Jia‐Rong Chen
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View article: Visible‐Light‐Driven 1,4‐Hydroalkylation of 1,3‐Conjugated Dienes with 1,3‐Dicarbonyls <sup>†</sup>
Visible‐Light‐Driven 1,4‐Hydroalkylation of 1,3‐Conjugated Dienes with 1,3‐Dicarbonyls <sup>†</sup> Open
Comprehensive Summary A mild and efficient visible‐light‐driven 1,4‐hydroalkylation of conjugated dienes with perfect atom economy, is disclosed. Key steps of this protocol involve catalytic generation of C ‐radicals from readily available…
View article: CCDC 2422766: Experimental Crystal Structure Determination
CCDC 2422766: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Evolutionary diversification of acyl-CoA synthetases underpins hydrophobic barrier formation across diverse tomato tissues and beyond
Evolutionary diversification of acyl-CoA synthetases underpins hydrophobic barrier formation across diverse tomato tissues and beyond Open
The transition of plants from aquatic to terrestrial environments required effective barriers against water loss and UV damage. The plant cuticle, a hydrophobic barrier covering aerial surfaces, emerged as a critical innovation, yet how it…
View article: Photoinduced Copper‐Catalyzed Asymmetric Radical Sulfonylcyanation of Vinylarenes with Sulfonyl Cyanides
Photoinduced Copper‐Catalyzed Asymmetric Radical Sulfonylcyanation of Vinylarenes with Sulfonyl Cyanides Open
The radical difunctionalization of alkenes, which involves the simultaneous incorporation of two functional groups across a carbon‐carbon double bond, is emerging as a robust platform for step‐ and atom‐economical construction of valuable …
View article: Enantioselective synthesis of chiral N-arylpyrroles through photoinduced desymmetrization
Enantioselective synthesis of chiral N-arylpyrroles through photoinduced desymmetrization Open
View article: Increasing phosphorus limitation with tree age in tropical forests
Increasing phosphorus limitation with tree age in tropical forests Open
Aims Phosphorus (P) availability commonly limits the growth of tropical plants, yet how this limitation changes with tree age remains uncertain.Methods Here we investigated the effect of tree age on P limitation in a tropical forest by exa…
View article: Novel Insights into the Mechanism of Luteolin and its Analogues as Potent Inhibitors of Xanthine Oxidase Activity: Inhibition Thermodynamics, Kinetics and Docking Simulation
Novel Insights into the Mechanism of Luteolin and its Analogues as Potent Inhibitors of Xanthine Oxidase Activity: Inhibition Thermodynamics, Kinetics and Docking Simulation Open
View article: Photoinduced Copper‐Catalyzed Three‐Component Radical Carboamination of Styrene Derivatives
Photoinduced Copper‐Catalyzed Three‐Component Radical Carboamination of Styrene Derivatives Open
The catalytic three‐component radical carboamination of alkenes has recently emerged as an alternative and robust platform for the rapid construction of diverse and valuable amines. Despite great advances in this field, new methods that en…
View article: A General Copper‐Box System for the Asymmetric Arylative Functionalization of Benzylic, Propargylic or Allenylic Radicals
A General Copper‐Box System for the Asymmetric Arylative Functionalization of Benzylic, Propargylic or Allenylic Radicals Open
Radical‐involved arylative cross‐coupling reactions have recently emerged as an attractive strategy to access valuable aryl‐substituted motifs. However, there still exist several challenges such as limited scope of radical precursors/accep…
View article: Pentalogy of Cantrell: A case report from China
Pentalogy of Cantrell: A case report from China Open
View article: Engineering Interphasial Chemistry for Zn Anodes in Aqueous Zinc Ion Batteries
Engineering Interphasial Chemistry for Zn Anodes in Aqueous Zinc Ion Batteries Open
Aqueous zinc ion batteries (AZIBs) have emerged as promising candidates for large-scale energy storage systems during post lithium-ion era, drawing attention for their environmental-friendliness, cost-effectiveness, high safety, and minima…
View article: A General Copper-Box System for the Asymmetric Ary-lative Functionalization of Benzylic, Propargylic or Allenylic Radicals
A General Copper-Box System for the Asymmetric Ary-lative Functionalization of Benzylic, Propargylic or Allenylic Radicals Open
Radical-involved arylative cross-coupling reactions have recently emerged as an attractive strategy to access valuable aryl-substituted motifs. However, there still exist several challenges such as limited scope of radi-cal precursors/acce…
View article: Radicals as Chiral Catalysts for Asymmetric Radical Cyclization Reactions
Radicals as Chiral Catalysts for Asymmetric Radical Cyclization Reactions Open
Due to the innate highly reactive properties and short life‐time, organic free radicals can often serve as promoters or intermediates to engage in various radical transformations, which are often otherwise difficult to access by ionic path…
View article: Controlled generation of ortho-quinone methides and (4+3) cyclization with 2-indolylalcohols by dual photoredox/Brønsted acid relay catalysis
Controlled generation of ortho-quinone methides and (4+3) cyclization with 2-indolylalcohols by dual photoredox/Brønsted acid relay catalysis Open
Given the significance of oxacyclic frameworks in molecular scaffolds and drug discovery, it is intriguing to precisely construct and manipulate such ring systems in chemical research. In this area, the intermolecular, multicomponent cycli…
