Justin L. Andrews
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View article: Substoichiometry in the Ba-Cu and Ba-Cu-O phase diagrams
Substoichiometry in the Ba-Cu and Ba-Cu-O phase diagrams Open
Electrides, which are a unique class of materials featuring anionic electrons (i.e., Farbe centers) localized at discrete crystallographic sites, provide an ideal platform for systematically investigating electron correlation. These compou…
View article: Photocatalytic hydrogen evolution mechanisms mediated by stereoactive lone pairs of Sb2VO5 in quantum dot heterostructures
Photocatalytic hydrogen evolution mechanisms mediated by stereoactive lone pairs of Sb2VO5 in quantum dot heterostructures Open
View article: CCDC 2295993: Experimental Crystal Structure Determination
CCDC 2295993: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A Solid Zn-Ion Conductor from an All-Zinc Metal–Organic Framework Replete with Mobile Zn<sup>2+</sup> Cations
A Solid Zn-Ion Conductor from an All-Zinc Metal–Organic Framework Replete with Mobile Zn<sup>2+</sup> Cations Open
We describe the synthesis and properties of Zn3[(Zn4Cl)3(BTT)8]2 (ZnZnBTT, BTT3- = 1,3,5-benzenetristetrazolate), a heretofore unknown member of a well-known, extensive fami…
View article: Toggling Stereochemical Activity through Interstitial Positioning of Cations between 2D V<sub>2</sub>O<sub>5</sub> Double Layers
Toggling Stereochemical Activity through Interstitial Positioning of Cations between 2D V<sub>2</sub>O<sub>5</sub> Double Layers Open
The 5/6s2 lone-pair electrons of p-block cations in their lower oxidation states are a versatile electronic and geometric structure motif that can underpin lattice anharmonicity and often engender electronic and structural insta…
View article: CSD 2257899: Experimental Crystal Structure Determination
CSD 2257899: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2212079: Experimental Crystal Structure Determination
CSD 2212079: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Effect of Stereochemically Active Electron Lone Pairs on Magnetic Ordering in Trivanadates
Effect of Stereochemically Active Electron Lone Pairs on Magnetic Ordering in Trivanadates Open
Stereoactive electron lone pairs derived from filled 5/6s2 states of p-block cations are an intriguing electronic and geometric structure motif that have been exploited for diverse applications such as thermoelectrics, thermochr…
View article: CSD 2215726: Experimental Crystal Structure Determination
CSD 2215726: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Festkörper‐Analyse, Speicherung und Trennung von Pyrophorem PH<sub>3</sub> und P<sub>2</sub>H<sub>4</sub> mit α‐Mg Formiat
Festkörper‐Analyse, Speicherung und Trennung von Pyrophorem PH<sub>3</sub> und P<sub>2</sub>H<sub>4</sub> mit α‐Mg Formiat Open
Phosphan, PH 3 – ein hochpyrophores und toxisches Gas – ist gewöhnlich mit H 2 und P 2 H 4 kontaminiert, was seine Handhabung gefährlich macht. Die kostengünstige metallorganische Gerüstverbindung (MOF) aus Magnesiumformiat, α‐[Mg(O 2 CH) …
View article: Solid‐State Investigation, Storage, and Separation of Pyrophoric PH<sub>3</sub> and P<sub>2</sub>H<sub>4</sub> with α‐Mg Formate
Solid‐State Investigation, Storage, and Separation of Pyrophoric PH<sub>3</sub> and P<sub>2</sub>H<sub>4</sub> with α‐Mg Formate Open
Phosphane, PH 3 —a highly pyrophoric and toxic gas—is frequently contaminated with H 2 and P 2 H 4 , which makes its handling even more dangerous. The inexpensive metal–organic framework (MOF) magnesium formate, α‐[Mg(O 2 CH) 2 ], can adso…
View article: Data science enables X-ray vision
Data science enables X-ray vision Open
View article: Multivariate hyperspectral data analytics across length scales to probe compositional, phase, and strain heterogeneities in electrode materials
Multivariate hyperspectral data analytics across length scales to probe compositional, phase, and strain heterogeneities in electrode materials Open
View article: CSD 2154907: Experimental Crystal Structure Determination
CSD 2154907: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2154908: Experimental Crystal Structure Determination
