Jonas Brandhoff
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View article: When Aromaticity Falls Short in Molecule–Surface Interactions
When Aromaticity Falls Short in Molecule–Surface Interactions Open
Aromaticity is one of the most important concepts in organic chemistry. There are cases in which a molecule undergoes changes to increase its aromaticity. This higher aromaticity comes with an energetic gain and is commonly referred to as …
View article: Enantiospecific mirror-imaged growth in overlayers of enantiopure thiadiazole-[9]helicene on Au(111) without commensurability
Enantiospecific mirror-imaged growth in overlayers of enantiopure thiadiazole-[9]helicene on Au(111) without commensurability Open
Two-dimensional (2D) crystallization of chiral molecules on achiral crystal surfaces typically exhibits mirror-imaged growth, defined by the substrate’s mirror plane and the lattices of each enantiomer. While various commensurate molecular…
View article: Partial restoration of aromaticity of pentacene-5,7,12,14-tetrone on Cu(111)
Partial restoration of aromaticity of pentacene-5,7,12,14-tetrone on Cu(111) Open
CO-AFM measurements and DFT calculations demonstrate that the aromaticity of pentacene-5,7,12,14-tetrone (P4O) is only partially restored upon interaction with the Cu(111) surface, contrasting the model of surface-induced aromatic stabiliz…
View article: Lifshitz Transition and Band Structure Evolution in Alkali Metal Intercalated 1Tprime-MoTe2
Lifshitz Transition and Band Structure Evolution in Alkali Metal Intercalated 1Tprime-MoTe2 Open
In van der Waals materials, coupling between adjacent layers is weak, and consequently interlayer interactions are weakly screened. This opens the possibility to profoundly modify the electronic structure, e.g., by applying electric fields…