Junkuo Gao
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View article: Synthesis of <scp>IPDI</scp>@<scp>PU</scp> Microcapsule Curing Agent and Its Curing Behavior for Epoxy Resin
Synthesis of <span>IPDI</span>@<span>PU</span> Microcapsule Curing Agent and Its Curing Behavior for Epoxy Resin Open
The development of latent curing agents is essential for advancements in industrial applications. In this study, we synthesize the IPDI@PU microcapsule curing agent with a regular spherical morphology and a uniform size distribution throug…
View article: Shaping the future of solar-driven photocatalysis by reticular framework materials
Shaping the future of solar-driven photocatalysis by reticular framework materials Open
View article: Synthesis, X‐ray Structure Investigation, Hirshfeld Surface Analysis and Theoretical Calculations of Metal Complexes on the Base of 2‐Aminobenzoxazole
Synthesis, X‐ray Structure Investigation, Hirshfeld Surface Analysis and Theoretical Calculations of Metal Complexes on the Base of 2‐Aminobenzoxazole Open
The mixed‐ligand complexes of Co, Cu, and Cd with 2‐aminobenzoxazole (2AB) and Cl (complex 1 ), 2AB and acetic acid (complex 2 ), as well as 2AB and iodine (complex 3 ) have been synthesized, and their X‐ray structures are determined. In a…
View article: Synergistic chaotropic effect and defect engineering promoting ultrahigh ionic conductivity in MOFs
Synergistic chaotropic effect and defect engineering promoting ultrahigh ionic conductivity in MOFs Open
This study presents a high-performance ionic conductor engineered through a synergistic chaotropic effect and defective structure using a solvent-free approach.
View article: Recent strategies to improve the electroactivity of metal–organic frameworks for advanced electrocatalysis
Recent strategies to improve the electroactivity of metal–organic frameworks for advanced electrocatalysis Open
Metal–organic frameworks (MOFs) have emerged as promising materials in the realm of electrocatalysis due to their high surface area, tunable porosity, and versatile chemical functionality. However, their practical application has been hamp…
View article: Constructing FeNiPt@C Trifunctional Catalyst by High Spin‐Induced Water Oxidation Activity for Zn‐Air Battery and Anion Exchange Membrane Water Electrolyzer
Constructing FeNiPt@C Trifunctional Catalyst by High Spin‐Induced Water Oxidation Activity for Zn‐Air Battery and Anion Exchange Membrane Water Electrolyzer Open
Developing cost‐efficient trifunctional catalysts capable of facilitating hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR) activity is essential for the progression of energy devices. …
View article: A Solid-State Transformation of Hydrogen-Bonded Organic Frameworks for Efficient Acetylene Storage and Gas Separation
A Solid-State Transformation of Hydrogen-Bonded Organic Frameworks for Efficient Acetylene Storage and Gas Separation Open
Developing robust microporous hydrogen-bonded organic frameworks (HOFs) is crucial for exploring novel physical adsorbents and revealing the structure-property relationship of hydrogen-bonding pairing behaviors. However, it is still challe…
View article: Long Storage Period Achieved by Zif-8 as the Second-Layer Shell Material for Microcapsule-Type Curing Agent
Long Storage Period Achieved by Zif-8 as the Second-Layer Shell Material for Microcapsule-Type Curing Agent Open
View article: Long Storage Period Achieved by Zif-8 as the Second-Layer Shell Material for Microcapsule-Type Curing Agent
Long Storage Period Achieved by Zif-8 as the Second-Layer Shell Material for Microcapsule-Type Curing Agent Open
View article: Hfs 2 /Bn Heterostructures: A Repeatable Detectable Water Sensing Material
Hfs 2 /Bn Heterostructures: A Repeatable Detectable Water Sensing Material Open
View article: Unveiling the Enhanced Hydrogen Evolution Performance of Trimetallic Co-Y-Mo Hydroxides: Interface Synergistic Effect
Unveiling the Enhanced Hydrogen Evolution Performance of Trimetallic Co-Y-Mo Hydroxides: Interface Synergistic Effect Open
View article: Fabrication of Highly Porous MOF/Cellulose Beads for Sustained Degradation of Dye
