Yoann Rousselin
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View article: FAlen–Zn Complexes for the Cycloaddition of CO<sub>2</sub> to Epoxide and the Ring-Opening Polymerization of Lactide
FAlen–Zn Complexes for the Cycloaddition of CO<sub>2</sub> to Epoxide and the Ring-Opening Polymerization of Lactide Open
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Synthesis and Structural Characterization of Manganese(I) Complexes Ligated by 2-Azabutadienes (ArS)2C=C(H)-N=CPh2 Open
The thioether-functionalized 2-azabutadienes (ArS)2C=C(H)-N=CPh2 (L1 Ar = Ph, L2 Ar = p-Tol) ligate to [Mn(CO)5Br] to form the octahedral five-membered S, N-chelate complexes fac-[MnBr(CO)3{(ArS)2C=C(H)-N=CPh2] (1 Ar = Ph; 2 Ar = p-Tol), w…
Phenylphosphonic acid corroles: corroles that link and bind Open
Thanks to the presence of a phosphonic acid group, A 2 B-corroles were covalently linked to the Zr clusters of a PCN-222 MOF. After insertion of Co, the cobalt corroles are able to bind CO with high selectivity vs. CO 2 , N 2 , and O 2 .
Bifunctional Hexadentate Pyclen–Based Chelating Agent for Mild Radiofluorination in Aqueous Solution at Room Temperature with a Ga‐<sup>18</sup>F Ternary Complex Open
Positron Emission Tomography (PET) is used in oncology for tumor diagnosis, commonly relying on fluorine‐18 ( 18 F) emission detection. The conventional method of 18 F incorporation on to probes by covalent bonding is harsh for sensitive b…
Pinaverium bromide Open
The structure of pinaverium bromide (systematic name: 4-[(2-bromo-4,5-dimethoxyphenyl)methyl]-4-{2-[2-(6,6-dimethyl-2-bicyclo[3.1.1]heptanyl)ethoxy]ethyl}morpholin-4-ium bromide; C 26 H 41 Br 2 NO 4 ), was determined at 110 K. It has monoc…
Prolinol‐Derived Phenoxy‐Amidine Titanium Complexes in Asymmetric Silylcyanation of Aldehydes Open
Three new tridentate phenoxy‐amidine ligands (FA) have been prepared via the ring‐opening of benzoxazole by 2‐(methylamino)ethanol, L ‐prolinol and L ‐diphenylprolinol. Coordination studies of these FA ligands with Ti have led to the synth…
Enantioselective Synthesis of P-Chirogenic 1,2,3-Triazolobenzophospholes Open
An enantioselective synthesis of a new class of benzophosphole-based heterocycles bearing a fused triazole ring with enantioselectivities of ≤99% is reported. The key steps of the synthesis are based on an innovative stereospecific phosphi…
Electronic Structure of Metallophlorins: Lessons from Iridium and Gold Phlorin Derivatives Open
Phlorins have long remained underexplored relative to their fully conjugated counterparts, such as porphyrins, hydroporphyrins, and corroles. Herein, we have attempted to bridge that knowledge gap with a scalar-relativistic density functio…
Poly(vinyl chloride) Dechlorination Catalyzed by Zirconium Open
Poly(vinyl chloride) undergoes dechlorination in the presence of triethylsilane (Et 3 SiH) and a catalytic amount of [Cp 2 Zr(NPh 2 )][CH 3 B(C 6 F 5 ) 3 ] ( 1 b) at 40–80 °C, with up to 91 % efficiency. Stoichiometric reactivity studies c…
Coordination Studies of the [13]aneN4 with Chromophoric Groups Open
We report here a complete study of coordination of the 5-aminomethyl-[13]aneN 4 with chromophoric groups (anthracene, pyrene and naphtalene) by four metals: Zn(II), Cu(II), Ni(II) and Cr(III).We aim to study the effect of the C-functionali…
View article: Phosphonate-substituted porphyrins as efficient, cost-effective and reusable photocatalysts
Phosphonate-substituted porphyrins as efficient, cost-effective and reusable photocatalysts Open
Incorporating phosphonate groups onto the phenyl substituents of meso -tetraphenylporphyrins proves advantageous for their utilization in photocatalysis.
CCDC 2270740: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270727: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270738: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270726: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270723: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270720: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270739: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270725: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270734: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270733: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270722: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270730: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270721: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270735: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270732: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270728: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2270731: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …