Jonathan M. Ryss
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View article: Light <b>-</b> driven deracemization enabled by excited <b>-</b> state electron transfer
Light <b>-</b> driven deracemization enabled by excited <b>-</b> state electron transfer Open
Charging through the looking glass Asymmetric catalysis is a commonly applied technique to prepare just one of two mirror-image products in a chemical reaction. But what if you already have the compound you want, stuck in a mixture of left…
View article: Light-Driven Deracemization Enabled by Excited-State Electron Transfer
Light-Driven Deracemization Enabled by Excited-State Electron Transfer Open
A new strategy for catalytic deracemization is presented, wherein amine derivatives undergo spontaneous optical enrichment upon exposure to visible light in the presence of three distinct molecular catalysts. Initiated by an excited-state …
View article: Light-Driven Deracemization Enabled by Excited-State Electron Transfer
Light-Driven Deracemization Enabled by Excited-State Electron Transfer Open
A new strategy for catalytic deracemization is presented, wherein amine derivatives undergo spontaneous optical enrichment upon exposure to visible light in the presence of three distinct molecular catalysts. Initiated by an excited-state …
View article: Disulfide-Bridged Peptides That Mediate Enantioselective Cycloadditions through Thiyl Radical Catalysis
Disulfide-Bridged Peptides That Mediate Enantioselective Cycloadditions through Thiyl Radical Catalysis Open
An enantioselective vinylcyclopropane ring-opening/cycloaddition cascade is described. The active thiyl radical catalysts are generated in situ via UV light-promoted homolysis of cystine-based dimers. Amide-functionalization of the peptide…
View article: CCDC 1586383: Experimental Crystal Structure Determination
CCDC 1586383: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1577970: Experimental Crystal Structure Determination
CCDC 1577970: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …