Jesper Bendix
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View article: Correction to “Determination of Uranium Central-Field Covalency with 3<i>d</i>4<i>f</i> Resonant Inelastic X-ray Scattering”
Correction to “Determination of Uranium Central-Field Covalency with 3<i>d</i>4<i>f</i> Resonant Inelastic X-ray Scattering” Open
View article: Tuning the <sup>2</sup>LMCT Deactivation of Cyclometalated Iron Carbene Complexes with Electronic Substituent Effects
Tuning the <sup>2</sup>LMCT Deactivation of Cyclometalated Iron Carbene Complexes with Electronic Substituent Effects Open
Fe III complexes based on the [Fe III (ImP) 2 ] + motif (ImP = bis(2,6‐bis(3‐methylimidazol‐2‐ylidene‐1‐yl)phenylene)), where the ligand contains both carbene and cyclometalated moieties, are a promising class of photoactive materials made…
View article: Magnetic Properties of Prolate Lanthanide Complexes: Synergy between Axial and Equatorial Ligands
Magnetic Properties of Prolate Lanthanide Complexes: Synergy between Axial and Equatorial Ligands Open
The chemical design of single-molecule magnets is a vibrant field of research. Huge efforts in determining the key factors to slow down the relaxation time of the magnetization led to massive improvements in the blocking temperature. Even …
View article: The role of electronic excited states in the spin-lattice relaxation of spin-1/2 molecules
The role of electronic excited states in the spin-lattice relaxation of spin-1/2 molecules Open
Magnetic resonance is a prime method for the study of chemical and biological structures and their dynamical processes. The interpretation of many of these experiments relies on understanding how the spin of unpaired electrons exchanges en…
View article: Exploiting High Order Magnetic Anisotropy for Advanced Magnetocaloric Refrigerants
Exploiting High Order Magnetic Anisotropy for Advanced Magnetocaloric Refrigerants Open
Three new 3 d – 4 f complexes of general formula trans ‐[MF 2 (py) 4 ][LnDOTA] (M=Cr 3+ or Co 3+ , Ln=Dy 3+ or Y 3+ , py=pyridine and DOTA=tetraazacyclododecane‐N,N′,N′′,N′′′‐tetraacetate) have been synthetised. The fluoride‐bridged system…
View article: Exploiting High Order Magnetic Anisotropy for Advanced Magnetocaloric Refrigerants
Exploiting High Order Magnetic Anisotropy for Advanced Magnetocaloric Refrigerants Open
Three new 3 d – 4 f complexes of general formula trans ‐[MF 2 (py) 4 ][LnDOTA] (M=Cr 3+ or Co 3+ , Ln=Dy 3+ or Y 3+ , py=pyridine and DOTA=tetraazacyclododecane‐N,N′,N′′,N′′′‐tetraacetate) have been synthetised. The fluoride‐bridged system…
View article: Dinuclear Dysprosium Compounds: The Importance of Rigid Bridges
Dinuclear Dysprosium Compounds: The Importance of Rigid Bridges Open
We report the synthesis, structures and magnetic behaviour of two isostructural dinuclear Dy 3+ complexes where the metal ions of a previously reported monomeric building block are connected by a peroxide (O 2 2− ) or a pair of fluoride (2…
View article: Determination of Uranium Central-Field Covalency with 3<i>d</i>4<i>f</i> Resonant Inelastic X-ray Scattering
Determination of Uranium Central-Field Covalency with 3<i>d</i>4<i>f</i> Resonant Inelastic X-ray Scattering Open
Understanding the nature of metal-ligand bonding is a major challenge in actinide chemistry. We present a new experimental strategy for addressing this challenge using actinide 3d4f resonant inelastic X-ray scattering (RIXS).…
View article: The role of electronic excited states in the spin-lattice relaxation of spin-1/2 molecules
The role of electronic excited states in the spin-lattice relaxation of spin-1/2 molecules Open
Magnetic resonance is a prime method for the study of chemical and biological structures and their dynamical processes. The interpretation of these experiments relies on considering the spin of electrons as the sole relevant degree of free…
View article: Determination of Uranium Central-Field Covalency with 3d4f Resonant Inelastic X-ray Scattering
Determination of Uranium Central-Field Covalency with 3d4f Resonant Inelastic X-ray Scattering Open
Understanding the nature of metal-ligand bonding is a major challenge in actinide chemistry. We present a new experimental strategy for addressing this challenge using actinide 3d4f resonant inelastic X-ray scattering (RIXS). Through a sys…
View article: How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron <i>N</i>-Heterocyclic Complexes: A Comparative Study
How Rigidity and Conjugation of Bidentate Ligands Affect the Geometry and Photophysics of Iron <i>N</i>-Heterocyclic Complexes: A Comparative Study Open
Two iron complexes featuring the bidentate, nonconjugated N-heterocyclic carbene (NHC) 1,1'-methylenebis(3-methylimidazol-2-ylidene) (mbmi) ligand, where the two NHC moieties are separated by a methylene bridge, have been synthesized to ex…
View article: Parallel-mode EPR spectra of the hexaaqua manganese(II) Ion in tetrahedral symmetry
Parallel-mode EPR spectra of the hexaaqua manganese(II) Ion in tetrahedral symmetry Open
Parallel-mode X-band EPR spectra of the manganese(II) hexaaqua ion as substitutional impurity in Cs[Mg(H 2 O) 6 ]AsO 4 are presented and interpreted. In this lattice the aqua ion, considering also the disposition of the hydrogen atoms, occ…
View article: A homoleptic Ag<sup>III</sup> complex stabilized by succinimidate ligands
A homoleptic Ag<sup>III</sup> complex stabilized by succinimidate ligands Open
Herein, the first example of a homoleptic Ag III complex stabilized by a monodentate N-donor ligand is presented.
View article: Inside back cover
Inside back cover Open
This article is Open Access All publication charges for this article have been paid for by the Royal Society of Chemistry
View article: CCDC 2281618: Experimental Crystal Structure Determination
CCDC 2281618: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2281616: Experimental Crystal Structure Determination
CCDC 2281616: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2281620: Experimental Crystal Structure Determination
CCDC 2281620: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2281329: Experimental Crystal Structure Determination
CCDC 2281329: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2281617: Experimental Crystal Structure Determination
CCDC 2281617: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2281619: Experimental Crystal Structure Determination
CCDC 2281619: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2281615: Experimental Crystal Structure Determination
CCDC 2281615: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: LnDOTA puppeteering: removing the water molecule and imposing tetragonal symmetry
LnDOTA puppeteering: removing the water molecule and imposing tetragonal symmetry Open
Ionic strength and solid state packing effects have been used to remove the coordinated water molecule from the LnDOTA complexes, allowing to understand the magnetic anisotropy and single molecule magnet properties of these complexes.
View article: Spatially anisotropic <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mi>S</mml:mi><mml:mo>=</mml:mo><mml:mn>1</mml:mn></mml:mrow></mml:math> square-lattice antiferromagnet with single-ion anisotropy realized in a Ni(II) pyrazine-<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mi>n</mml:mi><mml:mo>,</mml:mo><mml:msup><mml:mi>n</mml:mi><mml:mo>′</mml:mo></mml:msup></mml:mrow></mml:math>-dioxide coordination polymer
Spatially anisotropic square-lattice antiferromagnet with single-ion anisotropy realized in a Ni(II) pyrazine--dioxide coordination polymer Open
The Ni(NCS)2(pyzdo)2 coordination polymer is found to be an S = 1 spatially-anisotropic square lattice with easy-axis single-ion anisotropy. This conclusion is based upon considering in concert the experimental probes X-ray diffraction, ma…
View article: CCDC 2254082: Experimental Crystal Structure Determination
CCDC 2254082: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2254083: Experimental Crystal Structure Determination
CCDC 2254083: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Tunable valence tautomerism in lanthanide-organic alloys
Tunable valence tautomerism in lanthanide-organic alloys Open
The electronic structures of the lanthanide (Ln) ions are inimitable and key to advanced materials and technologies. The trivalent ions are ubiquitous and dwarf the use of di- and tetra-valent analogues, which, however, possess vastly diff…
View article: CO<sub>2</sub> complexation with cyclodextrins
CO<sub>2</sub> complexation with cyclodextrins Open
Carbon dioxide (CO 2 ) emissions from industrial processes, power generation, and transportation contribute significantly to global warming and climate change. Carbon capture and storage (CCS) technologies are essential to reduce these emi…
View article: CCDC 2247021: Experimental Crystal Structure Determination
CCDC 2247021: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited
Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited Open
Photoluminescence of the Fe III complex occurs only from its 2 LMCT state while its higher-energy but shorter-lived 2 MLCT state is non-luminescent. Blue emission arises instead from a photoproduct of the non-emitting Fe II complex.
View article: CCDC 2207832: Experimental Crystal Structure Determination
CCDC 2207832: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …