Min Shi
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View article: Palladium-catalyzed asymmetric dearomative [2π+2σ] cycloadditions of indoles with bicyclobutanes
Palladium-catalyzed asymmetric dearomative [2π+2σ] cycloadditions of indoles with bicyclobutanes Open
View article: G-companions on algebraic stacks and applications to canonical $\ell$-adic local systems on Shimura stacks
G-companions on algebraic stacks and applications to canonical $\ell$-adic local systems on Shimura stacks Open
Cases of Deligne's companion conjecture for normal schemes over finite fields have been proven by L. Lafforgue, Drinfeld, and Zheng in recent years: L. Lafforgue proved the conjecture for curves, Drinfeld proved the conjecture for all smoo…
View article: Thermally Induced Intramolecular Diels–Alder Reaction of Furan-Tethered Methylenecyclopropanes
Thermally Induced Intramolecular Diels–Alder Reaction of Furan-Tethered Methylenecyclopropanes Open
The substantial ring strain and activated double bonds render methylenecyclopropanes (MCPs) potential substrates for Diels–Alder (DA) reactions. In this work, we present a thermally induced intramolecular Diels–Alder (IMDA) reaction utiliz…
View article: A new typical cavefish of the genus Triplophysa (Teleostei, Cypriniformes, Nemacheilidae) from the Jinsha River, Yunnan, China
A new typical cavefish of the genus Triplophysa (Teleostei, Cypriniformes, Nemacheilidae) from the Jinsha River, Yunnan, China Open
Triplophysa baishuijiangensis sp. nov. , a new cave-dwelling loach, was collected from an underground river outlet in Xiaoganxi Village, Yiliang County, Yunnan Province, China, situated within the core area of the Baishuijiang National Aqu…
View article: Variation in Leaf C, N, and P Stoichiometric Characteristics of Populus euphratica Communities in a Desert Riparian Ecosystem of Northwest China
Variation in Leaf C, N, and P Stoichiometric Characteristics of Populus euphratica Communities in a Desert Riparian Ecosystem of Northwest China Open
Despite extensive research on how climate and environmental factors influence leaf stoichiometry at national and global scales, experimental evidence on their effects at the community level remains limited, particularly in extremely arid r…
View article: DFT Study of the Possible Mechanisms for Synthesizing <i>α</i>‐Cyanophosphonates from <i>β</i>‐Nitrostyrenes
DFT Study of the Possible Mechanisms for Synthesizing <i>α</i>‐Cyanophosphonates from <i>β</i>‐Nitrostyrenes Open
In this report, the reaction mechanism of triphenylphosphite addition to β ‐nitrostyrene is theoretically investigated. The M062X method, a subset of density functional theory (DFT), and the def2svp basis set are used to determine the appr…
View article: A Divergent Synthesis of Spiroindenes via Ligand‐Controlled [3+2]/[4+2] Cycloadditions of Zwitterionic π‐Propargyl Palladium Species with Benzofulvenes
A Divergent Synthesis of Spiroindenes via Ligand‐Controlled [3+2]/[4+2] Cycloadditions of Zwitterionic π‐Propargyl Palladium Species with Benzofulvenes Open
Comprehensive Summary A divergent synthesis of spiroindenes through a palladium catalyzed cycloaddition between zwitterionic π‐propargyl palladium species and benzofulvenes in moderate to good yields has been disclosed along with good func…
View article: A photocatalytic acylation of alkenes enabled by three-component oxidative difunctionalization and its applications in nature product synthesis
A photocatalytic acylation of alkenes enabled by three-component oxidative difunctionalization and its applications in nature product synthesis Open
View article: Role of Onboard Carbon Capture and Storage System in remedial units balancing under the IMO Net-Zero Framework: GFI methodology and 4E analyses
Role of Onboard Carbon Capture and Storage System in remedial units balancing under the IMO Net-Zero Framework: GFI methodology and 4E analyses Open
View article: A Motif-Based Deep Learning Tool for the Identification of Unusual NADH-Dependent Imine Reductases
A Motif-Based Deep Learning Tool for the Identification of Unusual NADH-Dependent Imine Reductases Open
View article: Contributions of Onboard Carbon Capture and Storage system under the GHG Fuel Intensity methodology: Remedial units and 4E analyses
Contributions of Onboard Carbon Capture and Storage system under the GHG Fuel Intensity methodology: Remedial units and 4E analyses Open
View article: Theoretical Studies on the Reaction Mechanism for the Cycloaddition of Zwitterionic π-Allenyl Palladium Species: Substrate-Controlled Isomerization
Theoretical Studies on the Reaction Mechanism for the Cycloaddition of Zwitterionic π-Allenyl Palladium Species: Substrate-Controlled Isomerization Open
Zwitterionic π-allenyl palladium species are newly developed intermediates. A substrate-controlled step existed in the cycloaddition of zwitterionic π-allenyl palladium species with tropsulfimides or tropones. With the assistance of previo…
View article: The regioselectivity in the gold-catalyzed cycloisomerization of alcohols: A full DFT study on carbene versus non-carbene mechanisms
The regioselectivity in the gold-catalyzed cycloisomerization of alcohols: A full DFT study on carbene versus non-carbene mechanisms Open
The mechanistic study of in the gold-catalyzed cycloisomerization of alcohols or amine tethered-vinylidenecyclopropanes has been performed using high-level DFT calculations to find the reasons of the observed selectivity of the products. T…
View article: An Engineered Imine Reductase for Highly Diastereo‐ and Enantioselective Synthesis of β‐Branched Amines with Contiguous Stereocenters
An Engineered Imine Reductase for Highly Diastereo‐ and Enantioselective Synthesis of β‐Branched Amines with Contiguous Stereocenters Open
β‐Branched chiral amines with contiguous stereocenters are valuable building blocks for preparing various biologically active molecules. However, their asymmetric synthesis remains challenging. Herein, we report a highly diastereo‐ and ena…
