Cot)Tb(Cnt)
View article: (Cot)Dy(cnt)
(Cot)Dy(cnt) Open
This contains the dataset for (Cot)Dy(cnt)
View article: (Cot)Tm(Cnt)
(Cot)Tm(Cnt) Open
This contains the dataset for (Cot)Tm(Cnt)
View article: (Cot)Tb(Cnt)
(Cot)Tb(Cnt) Open
This contains the dataset for (Cot)Tb(Cnt)
View article: (Cot)Tb(transCnt)
(Cot)Tb(transCnt) Open
This contains the dataset for (Cot)Tb(transCnt)