Jorge Bañuelos
YOU?
Author Swipe
View article: Acid-Catalyzed Dehydrative Nucleophilic Substitutions of 2,6-Di(hydroxymethyl) BODIPYs: A Platform for BODIPY Functionalization
Acid-Catalyzed Dehydrative Nucleophilic Substitutions of 2,6-Di(hydroxymethyl) BODIPYs: A Platform for BODIPY Functionalization Open
We report the synthesis of the novel 2,6-di(hydroxymethyl)-1,3,5,7-tetramethyl-8-phenyl BODIPY and its utility in efficient Lewis-acid-catalyzed dehydrative nucleophilic substitution reactions. This diol, readily prepared via a formylation…
View article: Judicial Convergence on Climate Change
Judicial Convergence on Climate Change Open
In just over a year, three of the world’s most prominent courts have addressed States’ legal obligations in the context of climate change. Although each court examined various questions from its own unique institutional and legal standpoin…
View article: All-orthogonal BINOLated BODIPY dimers: A synergistic strategy for advancing heavy-metal-free triplet photosensitizers
All-orthogonal BINOLated BODIPY dimers: A synergistic strategy for advancing heavy-metal-free triplet photosensitizers Open
Covalently linked organic multichromophores are promising photoactive molecular scaffolds for developing valuable heavy-metal-free triplet photosensitizers. Among them, orthogonally connected BODIPY dimers and easily accessible at-boron BI…
View article: Special Issue “Design, Synthesis, and Mechanism of Fluorescent and Luminescent Materials”
Special Issue “Design, Synthesis, and Mechanism of Fluorescent and Luminescent Materials” Open
Fluorescent and luminescent materials continue to revolutionize a broad spectrum of disciplines, including chemical sensing, biological imaging, lighting, displays, photodynamic therapy (PDT), and information storage [...]
View article: Water-soluble BODIPY dyes: a novel approach for their sustainable chemistry and applied photonics
Water-soluble BODIPY dyes: a novel approach for their sustainable chemistry and applied photonics Open
Our work presents a simple and efficient method to impart water solubility to BODIPY dyes while preserving their key properties, enabling broader applications in aqueous environments.
View article: Benzo[f]indazoles: A new class of glow dyes for the generation of versatile fluorophores
Benzo[f]indazoles: A new class of glow dyes for the generation of versatile fluorophores Open
The surge of photonics as key enabling technology for lighting has driven the search of new chart of modern applied fluorophores. In this line, we recently found that a set of compounds previously synthesized by us and pertaining to the fa…
View article: Heavy-atom-free BODIPY-based photodynamic therapy agents activated at long wavelengths
Heavy-atom-free BODIPY-based photodynamic therapy agents activated at long wavelengths Open
Covalently linked BODIPY-based dimers through key 3 position are heavy-atom-free fluorescent sensitizers for photodynamic therapy enabling simultaneous cell killing and fluorescent staining upon illumination with red light.
View article: Enhanced Circularly Polarized Luminescence of Urea-Bridged Dimers of Axially Chiral BODIPY–Carbohydrate Hybrids
Enhanced Circularly Polarized Luminescence of Urea-Bridged Dimers of Axially Chiral BODIPY–Carbohydrate Hybrids Open
Herein, we report the synthesis of novel dimeric urea-bridged BODIPY-carbohydrate conjugates, which display circularly polarized luminescence (CPL). The dimers are composed of diastereomerically pure, axially chiral (P or M) BODIPY monomer…
View article: <i>De Novo</i> Access to BODIPY <i>C</i>-Glycosides as Linker-Free Nonsymmetrical BODIPY-Carbohydrate Conjugates
<i>De Novo</i> Access to BODIPY <i>C</i>-Glycosides as Linker-Free Nonsymmetrical BODIPY-Carbohydrate Conjugates Open
Recent years have witnessed an increasing interest in the synthesis and study of BODIPY-glycoconjugates. Most of the described synthetic methods toward these derivatives involve postfunctional modifications of the BODIPY core followed by t…
View article: Chemoselective reaction of methoxyaminomethyl BODIPYs with unprotected carbohydrates: a powerful tool for accessing BODIPY neoglycosides
Chemoselective reaction of methoxyaminomethyl BODIPYs with unprotected carbohydrates: a powerful tool for accessing BODIPY neoglycosides Open
The neoglycosylation of methoxyaminomethyl BODIPYs with unprotected reducing saccharides produces cyclic N -glycosyl- N -methoxy-BODIPY conjugates, which display excellent photophysical characteristics in pure water, even at high dye conce…
View article: A highly fluorescent and readily accessible all-organic photosensitizer model for advancing image-guided cancer PDT
A highly fluorescent and readily accessible all-organic photosensitizer model for advancing image-guided cancer PDT Open
A simple model for advancing the rapid construction of heavy-atom-free image-guided PDT agents for cancer treatment has been developed on the basis of using mitochondria targeting and BODIPY chemistry.
View article: Bridge-induced taming of the visible electronic circular dichroism signatures of helicoBODIPYs
Bridge-induced taming of the visible electronic circular dichroism signatures of helicoBODIPYs Open
Helically-flexible bis(BODIPY)s based on chiral ethane-1,2-diamine or −1,2-diol bridges (named helicoBODIPYs) are an interesting family of accessible and tunable small multichromophoric organic dyes enabling visible electronic circular dic…
View article: CCDC 2288043: Experimental Crystal Structure Determination
CCDC 2288043: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288046: Experimental Crystal Structure Determination
CCDC 2288046: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288042: Experimental Crystal Structure Determination
CCDC 2288042: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288044: Experimental Crystal Structure Determination
CCDC 2288044: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288048: Experimental Crystal Structure Determination
CCDC 2288048: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288047: Experimental Crystal Structure Determination
CCDC 2288047: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288045: Experimental Crystal Structure Determination
CCDC 2288045: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2269820: Experimental Crystal Structure Determination
CCDC 2269820: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Formylation as a Chemical Tool to Modulate the Performance of Photosensitizers Based on Boron Dipyrromethene Dimers
Formylation as a Chemical Tool to Modulate the Performance of Photosensitizers Based on Boron Dipyrromethene Dimers Open
Heavy-atom-free photosensitizers are envisioned as the next generation of photoactive molecules for photo-theragnosis. In this approach, and after suitable irradiation, a single molecular scaffold is able to visualize and kill tumour cells…
View article: Adsorption and migration of Cs and Na ions in geopolymers and zeolites
Adsorption and migration of Cs and Na ions in geopolymers and zeolites Open
Geopolymers may provide a more sustainable alternative to Portland Cement for various possible applications. Geopolymers have attracted particular interest for the immobilization of pollutants, owing to their high adsorption capacity, high…
View article: Extended BODIPYs as Red–NIR Laser Radiation Sources with Emission from 610 nm to 750 nm
Extended BODIPYs as Red–NIR Laser Radiation Sources with Emission from 610 nm to 750 nm Open
Herein, we report the synthetic access to a set of π-extended BODIPYs featuring a penta-arylated (phenyl and/or thiophene) dipyrrin framework. We take advantage of the full chemoselective control of 8-methylthio-2,3,5,6-tetrabromoBODIPY wh…
View article: 4,4′-Dicyano- versus 4,4′-Difluoro-BODIPYs in Chemoselective Postfunctionalization Reactions: Synthetic Advantages and Applications
4,4′-Dicyano- versus 4,4′-Difluoro-BODIPYs in Chemoselective Postfunctionalization Reactions: Synthetic Advantages and Applications Open
The presence of F or CN substituents at boron in BODIPYs causes a dramatic effect on their reactivity, which allows their chemoselective postfunctionalization. Thus, whereas 1,3,5,7-tetramethyl B(CN)2-BODIPYs displayed enhanced reactivity …
View article: Dissimilar-at-boron <i>N</i>-BODIPYs: from light-harvesting multichromophoric arrays to CPL-bright <i>chiral-at-boron</i> BODIPYs
Dissimilar-at-boron <i>N</i>-BODIPYs: from light-harvesting multichromophoric arrays to CPL-bright <i>chiral-at-boron</i> BODIPYs Open
Easy and direct BODIPY post-multifunctionalization without photophysics interference for the rapid design and synthesis of functional organic dyes, including forefront CPL-bright chiral-at-boron BODIPYs.
View article: Polar ammoniostyryls easily converting a clickable lipophilic BODIPY in an advanced plasma membrane probe
Polar ammoniostyryls easily converting a clickable lipophilic BODIPY in an advanced plasma membrane probe Open
A very simple, small and symmetric, but highly bright, photostable and functionalizable molecular probe for plasma membrane (PM) has been developed from an accessible, lipophilic and clickable organic dye based on BODIPY.
View article: Tuning CPL by helical pitch modulation in helically flexible small organic multichromophores
Tuning CPL by helical pitch modulation in helically flexible small organic multichromophores Open
Modulating the helical pitch by simply playing with steric effects in a series of helically flexible BODIPY dimers allows easy tuning of the luminescence dissymmetry factors associated with their circularly polarized emissions.
View article: A Revisit of the Underlying Fundamentals in the Laser Emission from BODIPYs
A Revisit of the Underlying Fundamentals in the Laser Emission from BODIPYs Open
This chapter aims to provide a comprehensive assessment of the laser performance of commercially available laser dyes based on the boron-dipyrromethene (BODIPY) chromophore in a liquid state, as well as to remark the main underlying photop…