View article: Correlation between Discharge Noise and Flow Field Characteristics of Hydraulic Turbine
Correlation between Discharge Noise and Flow Field Characteristics of Hydraulic Turbine Open
The water flow within the turbine passage of a hydropower station exhibits high-speed closed-pressure flow. The flow field characteristics will directly affect the turbine’s operational efficiency and safety. To ensure the safe operation o…
View article: An engineered imine reductase for highly diastereo- and enantioselective synthesis of β-branched amines with contiguous stereocenters
An engineered imine reductase for highly diastereo- and enantioselective synthesis of β-branched amines with contiguous stereocenters Open
βBranched chiral amines with contiguous stereocenters are valuable building blocks for preparing various biologically active molecules. However, their asymmetric synthesis remains challenging. Herein, we report a highly diastereo- and enan…
View article: Mechanistic studies on rhodium-catalyzed chemo-selective cy-cloaddition of ene-vinylidenecyclopropanes: water-assisted proton transfer
Mechanistic studies on rhodium-catalyzed chemo-selective cy-cloaddition of ene-vinylidenecyclopropanes: water-assisted proton transfer Open
Rhodium-catalyzed cycloaddition reactions are a powerful tool for the construction of polycyclic compounds. Experimental combined with DFT studies were used to investigate the temperature-controlled chemoselectivity of cationic rhodium-cat…
View article: Mechanistic Studies on Rhodium-Catalyzed Chemoselective Cycloaddition of Ene-Vinylidenecyclopropanes: Water-Assisted Proton Transfer
Mechanistic Studies on Rhodium-Catalyzed Chemoselective Cycloaddition of Ene-Vinylidenecyclopropanes: Water-Assisted Proton Transfer Open
Rhodium-catalyzed cycloaddition reactions are a powerful tool for the construction of polycyclic compounds. Combined experimental and DFT studies were used to investigate the temperature-controlled chemoselectivity of cationic rhodium-cata…
View article: Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors
Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors Open
Combined experimental and quantum-chemical studies were used to characterise the philicity/fugality features of tertiary phosphines and Michael acceptors in phospha-Michael reactions, which are key steps in phosphine-catalysed organic reac…
View article: Palladium-catalyzed selective C–C bond cleavage of keto-vinylidenecyclopropanes: construction of structurally rich dihydrofurans and tetrahydrofurans
Palladium-catalyzed selective C–C bond cleavage of keto-vinylidenecyclopropanes: construction of structurally rich dihydrofurans and tetrahydrofurans Open
A series of bicyclic products containing dihydrofuran and tetrahydrofuran skeletons were obtained by divergent palladium-catalyzed selective C–C bond cleavage of keto-VDCPs. The reaction mechanism was also investigated systematically.
View article: Iodine radical mediated cascade [3 + 2] carbocyclization of ene-vinylidenecyclopropanes with thiols and selenols <i>via</i> photoredox catalysis
Iodine radical mediated cascade [3 + 2] carbocyclization of ene-vinylidenecyclopropanes with thiols and selenols <i>via</i> photoredox catalysis Open
A iodine radical mediated cascade [3 + 2] carbocyclization of ene-vinylidenecyclopropanes with thiols and selenols to provide sulfur- or selenium-containing derivatives has been disclosed.
View article: Ultra-High Cross-Linked Active Ester-Cured Epoxy Resins: Side Group Cross-Linking for Performance Enhancement
Ultra-High Cross-Linked Active Ester-Cured Epoxy Resins: Side Group Cross-Linking for Performance Enhancement Open
View article: CCDC 2220231: Experimental Crystal Structure Determination
CCDC 2220231: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2083431: Experimental Crystal Structure Determination
CCDC 2083431: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2142800: Experimental Crystal Structure Determination
CCDC 2142800: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synergistic Visible Light Photocatalysis with Organocatalysis
Synergistic Visible Light Photocatalysis with Organocatalysis Open
In recent years, the strategy of merging visible light photocatalysis and organocatalysis has been utilized and applied in a wide range of reactions. Taking advantage of synergistic visible light photocatalysis with organocatalysis, remark…
View article: Data Supplement from A Novel KLF4/LDHA Signaling Pathway Regulates Aerobic Glycolysis in and Progression of Pancreatic Cancer
Data Supplement from A Novel KLF4/LDHA Signaling Pathway Regulates Aerobic Glycolysis in and Progression of Pancreatic Cancer Open
Supplementary Figures 1-5 Legends
View article: Data from A Novel KLF4/LDHA Signaling Pathway Regulates Aerobic Glycolysis in and Progression of Pancreatic Cancer
Data from A Novel KLF4/LDHA Signaling Pathway Regulates Aerobic Glycolysis in and Progression of Pancreatic Cancer Open
Purpose: Krüppel-like factor 4 (KLF4) is a transcription factor and putative tumor suppressor. However, little is known about its effect on aerobic glycolysis in pancreatic tumors. Therefore, we investigated the clinical significanc…
View article: Data from A Novel KLF4/LDHA Signaling Pathway Regulates Aerobic Glycolysis in and Progression of Pancreatic Cancer
Data from A Novel KLF4/LDHA Signaling Pathway Regulates Aerobic Glycolysis in and Progression of Pancreatic Cancer Open
Purpose: Krüppel-like factor 4 (KLF4) is a transcription factor and putative tumor suppressor. However, little is known about its effect on aerobic glycolysis in pancreatic tumors. Therefore, we investigated the clinical significanc…
View article: CCDC 2178226: Experimental Crystal Structure Determination
CCDC 2178226: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …