Jonas R. Schmid
YOU?
Author Swipe
View article: Synthesis and Characterization of the μ<sub>6</sub>-F Compounds [NEt<sub>4</sub>][F(Cl<sub>2</sub>)<sub>3</sub>] and [NEt<sub>4</sub>][F(Br<sub>2</sub>)<sub>3</sub>]
Synthesis and Characterization of the μ<sub>6</sub>-F Compounds [NEt<sub>4</sub>][F(Cl<sub>2</sub>)<sub>3</sub>] and [NEt<sub>4</sub>][F(Br<sub>2</sub>)<sub>3</sub>] Open
The reaction of tetraethylammonium polychlorides or polybromides in propionitrile with substoichiometric amounts of diluted fluorine at low temperatures leads to the non-classical interhalogen compounds [NEt4]-[F-(X2)…
View article: Ferrocene‐Based Ozonide: [CpFeCpCH<sub>2</sub>NMe<sub>3</sub>]O<sub>3</sub>·1.47 NH<sub>3</sub>, Synthesis and Crystal Structure Analysis
Ferrocene‐Based Ozonide: [CpFeCpCH<sub>2</sub>NMe<sub>3</sub>]O<sub>3</sub>·1.47 NH<sub>3</sub>, Synthesis and Crystal Structure Analysis Open
The highly reactive ozonide anion could be stabilized for the first time with a ferrocene‐based cation resulting in the title compound [CpFeCpCH 2 NMe 3 ]O 3 ·1.47 NH 3 . The target compound was thoroughly characterized by X‐ray diffractio…
View article: Investigation of Pyrrolidinium‐based Superoxides and Ozonides
Investigation of Pyrrolidinium‐based Superoxides and Ozonides Open
Pyrrolidinium‐based cations were systematically modified to investigate their influence on ozonide and superoxide anions and to understand the scattering of experimentally determined dimensions of these radical anions. Hence, 1‐ethyl‐1‐met…
View article: Formation of Peroxynitrite, [O−N−O−O]<sup>−</sup>, via a Cascade of Reactions between Ozonide and Ammonia
Formation of Peroxynitrite, [O−N−O−O]<sup>−</sup>, via a Cascade of Reactions between Ozonide and Ammonia Open
We report on an unexpected reaction between ammonia and potassium ozonide dissolved in liq. NH 3 resulting in the formation of peroxynitrite, [ONOO] − , which exclusively happens in the presence of a specific partially fluorinated aniline‐…
View article: [Me <sub>3</sub> N(C <sub>6</sub> H <sub>3</sub> (CF <sub>3</sub> ) <sub>2</sub> )][BF <sub>4</sub> ] and [Me <sub>3</sub> N(C <sub>6</sub> H <sub>3</sub> (CH <sub>3</sub> ) <sub>2</sub> )][BF <sub>4</sub> ], as potential synthons for non-covalent supramolecular assembly
[Me <sub>3</sub> N(C <sub>6</sub> H <sub>3</sub> (CF <sub>3</sub> ) <sub>2</sub> )][BF <sub>4</sub> ] and [Me <sub>3</sub> N(C <sub>6</sub> H <sub>3</sub> (CH <sub>3</sub> ) <sub>2</sub> )][BF <sub>4</sub> ], as potential synthons for non-covalent supramolecular assembly Open
The compounds [Me 3 N(C 6 H 3 (CF 3 ) 2 )][BF 4 ] and [Me 3 N(C 6 H 3 (CH 3 ) 2 )][BF 4 ] were synthesized from commercially available starting materials and fully characterized by single-crystal X-ray diffraction, NMR, IR and Raman spectr…
View article: CCDC 2176412: Experimental Crystal Structure Determination
CCDC 2176412: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Cover Feature: [NEt<sub>3</sub>Me][O<sub>3</sub>], Synthesis, Crystal Growth and Crystal Structure Analysis (Z. Anorg. Allg. Chem. 21/2022)
Cover Feature: [NEt<sub>3</sub>Me][O<sub>3</sub>], Synthesis, Crystal Growth and Crystal Structure Analysis (Z. Anorg. Allg. Chem. 21/2022) Open
Over time, several crystal structure analyses on ionic ozonides have been reported. As a puzzling and still debated outcome, the dimensions as found for the ozonide radical anion show a conspicuous spread. Inspecting crystal structures as …
View article: CCDC 2181389: Experimental Crystal Structure Determination
CCDC 2181389: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: [NEt<sub>3</sub>Me][O<sub>3</sub>], Synthesis, Crystal Growth and Crystal Structure Analysis
[NEt<sub>3</sub>Me][O<sub>3</sub>], Synthesis, Crystal Growth and Crystal Structure Analysis Open
[NEt 3 Me][O 3 ] was obtained for the first time by an ion exchange reaction in liquid ammonia. It was thoroughly characterized by X‐Ray diffraction [ P 2 1 ; a =598.51(4) pm, b =1032.03(7) pm, c =723.83(6) pm, β =92.677(3)°, R =0.0384, 15…
View article: CCDC 2096974: Experimental Crystal Structure Determination
CCDC 2096974: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Activation of tetrahydrofuran with 2-((Fluoroalkyl)thio)Benzothiazolium reagents
Activation of tetrahydrofuran with 2-((Fluoroalkyl)thio)Benzothiazolium reagents Open
The ability of BT-SCF3 and related 2-(fluoroalkylthio)benzothiazolium salts to activate tetrahydrofuran (THF) has been investigated. In the presence of carboxylate nucleophiles, ring-opening polymerization reactions affording various fluor…
View article: CCDC 2015007: Experimental Crystal Structure Determination
CCDC 2015007: Experimental Crystal Structure Determination Open
View article: CCDC 2015011: Experimental Crystal Structure Determination
CCDC 2015011: Experimental Crystal Structure Determination Open
View article: Radical C−H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide
Radical C−H Trifluoromethoxylation of (Hetero)arenes with Bis(trifluoromethyl)peroxide Open
Trifluoromethoxylated (hetero)arenes are of great interest for several disciplines, especially in agro‐ and medicinal chemistry. Radical C−H trifluoromethoxylation of (hetero)arenes represents an attractive approach to prepare such compoun…
View article: Conductivity and Redox Potentials of Ionic Liquid Trihalogen Monoanions [X<sub>3</sub>]<sup>−</sup>, [XY<sub>2</sub>]<sup>−</sup>, and [BrF<sub>4</sub>]<sup>−</sup> (X=Cl, Br, I and Y=Cl, Br)
Conductivity and Redox Potentials of Ionic Liquid Trihalogen Monoanions [X<sub>3</sub>]<sup>−</sup>, [XY<sub>2</sub>]<sup>−</sup>, and [BrF<sub>4</sub>]<sup>−</sup> (X=Cl, Br, I and Y=Cl, Br) Open
The ionic liquid (IL) trihalogen monoanions [N 2221 ][X 3 ] − and [N 2221 ][XY 2 ] − ([N 2221 ] + =triethylmethylammonium, X=Cl, Br, I, Y=Cl, Br) were investigated electrochemically via temperature dependent conductance and cyclic voltamme…
View article: CCDC 2015010: Experimental Crystal Structure Determination
CCDC 2015010: Experimental Crystal Structure Determination Open
View article: CCDC 2015012: Experimental Crystal Structure Determination
CCDC 2015012: Experimental Crystal Structure Determination Open
View article: CCDC 2015013: Experimental Crystal Structure Determination
CCDC 2015013: Experimental Crystal Structure Determination Open
View article: CCDC 2015014: Experimental Crystal Structure Determination
CCDC 2015014: Experimental Crystal Structure Determination Open
View article: CCDC 2015008: Experimental Crystal Structure Determination
CCDC 2015008: Experimental Crystal Structure Determination Open
View article: Soluble Fluoridobromates as Well‐Behaved Strong Fluorination Reagents
Soluble Fluoridobromates as Well‐Behaved Strong Fluorination Reagents Open
We present a facile synthesis of the soluble fluoridobromates [NEt 3 Me][BrF 4 ] and [NEt 3 Me][Br 2 F 7 ] via fluorination of the corresponding bromide salts in acetonitrile, propionitrile or bromine. We structurally characterized the [Br…
View article: CCDC 2015009: Experimental Crystal Structure Determination
CCDC 2015009: Experimental Crystal Structure Determination Open
View article: CCDC 1948998: Experimental Crystal Structure Determination
CCDC 1948998: Experimental Crystal Structure Determination Open
View article: CCDC 2004243: Experimental Crystal Structure Determination
CCDC 2004243: Experimental Crystal Structure Determination Open
View article: Verbesserter Zugang zu organisch löslichen Di‐ und Tetrafluoridochlorat(I/III)‐Salzen
Verbesserter Zugang zu organisch löslichen Di‐ und Tetrafluoridochlorat(I/III)‐Salzen Open
Es wird über eine einfache Eintopfsynthese für Tetraalkylammoniumtetrafluoridochlorat(III), [kat][ClF 4 ] ([kat]=[NEt 3 Me] + , [NEt 4 ] + ), im Gramm‐Maßstab berichtet. In Acetonitril wird ein Chloridsalz bei tiefen Temperaturen mit verdü…
View article: Improved Access to Organo‐Soluble Di‐ and Tetrafluoridochlorate(I)/(III) Salts
Improved Access to Organo‐Soluble Di‐ and Tetrafluoridochlorate(I)/(III) Salts Open
A facile one‐pot gram‐scale synthesis of tetraalkylammonium tetrafluoridochlorate(III) [cat][ClF 4 ] ([cat]=[NEt 3 Me] + , [NEt 4 ] + ) is described. An acetonitrile solution of the corresponding alkylammonium chloride salt is fluorinated …