Fabrication of Highly Porous MOF/Cellulose Beads for Sustained Degradation of Dye Open
Metal-organic frameworks (MOFs) have received widespread attention in recent years. However, the powder form of MOFs limits their large-scale applications. To facilitate the application of MOFs, mass production and shaped manufacturing of …
View article: In Situ Growth of Ti3C2/UiO-66-NH2 Composites for Photoreduction of Cr(VI)
In Situ Growth of Ti3C2/UiO-66-NH2 Composites for Photoreduction of Cr(VI) Open
Cr(VI) is one of the most toxic heavy metals, posing multiple threats to humans and ecosystems. Photoreduction of toxic Cr(VI) to para-toxic Cr(III) is one of the most effective ways to remove heavy metal chromium but is still challenging.…
View article: N-Doping of Β-Ketoenamine Based Covalent Organic Frameworks for Catalytic Conversion of Co2 to Cyclic Carbonate and Knoevenagel Condensation
N-Doping of Β-Ketoenamine Based Covalent Organic Frameworks for Catalytic Conversion of Co2 to Cyclic Carbonate and Knoevenagel Condensation Open
View article: Multi-Responsive Sensor Based on Porous Hydrogen-Bonded Organic Frameworks for Selective Sensing of Ions and Dopamine Molecules
Multi-Responsive Sensor Based on Porous Hydrogen-Bonded Organic Frameworks for Selective Sensing of Ions and Dopamine Molecules Open
Hydrogen-bonded organic frameworks (HOFs), as an emerging porous material, have attracted increasing research interest in fluorescence sensing due to their inherent fluorescence emission units with unique physicochemical properties. Herein…
View article: Postsynthetic Modification of NU-1000 for Designing a Polyoxometalate-Containing Nanocomposite with Enhanced Third-Order Nonlinear Optical Performance
Postsynthetic Modification of NU-1000 for Designing a Polyoxometalate-Containing Nanocomposite with Enhanced Third-Order Nonlinear Optical Performance Open
For the advancement of laser technologies and optical engineering, various types of new inorganic and organic materials are emerging. Metal-organic frameworks (MOFs) reveal a promising use in nonlinear optics, given the presence of organic…
View article: Recent advances of metal–organic frameworks‐based proton exchange membranes in fuel cell applications
Recent advances of metal–organic frameworks‐based proton exchange membranes in fuel cell applications Open
In recent years, proton exchange membrane (PEM) fuel cell (FC; PEMFC) has been widely studied and gradually applied to vehicle power supply, portable supply, communication base station backup, emergency power supply, and so on. Especially …
View article: >Recent advances of metal–organic frameworks‐based proton exchange membranes in fuel cell applications
>Recent advances of metal–organic frameworks‐based proton exchange membranes in fuel cell applications Open
Metal–organic frameworks (MOFs) composed of metal ions/clusters and organic ligands have attracted extensive attention in the field of proton conduction. The hybrid membranes formed by MOFs and polymers show excellent performances and desi…
View article: Tuning the electronic structure of a metal–organic framework for an efficient oxygen evolution reaction by introducing minor atomically dispersed ruthenium
Tuning the electronic structure of a metal–organic framework for an efficient oxygen evolution reaction by introducing minor atomically dispersed ruthenium Open
The establishment of efficient oxygen evolution electrocatalysts is of great value but also challenging. Herein, a durable metal–organic framework (MOF) with minor atomically dispersed ruthenium and an optimized electronic structure is con…
View article: Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis
Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis Open
The 2D nanosheets of metal–organic frameworks (MOFs) have recently emerged as a promising material that makes them valuable in widespread electrocatalytic fields due to their atomic‐level thickness, abundant active sites, and large surface…
View article: Achievements and Perspectives in Metal–Organic Framework-Based Materials for Photocatalytic Nitrogen Reduction
Achievements and Perspectives in Metal–Organic Framework-Based Materials for Photocatalytic Nitrogen Reduction Open
