Victor G. Young
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View article: Synthetic Routes to, Stabilities and Transformations of, and Characterization of (Carbamoyl)disulfanyl Chlorides and Related Compounds1,2
Synthetic Routes to, Stabilities and Transformations of, and Characterization of (Carbamoyl)disulfanyl Chlorides and Related Compounds1,2 Open
Previously unobserved (carbamoyl)disulfanyl chlorides were prepared by (i) addition of limiting aromatic secondary amine to (chlorocarbonyl)disulfanyl chloride; (ii) Harris reactions of sulfur dichloride with appropriate O-alkyl N-methyl-N…
View article: Over 20000-fold activation of a S = 1 Nonheme Iron(IV)Oxo Complex for C-H bond cleavage Reaction in a Tris Imidazole methylamine (TMIMA) ligand backbone
Over 20000-fold activation of a S = 1 Nonheme Iron(IV)Oxo Complex for C-H bond cleavage Reaction in a Tris Imidazole methylamine (TMIMA) ligand backbone Open
Our recent findings discovered that the spin state is not the only factor for determining the reactivity of iron oxo complexes. To shed more light on this context, we introduced the closest biomimetic Imidazole as a ligand. We have prepare…
View article: Using the MATCH procedure in Oxford University’s <i>Crystals for Windows</i> software to search for phase transitions in twins
Using the MATCH procedure in Oxford University’s <i>Crystals for Windows</i> software to search for phase transitions in twins Open
The MATCH procedure1 in Oxford University’s Crystals for Windows software2 has proven to be a useful tool to analyze pseudosymmetry within crystal structures. It will compare pairs of independent molecules, or parts within, to provide a de…
View article: A 5,000-fold increase in the HAT reactivity of a nonheme Fe <sup>IV</sup> =O complex simply by replacing two pyridines of the pentadentate N4Py ligand with pyrazoles
A 5,000-fold increase in the HAT reactivity of a nonheme Fe <sup>IV</sup> =O complex simply by replacing two pyridines of the pentadentate N4Py ligand with pyrazoles Open
A pentadentate [N5] ligand (N2Py2Pz) based on the classic N4Py ( N,N -bis(2-pyridylmethyl)- N -bis(2-pyridyl)methylamine) framework has been synthesized by replacing the two pyridylmethyl arms with corresponding ( N -methyl)pyrazolylmethyl…
View article: CCDC 2296812: Experimental Crystal Structure Determination
CCDC 2296812: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Crystal structure and synthesis of the bis(anthracene)dicuprate dianion as the dipotassium salt, [K(tetrahydrofuran)<sub>2</sub>]<sub>2</sub>[{Cu(9,10-η<sup>2</sup>-anthracene)}<sub>2</sub>], the first anionic arene complex of copper
Crystal structure and synthesis of the bis(anthracene)dicuprate dianion as the dipotassium salt, [K(tetrahydrofuran)<sub>2</sub>]<sub>2</sub>[{Cu(9,10-η<sup>2</sup>-anthracene)}<sub>2</sub>], the first anionic arene complex of copper Open
Reactions of (tricyclohexylphosphane)copper(I) chloride with two equivalents of potassium anthracene (KAn) in tetrahydrofuran (THF) at 200 K provides air-sensitive but thermally stable (at 293 K) solutions from which yellow crystalline blo…
View article: CCDC 2040508: Experimental Crystal Structure Determination
CCDC 2040508: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2105013: Experimental Crystal Structure Determination
CCDC 2105013: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2070210: Experimental Crystal Structure Determination
CCDC 2070210: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2070211: Experimental Crystal Structure Determination
CCDC 2070211: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2105012: Experimental Crystal Structure Determination
CCDC 2105012: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Electrolyte Solvation and Ionic Association: Part IX. Structures and Raman Spectroscopic Characterization of LiFSI Solvates
Electrolyte Solvation and Ionic Association: Part IX. Structures and Raman Spectroscopic Characterization of LiFSI Solvates Open
The bis(fluorosulfonyl)imide anion N(SO 2 F) 2 − (i.e., FSI − ) (also referred to as bis(fluorosulfonyl)amide (i.e., FSA − ) and imidodi(sulphuryl fluoride)) has attracted tremendous interest in recent years for its utility in both lithium…
View article: Learning from approximate periodic symmetry in organic <i>P</i>1 structures
Learning from approximate periodic symmetry in organic <i>P</i>1 structures Open
The article by Brock (2022) is the result of an ambitious 3+ year long project to study the occurrences of approximate symmetries in the space group P1.Brock selected the November 2019 version of the Cambridge Structural Database (CSD; Gro…
View article: CCDC 2076274: Experimental Crystal Structure Determination
CCDC 2076274: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2076275: Experimental Crystal Structure Determination
CCDC 2076275: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2076277: Experimental Crystal Structure Determination
CCDC 2076277: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2076276: Experimental Crystal Structure Determination
CCDC 2076276: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2092926: Experimental Crystal Structure Determination
CCDC 2092926: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2076278: Experimental Crystal Structure Determination
CCDC 2076278: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: One-electron bonds in copper–aluminum and copper–gallium complexes
One-electron bonds in copper–aluminum and copper–gallium complexes Open
Hanging on by a thread. Formally zerovalent copper complexes with an Al( iii ) or Ga( iii ) support were investigated. The combined experimental and theoretical data corroborate the presence of an odd-electron σ-bond between Cu and the Gro…
View article: Effect of Spin–Orbit Coupling on Phonon-Mediated Magnetic Relaxation in a Series of Zero-Valent Vanadium, Niobium, and Tantalum Isocyanide Complexes
Effect of Spin–Orbit Coupling on Phonon-Mediated Magnetic Relaxation in a Series of Zero-Valent Vanadium, Niobium, and Tantalum Isocyanide Complexes Open
Spin-vibronic coupling leads to spin relaxation in paramagnetic molecules, and an understanding of factors that contribute to this phenomenon is essential for designing next-generation spintronics technology, including single-molecule magn…
View article: CCDC 2034427: Experimental Crystal Structure Determination
CCDC 2034427: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Unmasking Steps in Intramolecular Aromatic Hydroxylation by a Synthetic Nonheme Oxoiron(IV) Complex
Unmasking Steps in Intramolecular Aromatic Hydroxylation by a Synthetic Nonheme Oxoiron(IV) Complex Open
In this study, a methyl group on the classic tetramethylcyclam (TMC) ligand framework is replaced with a benzylic group to form the metastable [Fe IV (O syn )(Bn3MC)] 2+ ( 2 ‐syn; Bn3MC=1‐benzyl‐4,8,11‐trimethyl‐1,4,8,11‐tetraazacyclotetra…