Jesse Murillo
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View article: Product Variation in Reactions of MI<sub>3</sub>(thf)<sub>4</sub> with Bis(Mesitoyl)Phosphide Across the M = U, Np, Pu Series
Product Variation in Reactions of MI<sub>3</sub>(thf)<sub>4</sub> with Bis(Mesitoyl)Phosphide Across the M = U, Np, Pu Series Open
A series of reactions using sodium bis(mesitoyl)phosphide (MesBAP-) with the actinide starting material AnI3(thf)4 (An = U, Np, Pu) as well as the analogous reaction with CeI3(thf)4 was performed. Similar U and Np An(MesBAP)4 (An = U, Np) …
View article: Structural and Theoretical Assessment of Covalency in a Pu(III) Borohydride Complex
Structural and Theoretical Assessment of Covalency in a Pu(III) Borohydride Complex Open
Despite the discovery of actinide borohydride complexes over 80 years ago, no plutonium borohydride complexes have been structurally validated using single-crystal X-ray diffraction (XRD). Here we describe Pu2(H3BPtBu2BH3)6, the first exam…
View article: Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs
Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs Open
Organoplutonium chemistry was established in 1965, yet structurally authenticated plutonium-carbon bonds remain rare being limited to π-bonded carbocycle and σ-bonded isonitrile and hydrocarbyl derivatives. Thus, plutonium-carbenes, includ…
View article: Examining the Electronic Structures of Monouranium Endohedral Metallofullerenes: Solution Versus Solid-State Effects in U@C82
Examining the Electronic Structures of Monouranium Endohedral Metallofullerenes: Solution Versus Solid-State Effects in U@C82 Open
In uranium endohedral metallofullerenes, cage isomer dependent oxidation states have been theoretically deter-mined for U3+@C2v(9)-C823- and U4+@C2(5)-C824+. Solution phase EPR supports this assessment; however, in the solid-state, EPR, SQ…
View article: CCDC 2238465: Experimental Crystal Structure Determination
CCDC 2238465: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238473: Experimental Crystal Structure Determination
CCDC 2238473: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238469: Experimental Crystal Structure Determination
CCDC 2238469: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238467: Experimental Crystal Structure Determination
CCDC 2238467: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238471: Experimental Crystal Structure Determination
CCDC 2238471: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238466: Experimental Crystal Structure Determination
CCDC 2238466: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238470: Experimental Crystal Structure Determination
CCDC 2238470: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238472: Experimental Crystal Structure Determination
CCDC 2238472: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2238468: Experimental Crystal Structure Determination
CCDC 2238468: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Trace Actinide Signatures of a Bulk Neptunium Sample
Trace Actinide Signatures of a Bulk Neptunium Sample Open
In nuclear forensic analyses, measurements of actinide elements in a sample can assist with identifying interdicted or unknown materials. While these radiochemical signatures have been extensively investigated in uranium materials, less is…
View article: CCDC 2206769: Experimental Crystal Structure Determination
CCDC 2206769: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2206446: Experimental Crystal Structure Determination
CCDC 2206446: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2206768: Experimental Crystal Structure Determination
CCDC 2206768: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2206447: Experimental Crystal Structure Determination
CCDC 2206447: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2206445: Experimental Crystal Structure Determination
CCDC 2206445: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis of Trimethyltriazacyclohexane (Me<sub>3</sub>tach) Sandwich Complexes of Uranium, Neptunium, and Plutonium Triiodides: (Me<sub>3</sub>tach)<sub>2</sub>AnI<sub>3</sub>
Synthesis of Trimethyltriazacyclohexane (Me<sub>3</sub>tach) Sandwich Complexes of Uranium, Neptunium, and Plutonium Triiodides: (Me<sub>3</sub>tach)<sub>2</sub>AnI<sub>3</sub> Open
1,3,5-Trimethyl-1,3,5-triazacyclohexane (Me3tach) readily complexes uranium triiodide to form (Me3tach)2UI3. The complex is soluble in THF and arenes and can function as a source of UI3 to form organometallic U(III) complexes. When dissolv…
View article: CCDC 2172188: Experimental Crystal Structure Determination
CCDC 2172188: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172190: Experimental Crystal Structure Determination
CCDC 2172190: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172189: Experimental Crystal Structure Determination
CCDC 2172189: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Actinide Arene-Metalates: 2. A Neutral Uranium Bis(Anthracenide) Sandwich Complex and Elucidation of its Electronic Structure
Actinide Arene-Metalates: 2. A Neutral Uranium Bis(Anthracenide) Sandwich Complex and Elucidation of its Electronic Structure Open
An unprecedented sandwich complex of the actinides is synthesized from the treatment of [UI2(HMPA)4]I (HMPA = OP(NMe2)3) (2) with 3 equiv. of K[C14H10] to give the neutral, bis(arenide) species U(η6-C14H10)(η4-C14H10)(HMPA)2 (1). Solid-sta…
View article: CCDC 2125324: Experimental Crystal Structure Determination
CCDC 2125324: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125323: Experimental Crystal Structure Determination
CCDC 2125323: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125329: Experimental Crystal Structure Determination
CCDC 2125329: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125330: Experimental Crystal Structure Determination
CCDC 2125330: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125327: Experimental Crystal Structure Determination
CCDC 2125327: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2125325: Experimental Crystal Structure Determination
CCDC 2125325: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …