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View article: Machine Learning‐Based Automatic Scratch Performance Quantification on Polymeric Surfaces
Machine Learning‐Based Automatic Scratch Performance Quantification on Polymeric Surfaces Open
Quantitative scratch resistance characterization constitutes an important step in the performance evaluation of polymeric surfaces. By applying the standardized ASTM and ISO scratch test methodology, the present work discusses an approach …
View article: Evaluation of Roughening Mar Resistance of Glossy Ductile Thermoplastics
Evaluation of Roughening Mar Resistance of Glossy Ductile Thermoplastics Open
Mar is a type of subtle surface damage caused by sliding objects, visible to the human eye, and critically impacts the esthetics of polymeric surfaces. Despite its critical importance, no standardized method exists for quantifying rougheni…
View article: MoS2 Additives in Lithium Grease for Electrified Systems
MoS2 Additives in Lithium Grease for Electrified Systems Open
This study investigates the effectiveness of micron- and nano-sized molybdenum disulfide (MoS2) particles as additives in lithium (Li) grease under electrified conditions. By systematically applying electric current and high temperatures a…
View article: Effect of physical aging on scratch behavior of polycarbonate
Effect of physical aging on scratch behavior of polycarbonate Open
Physical aging refers to relaxation of the polymer glassy state toward the amorphous state and this phenomenon affects their physical‐mechanical properties. This work investigates the effect of physical aging on polymer scratch behavior an…
View article: Predicting the Processability of Polymers in a Twin-Screw Extruder: CFD Simulation and Experimental Validation
Predicting the Processability of Polymers in a Twin-Screw Extruder: CFD Simulation and Experimental Validation Open
Twin-screw extruders are widely used to manufacture various polymers for large-scale processing in the industry. However, new polymers and modified polymers that have not been manufactured before would require experiments to undergo a tria…
View article: Hydrophilized MoS2 as Lubricant Additive
Hydrophilized MoS2 as Lubricant Additive Open
Molybdenum disulfide (MoS2) has been used in a variety of lubrication products due to its highly tunable surface chemistry. However, the performance of MoS2-derived tribofilms falls short when compared to other commercially available antiw…
View article: Scratch Visibility Modeling on Flat & Textured Polymeric Surfaces
Scratch Visibility Modeling on Flat & Textured Polymeric Surfaces Open
View article: Electron-Beam Curing of Bismaleimide-Reactive Diluent Resins
Electron-Beam Curing of Bismaleimide-Reactive Diluent Resins Open
View article: Effect of surfactant type on oxygen barrier behavior of polyvinyl alcohol/α‐zirconium phosphate nanocomposites
Effect of surfactant type on oxygen barrier behavior of polyvinyl alcohol/α‐zirconium phosphate nanocomposites Open
Surfactants used to exfoliate and disperse nanoparticles are expected to have an impact on polymer nanocomposite properties. In this work, both ionic tetrabutylammonium hydroxide (TBA) and amphiphilic polyoxyalkyleneamine (M1000) surfactan…
View article: Mechanically Interlocked Vitrimer Based on Polybenzoxazine and Polyrotaxane
Mechanically Interlocked Vitrimer Based on Polybenzoxazine and Polyrotaxane Open
A mechanically interlocked vitrimer (MIV) based on a benzoxazine monomer and polyrotaxane (PR) has been prepared through a mechanically interlocked network (MIN) and dynamic covalent bond chemistry. The dynamic transacetalation exchange th…
View article: Preparation of Polyethylene/α-Zirconium Phosphate Nanocomposites via a Well-Controlled Polyethylene-Grafted Interface
Preparation of Polyethylene/α-Zirconium Phosphate Nanocomposites via a Well-Controlled Polyethylene-Grafted Interface Open
It is a daunting task to prepare polyolefin nanocomposites that contain well-exfoliated nanoplatelets due to the nonpolar and high crystallinity nature of polyolefins. In this research, a robust approach was developed to prepare polyethyle…
View article: Fracture Behavior of Polybenzoxazine Toughened by Polyrotaxane Molecules and Core–Shell Rubber
Fracture Behavior of Polybenzoxazine Toughened by Polyrotaxane Molecules and Core–Shell Rubber Open
The inherent brittleness of polybenzoxazines (PBas) makes them difficult for high-performance microelectronics and composite applications. Conventional toughening approaches are either ineffective or cause a reduction in the glass transiti…
View article: Making molecular nanotubes by cross-linking stackable rings
Making molecular nanotubes by cross-linking stackable rings Open
briefing Making molecular nanotubes by cross-linking stackable rings Discrete chiral nanotubes have been synthesized with high efficiency by connecting rimdesymmetrized macrocycles through dynamic covalent linkages.These 2-nm long and 4.7-…
View article: Effect of color on scratch and mar visibility of polymers
Effect of color on scratch and mar visibility of polymers Open
Polymer scratch mechanics has been widely studied. However, the physics behind scratch visibility is still not well understood. Scratch deformation mechanisms certainly affect visibility but also other material properties, such as roughnes…
View article: Highly Conductive and Ultra-Strong Carbon Nanotube-Copper Core-Shell Wires as High-Performance Power Transmission Cables
Highly Conductive and Ultra-Strong Carbon Nanotube-Copper Core-Shell Wires as High-Performance Power Transmission Cables Open
View article: Photopolymerized superhydrophobic hybrid coating enabled by dual-purpose tetrapodal ZnO for liquid/liquid separation
Photopolymerized superhydrophobic hybrid coating enabled by dual-purpose tetrapodal ZnO for liquid/liquid separation Open
Dual purposed ZnO tetrapods promote photopolymerization of methacrylates and provide surface roughness for superhydrophobicity. Large area photochemical fabrication of hybrid coating is demonstrated for liquid/liquid separation application…
View article: Cover Feature: Phototunable Lignin Plastics to Enable Recyclability (ChemSusChem 19/2021)
Cover Feature: Phototunable Lignin Plastics to Enable Recyclability (ChemSusChem 19/2021) Open
The Cover Feature shows that a PMMA-g-lignin-ZnO polymeric film with superior mechanical performance has been developed, where photo-degradable lignin serves as core to be cleaved by ZnO nano-catalysts and to enable the recycling of PMMA a…
View article: Fracture behavior of hybrid epoxy nanocomposites based on multi-walled carbon nanotube and core-shell rubber
Fracture behavior of hybrid epoxy nanocomposites based on multi-walled carbon nanotube and core-shell rubber Open
View article: Phototunable Lignin Plastics to Enable Recyclability
Phototunable Lignin Plastics to Enable Recyclability Open
The accumulation of non‐degradable petrochemical plastics imposes a significant threat to the environment and ecosystems. We addressed this challenge by designing a new type of phototunable plastics based on the unique lignin chemistry to …
View article: Critical challenges and advances in the carbon nanotube–metal interface for next-generation electronics
Critical challenges and advances in the carbon nanotube–metal interface for next-generation electronics Open
In this paper the major challenges of CNT–metal systems and a few of their potential applications in future electronics are reviewed.
View article: Tuning the composition and morphology of carbon nanotube-copper interface
Tuning the composition and morphology of carbon nanotube-copper interface Open
View article: Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption
Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption Open
Modulation and templating are two synthetic techniques that have garnered significant attention over the last several years for the preparation of hierarchically porous metal–organic frameworks (HP‐MOFs). In this study, by using fatty acid…
View article: Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption
Modulation versus Templating: Fine‐Tuning of Hierarchally Porous PCN‐250 Using Fatty Acids To Engineer Guest Adsorption Open
Modulation and templating are two synthetic techniques that have garnered significant attention over the last several years for the preparation of hierarchically porous metal–organic frameworks (HP‐MOFs). In this study, by using fatty acid…
View article: Scratch behavior of model epoxy resins with different crosslinking densities
Scratch behavior of model epoxy resins with different crosslinking densities Open
View article: Controlled size and high stability SiO<sub>2</sub>@ZnO QD’s with high green emission obtained by a simple colloidal route
Controlled size and high stability SiO<sub>2</sub>@ZnO QD’s with high green emission obtained by a simple colloidal route Open
In this work the synthesis of visible ZnO quantum dots (QDs) functionalized/stabilized with oleic acid and core-shelled with SiO 2 is presented. A colloidal route was followed to synthesize ZnO QDs with 5 nm average size. Several character…
View article: Non‐Solvent Fractionation of Lignin Enhances Carbon Fiber Performance
Non‐Solvent Fractionation of Lignin Enhances Carbon Fiber Performance Open
Even though lignin carbon fiber has been sought after for several decades, the poor mechanical performance remains to be a major barrier for commercial applications. The low mechanical performance is attributed to the heterogeneity of lign…
View article: Synthesis of Oxidation-Resistant Electrochemical-Active Copper Nanowires\n Using Phenylenediamine Isomers
Synthesis of Oxidation-Resistant Electrochemical-Active Copper Nanowires\n Using Phenylenediamine Isomers Open
Phenylenediamine (PDA) was chosen as a coordinating, reducing, and capping\nagent to effectively direct growth and protect against oxidation of Cu\nnanowires (Cu NWs) in an aqueous solution. PDA was found to reduce Cu (II) to\nCu (I) at ro…
View article: Synthesis of Oxidation-Resistant Electrochemical-Active Copper Nanowires Using Phenylenediamine Isomers
Synthesis of Oxidation-Resistant Electrochemical-Active Copper Nanowires Using Phenylenediamine Isomers Open
Phenylenediamine (PDA) was chosen as a coordinating, reducing, and capping agent to effectively direct growth and protect against oxidation of Cu nanowires (Cu NWs) in an aqueous solution. PDA was found to reduce Cu (II) to Cu (I) at room …
View article: Synthesis of oxidation-resistant electrochemical-active copper nanowires using phenylenediamine isomers
Synthesis of oxidation-resistant electrochemical-active copper nanowires using phenylenediamine isomers Open
Phenylenediamine (PDA) was chosen as a coordinating, reducing, and capping agent to effectively direct growth and protect against oxidation of Cu nanowires (Cu NWs) in an aqueous solution. PDA was found to reduce Cu (II) to Cu (I) at room …
View article: Carbon nanotube-copper fibers produced by electrospinning: electrical conductivity measurements
Carbon nanotube-copper fibers produced by electrospinning: electrical conductivity measurements Open
Recent advances in nanotechnology have provided new materials which have the potential to surpass copper and aluminum alloys in electrical conductivity, weight and ampacity [2-6]. Among these carbon nanotubes (CNTs) stand out due to their …