Kane Jacob
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View article: Room temperature spin crossover properties in a series of mixed-anion Fe(NH<sub>2</sub>trz)<sub>3</sub>(BF<sub>4</sub>)<sub>2−<i>x</i></sub>(SiF<sub>6</sub>)<sub><i>x</i>/2</sub> complexes
Room temperature spin crossover properties in a series of mixed-anion Fe(NH<sub>2</sub>trz)<sub>3</sub>(BF<sub>4</sub>)<sub>2−<i>x</i></sub>(SiF<sub>6</sub>)<sub><i>x</i>/2</sub> complexes Open
A series of mixed-anion Fe(NH 2 trz) 3 (BF 4 ) 2− x (SiF 6 ) x /2 complexes presenting abrupt spin crossover behaviour with a narrow hysteresis loop just above room temperature is obtained by coordination reaction or solid–liquid post synt…
First Nanoparticles of a Conductor Based on the Organic Donor Molecule BETS: κ-(BETS)2FeCl4 Open
Nanoparticles of the molecular superconductor (BETS)2FeCl4 were obtained by the electrochemical oxidation of BETS in the presence of [(C2H5)4N]FeCl4 and an amphiphilic imine (OATM), acting as a growth controlling agent. When the reaction w…
Characterization of Charge States in Conducting Organic Nanoparticles by X-ray Photoemission Spectroscopy Open
The metallic and semiconducting character of a large family of organic materials based on the electron donor molecule tetrathiafulvalene (TTF) is rooted in the partial oxidation (charge transfer or mixed valency) of TTF derivatives leading…
Possible observation of the signature of the bad metal phase and its crossover to a Fermi liquid in <i>κ</i> –(BEDT–TTF) <sub>2</sub> Cu(NCS) <sub>2</sub> bulk and nanoparticles by Raman scattering Open
κ ‐(BEDT‐TTF) 2 Cu(NCS) 2 has been investigated by Raman scattering in both bulk and nanoparticle compounds. Phonon modes from 20 to 1600 cm −1 have been assigned. Focusing on the unexplored low frequency phonons, a plateau in frequencies …
Nanoparticles of Molecular Conductors and Superconductors: Progress Over the Last Ten Years Open
We review conditions for growing molecular conductors and superconductors as nanoparticles, an attractive morphology for integrating them into electronic components or composite materials. Although the one‐dimensional character of these ma…
Synthesis and Characterization of the Thermoelectric Nickel Tetrathiooxalate Polymer as Nanoparticles Open
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A new compound in the BEDT-TTF family [BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene] with a tetrathiocyanatocuprate(II) anion, (BEDT-TTF)<sub>4</sub>[Cu(NCS)<sub>4</sub>] Open
A new phase combining BEDT-TTF and [Cu(NCS) 4 ] 2– as the counter-anion, namely bis[bis(ethylenedithio)tetrathiafulvalenium] tetrathiocyanatocuprate(II) bis[bis(ethylenedithio)tetrathiafulvalene], (C 10 H 8 S 8 ) 2 [Cu(NCS) 4 ]·2C 10 H 8 S…
Titelbild: Measuring the Relative Reactivity of the Carbon–Hydrogen Bonds of Alkanes as Nucleophiles (Angew. Chem. 42/2018) Open
Die relative Reaktivität der C-H-Bindungen von Alkanen als Nucleophile gegenüber mehreren Silber-, Kupfer- und Rhodium-Carben-Komplexen als starke Elektrophile wurde untersucht. In ihrer Zuschrift auf S. 14044 ff. zeigen P. J. Pérez et al.…
Cover Picture: Measuring the Relative Reactivity of the Carbon–Hydrogen Bonds of Alkanes as Nucleophiles (Angew. Chem. Int. Ed. 42/2018) Open
The relative reactivity of a series of alkane C−H bonds towards silver, copper, and rhodium carbene complexes acting as electrophiles has been studied. In their Communication on page 13848 ff., P. J. Pérez and co-workers show that the carb…
Measuring the Relative Reactivity of the Carbon–Hydrogen Bonds of Alkanes as Nucleophiles Open
We report quantitative measurements of the relative reactivities of a series of C−H bonds of gaseous or liquid C n H 2 n +2 alkanes ( n =1–8, 29 different C−H bonds) towards in situ generated electrophiles (copper, silver, and rhodium carb…
CCDC 1527875: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1527874: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1527877: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1527873: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1527876: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1511342: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
Adjusting the cation and anion nature in ionic liquids used for the growth control of nanoparticles of organic conductors Open
Ionic liquids are used for controlling the growth of organic conductors as nanoparticles. We review the conditions of preparation of nanoparticles of conductors derived from tetrathiafulvalene (TTF), tetramethyltetraselenafulvalene (TMTSF)…
CCDC 1511340: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 1511341: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …