Xinjun Luan
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View article: Trifunctionalization of Iodoarenes via Sequence‐Controlled Double <i>Ortho</i> C─H Acylations by Palladium/Norbornene Catalysis
Trifunctionalization of Iodoarenes via Sequence‐Controlled Double <i>Ortho</i> C─H Acylations by Palladium/Norbornene Catalysis Open
Herein we report a novel palladium/norbornene‐catalyzed trifunctionalization reaction of ortho ‐unsubstituted iodoarenes by incorporating two distinct acyl groups at their ortho C─H positions and replacing the ipso ‐iodide with an alkenyl …
View article: Trifunctionalization of Iodoarenes via Sequence‐Controlled Double <i>Ortho</i> C─H Acylations by Palladium/Norbornene Catalysis
Trifunctionalization of Iodoarenes via Sequence‐Controlled Double <i>Ortho</i> C─H Acylations by Palladium/Norbornene Catalysis Open
Herein we report a novel palladium/norbornene‐catalyzed trifunctionalization reaction of ortho ‐unsubstituted iodoarenes by incorporating two distinct acyl groups at their ortho C─H positions and replacing the ipso ‐iodide with an alkenyl …
View article: Cooperative Photoredox and Cobalt‐Catalyzed Acceptorless Dehydrogenative Functionalization of Cyclopropylamides towards Allylic <i>N,O</i>‐Acyl‐acetal Derivatives
Cooperative Photoredox and Cobalt‐Catalyzed Acceptorless Dehydrogenative Functionalization of Cyclopropylamides towards Allylic <i>N,O</i>‐Acyl‐acetal Derivatives Open
We disclose herein a novel photoredox and cobalt co‐catalyzed ring‐opening/acceptorless dehydrogenative functionalization of mono‐donor cyclopropanes. This sustainable and atom‐economic approach allows the rapid assembly of a wide range of…
View article: CCDC 2256585: Experimental Crystal Structure Determination
CCDC 2256585: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2256584: Experimental Crystal Structure Determination
CCDC 2256584: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2256586: Experimental Crystal Structure Determination
CCDC 2256586: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2216790: Experimental Crystal Structure Determination
CCDC 2216790: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2216760: Experimental Crystal Structure Determination
CCDC 2216760: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2220120: Experimental Crystal Structure Determination
CCDC 2220120: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: In(OTf)<sub>3</sub>-catalyzed reorganization/cycloaddition of two imine units and subsequent modular assembly of acridinium photocatalysts
In(OTf)<sub>3</sub>-catalyzed reorganization/cycloaddition of two imine units and subsequent modular assembly of acridinium photocatalysts Open
Herein, we disclose a novel reorganization/cycloaddition between two imine units catalyzed by In(OTf) 3 Lewis acid that differs from the well-known [4 + 2] cycloaddition version via the Povarov reaction.
View article: Mechanochromic, thermoresponsive and triboluminescence behaviors of one divinyl thioxanthene based AIE luminogen with variable conformations
Mechanochromic, thermoresponsive and triboluminescence behaviors of one divinyl thioxanthene based AIE luminogen with variable conformations Open
A conformation variable thioxanthene chromophore was employed for the first time to construct a muti-stimuli-responsive luminescent material, which generates three polymorphs with distinct mechano-, thermochromic and triboluminescence beha…
View article: In(OTf)3-Catalyzed Reorganization/Cycloaddition of Two Imine Units and Subsequently Modular Assembly of Acridinium Photocatalysts
In(OTf)3-Catalyzed Reorganization/Cycloaddition of Two Imine Units and Subsequently Modular Assembly of Acridinium Photocatalysts Open
Reorganization of unsaturated chemical bonds is one of the most promising strategies to generate architecturally diversified and innovative molecular library. Herein, we disclose a novel reorganization/cycloaddition between two imine units…
View article: CCDC 1977832: Experimental Crystal Structure Determination
CCDC 1977832: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2061877: Experimental Crystal Structure Determination
CCDC 2061877: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2061878: Experimental Crystal Structure Determination
CCDC 2061878: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1852643: Experimental Crystal Structure Determination
CCDC 1852643: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1852644: Experimental Crystal Structure Determination
CCDC 1852644: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Catalytic Asymmetric [4+1] Spiroannulation of α-Bromo-β-Naphthols with Azoalkenes by an Electrophilic Dearomatization/S <sub>RN</sub> 1-Debromination Approach
Catalytic Asymmetric [4+1] Spiroannulation of α-Bromo-β-Naphthols with Azoalkenes by an Electrophilic Dearomatization/S <sub>RN</sub> 1-Debromination Approach Open
Open AccessCCS ChemistryRESEARCH ARTICLE1 Mar 2022Catalytic Asymmetric [4+1] Spiroannulation of α-Bromo-β-Naphthols with Azoalkenes by an Electrophilic Dearomatization/SRN1-Debromination Approach Lu Bai†, Xin Luo†, Yicong Ge, Hui Wang, Jin…
View article: Palladium-Catalyzed Enantioselective Heteroarenyne Cycloisomerization Reaction
Palladium-Catalyzed Enantioselective Heteroarenyne Cycloisomerization Reaction Open
自然界中许多光学活性分子都含有高度官能化的碳环和杂环.这些重要的结构特征, 往往是分子具有生 物活性和特定功能所必需的, 为此合成化学家一直在寻 找有效的方法来合成这些化合物 [1] .1,n-烯炔的 ene 型环 异构化反应能直接、有效地合成环状 1,4-二烯分子 (Scheme 1) [2] .此类方法是利用一些简单易得的底物制 备一些具有复杂结构的环状化合物.具有原子经济性 高, 对环境友好的特点, 已成为了一种极具吸引力的合 成方法.自 1985 年 Trost 等…