Metal–organic frameworks (MOFs) are coordination polymers with high porosity that are constructed from molecular engineering. Constructing MOFs as photocatalysts for the reduction of nitrogen to ammonia is a newly emerging but fast-growing…
View article: Amino-Functionalized Titanium Based Metal-Organic Framework for Photocatalytic Hydrogen Production
Amino-Functionalized Titanium Based Metal-Organic Framework for Photocatalytic Hydrogen Production Open
Photocatalytic hydrogen production using stable metal-organic frameworks (MOFs), especially the titanium-based MOFs (Ti-MOFs) as photocatalysts is one of the most promising solutions to solve the energy crisis. However, due to the high rea…
View article: A Zr-MOF nanoflower sensor and its mixed-matrix membrane for the highly sensitive detection of nitroaromatics
A Zr-MOF nanoflower sensor and its mixed-matrix membrane for the highly sensitive detection of nitroaromatics Open
A nanoflower-like Zr metal–organic framework CJLU-1 with a 2D layered porous structure and its mixed-matrix membrane were realized as a novel sensing platform for the detection of nitroaromatics in the ppb range.
View article: Oxygen Ether Chain Containing Imine-Based Covalent Organic Frameworks: Synthesis, Characterization, Optical Properties and Water Detection
Oxygen Ether Chain Containing Imine-Based Covalent Organic Frameworks: Synthesis, Characterization, Optical Properties and Water Detection Open
View article: Regulating the coordination environment of a metal–organic framework for an efficient electrocatalytic oxygen evolution reaction
Regulating the coordination environment of a metal–organic framework for an efficient electrocatalytic oxygen evolution reaction Open
A novel metal–organic framework (MOF) with efficient OER electrocatalytic performance (defined as FeCo-L 1 L 2 ) was successfully synthesized.
View article: Recent progress in 2D metal-organic framework photocatalysts: synthesis, photocatalytic mechanism and applications
Recent progress in 2D metal-organic framework photocatalysts: synthesis, photocatalytic mechanism and applications Open
2D metal-organic framework (2D MOF) nanosheets and their derived nanocomposites have been widely studied in recent years due to their ultrathin atomic-level thickness, large surface area and adjustable structure. This review is thus aimed …
View article: Advances in metal–organic frameworks and their derivatives for diverse electrocatalytic applications
Advances in metal–organic frameworks and their derivatives for diverse electrocatalytic applications Open
Oxygen evolution reaction (OER), hydrogen evolution reaction (HER), oxygen reduction reaction (ORR), nitrogen reduction reaction (NRR), and carbon dioxide reduction reaction (CO2RR) are five major reactions in the progress, conversion, and…
View article: Metal–Organic Frameworks for Photo/Electrocatalysis
Metal–Organic Frameworks for Photo/Electrocatalysis Open
Metal–organic frameworks (MOFs), constructed from metal clusters/ions and organic ligands, are ideal materials for photo/electrocatalysis, mainly due to the advantages of large surface areas, high porosity, and easily tunable optical and e…
View article: Recent advances in vacancy engineering of metal‐organic frameworks and their derivatives for electrocatalysis
Recent advances in vacancy engineering of metal‐organic frameworks and their derivatives for electrocatalysis Open
The efficient electrocatalysis plays the key role in the development of electrochemical energy conversion technologies to alleviate energy crisis. Given their multiple active sites and large specific surface areas as electrocatalysts, meta…
View article: Mixed Metal–Organic Framework with Multiple Binding Sites for Efficient C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub>Separation
Mixed Metal–Organic Framework with Multiple Binding Sites for Efficient C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub>Separation Open
The separation of C 2 H 2 /CO 2 is particularly challenging owing to their similarities in physical properties and molecular sizes. Reported here is a mixed metal–organic framework (M′MOF), [Fe(pyz)Ni(CN) 4 ] ( FeNi‐M′MOF , pyz=pyrazine), …