CSD 2154908: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CCDC 2209895: Experimental Crystal Structure Determination
CCDC 2209895: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit
Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit Open
We report a metal–organic framework (MOF) with a rare two‐dimensional (2D) secondary building unit (SBU). The SBU comprises mixed‐valent Fe 2+ and Fe 3+ metal ions bridged by oxygen atoms pertaining to the polytopic ligand 3,3′,4,4′,5,5′‐h…
View article: Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit
Pyrogallate‐Based Metal‐Organic Framework with a Two‐Dimensional Secondary Building Unit Open
We report a metal–organic framework (MOF) with a rare two‐dimensional (2D) secondary building unit (SBU). The SBU comprises mixed‐valent Fe 2+ and Fe 3+ metal ions bridged by oxygen atoms pertaining to the polytopic ligand 3,3′,4,4′,5,5′‐h…
View article: Teaching Metal-Organic Frameworks to Conduct: Ion and Electron Transport in Metal-Organic Frameworks
Teaching Metal-Organic Frameworks to Conduct: Ion and Electron Transport in Metal-Organic Frameworks Open
Metal-organic frameworks (MOFs) are an expansive class of extended solids formed by coordination bonding between metal ions/clusters and organic ligands. Although MOFs are best known for their intrinsic porosity, they are now also emerging…
View article: Lone but Not Alone: Precise Positioning of Lone Pairs for the Design of Photocatalytic Architectures
Lone but Not Alone: Precise Positioning of Lone Pairs for the Design of Photocatalytic Architectures Open
With current economic growth and consumption trends projected to bring about a precipitous and rapid rise of the global temperature, the world stands at a crossroads with regards to climate change. The rate at which greenhouse gas emission…
View article: CSD 2084510: Experimental Crystal Structure Determination
CSD 2084510: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2084509: Experimental Crystal Structure Determination
CSD 2084509: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2084513: Experimental Crystal Structure Determination
CSD 2084513: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2084512: Experimental Crystal Structure Determination
CSD 2084512: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2084511: Experimental Crystal Structure Determination
CSD 2084511: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Topochemical stabilization and single-crystal transformations of a metastable 2D γʹ-V2O5 intercalation cathode
Topochemical stabilization and single-crystal transformations of a metastable 2D γʹ-V2O5 intercalation cathode Open
The atomistic design of positive electrode materials requires understanding of (1) how guest cations diffuse through an intercalation host to fill empty interstices and (2) the distortions of the host lattice induced as a result of ion int…
View article: Lessons learned from FeSb2O4 on stereoactive lone pairs as a design principle for anion insertion
Lessons learned from FeSb2O4 on stereoactive lone pairs as a design principle for anion insertion Open
View article: Does Water Enhance Mg Intercalation in Oxides? The Case of a Tunnel Framework
Does Water Enhance Mg Intercalation in Oxides? The Case of a Tunnel Framework Open
The presence of H2O has been linked to enhancements in the reactivity of cathodes for Mg2+ electrochemistry. If the enhancements were mimicked by nonaqueous solvents, they could enable Mg batteries with transformation…
View article: Curvature-Induced Modification of Mechano-Electrochemical Coupling and Nucleation Kinetics in a Cathode Material
Curvature-Induced Modification of Mechano-Electrochemical Coupling and Nucleation Kinetics in a Cathode Material Open
View article: Reversible Room-Temperature Fluoride-Ion Insertion in a Tunnel-Structured Transition Metal Oxide Host
Reversible Room-Temperature Fluoride-Ion Insertion in a Tunnel-Structured Transition Metal Oxide Host Open
An energy storage paradigm orthogonal to Li-ion battery chemistries can be conceptualized by employing anions as the primary charge carriers. F-ion conversion chemistries show promise but have limited cyclability as a result of the signifi…