View article: A Study on the Forecast of Fine Dust Emissions in the Future According to the Introduction of Eco-Friendly Ships
A Study on the Forecast of Fine Dust Emissions in the Future According to the Introduction of Eco-Friendly Ships Open
View article: Sensor-Fusion-based Optimal Multi-Disturbance Filtering in Atomic Force Microscope Imaging
Sensor-Fusion-based Optimal Multi-Disturbance Filtering in Atomic Force Microscope Imaging Open
View article: Influence of sintering temperature on structure and mechanical properties of polycrystalline cubic boron nitride composites
Influence of sintering temperature on structure and mechanical properties of polycrystalline cubic boron nitride composites Open
Polycrystalline cubic boron nitride (PcBN) cutting tool materials were prepared by mixing cBN (85 wt.%) and TiN-Ti-Co (15 wt.%) micropowders under high temperature and ultra-high pressure. X-ray diffraction and scanning electron microscopy…
View article: Regulating the Horizontal Confined Deposition of Lithium Metal by Co-Nx Modified Honeycomb-Like Carbon Nanosheets
Regulating the Horizontal Confined Deposition of Lithium Metal by Co-Nx Modified Honeycomb-Like Carbon Nanosheets Open
View article: Controlled Generation of Ortho-Quinone Methides and (4+3) Cyclization with 2-Indolylalcohols by Dual Photoredox/Brønsted Acid Relay Catalysis
Controlled Generation of Ortho-Quinone Methides and (4+3) Cyclization with 2-Indolylalcohols by Dual Photoredox/Brønsted Acid Relay Catalysis Open
View article: Increasing Phosphorus Limitation with Tree Age in Tropical Forests
Increasing Phosphorus Limitation with Tree Age in Tropical Forests Open
View article: Photoinduced Five‐Component Radical Relay Aminocarbonylation of Alkenes
Photoinduced Five‐Component Radical Relay Aminocarbonylation of Alkenes Open
Radical single carbonylation reactions with CO constitute a direct and robust strategy toward various carbonyl compounds from readily available chemicals, and have been extensively studied over the past decades. However, realizing highly s…
View article: Optimized allotopic expression of mitochondrial ND6 transgene restored complex I and apoptosis deficiencies caused by LHON-linked ND6 14484T > C mutation
Optimized allotopic expression of mitochondrial ND6 transgene restored complex I and apoptosis deficiencies caused by LHON-linked ND6 14484T > C mutation Open
Background Leber’s hereditary optic neuropathy (LHON) is a maternally inherited eye disease due to mutations in mitochondrial DNA. However, there is no effective treatment for this disease. LHON-linked ND6 14484T > C (p.M64V) mutation caus…
View article: Bioinformatic analysis of short-chain dehydrogenase/reductase proteins in plant peroxisomes
Bioinformatic analysis of short-chain dehydrogenase/reductase proteins in plant peroxisomes Open
Peroxisomes are ubiquitous eukaryotic organelles housing not only many important oxidative metabolic reactions, but also some reductive reactions that are less known. Members of the short-chain dehydrogenase/reductase (SDR) superfamily, wh…
View article: Large-range high-speed dynamic-mode atomic force microscope imaging: adaptive tapping towards minimal force
Large-range high-speed dynamic-mode atomic force microscope imaging: adaptive tapping towards minimal force Open
In this paper, a software-hardware integrated approach is proposed for high-speed, large-range tapping mode imaging of atomic force microscope (AFM). High speed AFM imaging is needed in various applications, particularly in interrogating d…
View article: The Impact of Marketing Labels on Housing Prices: An Empirical Study on Hangzhou City
The Impact of Marketing Labels on Housing Prices: An Empirical Study on Hangzhou City Open
As urbanization continues to advance, real estate development is gradually shifting from an incremental market to a stock market, and consumers' requirements for the "comfort" and "functionality" of residential properties have increased si…
View article: Multi-objective Spatial Optimization and Evaluation of Land Use in Xishuangbanna
Multi-objective Spatial Optimization and Evaluation of Land Use in Xishuangbanna Open
Effective management of environmental resources and energy demands optimal land use, which is a crucial issue in environmental planning and assessment nowadays. This paper proposes a method for optimal land use in the Xishuangbanna Prefect…
View article: Photochemical Synthesis of Unsymmetric Azoxy Compounds and Azoxy Group Transfer Reactions
Photochemical Synthesis of Unsymmetric Azoxy Compounds and Azoxy Group Transfer Reactions Open
View article: Phase Composition, Microstructure, and Mechanical Properties of Pcbn Composites with Ti and Ti-Al Binders: Effects of Holding Time and Synthesis Pressure
Phase Composition, Microstructure, and Mechanical Properties of Pcbn Composites with Ti and Ti-Al Binders: Effects of Holding Time and Synthesis Pressure Open
View article: Enantioselective diversification of alkene radical anions
Enantioselective diversification of alkene radical anions Open
Alkene radical ions constitute an integral and unique class of reactive intermediates for the synthesis of valuable compounds, because they have both unpaired spins and charge. However, relatively few synthetic applications of alkene radic…
View article: CCDC 2203911: Experimental Crystal Structure Determination
CCDC 2203911: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …