Jean‐Luc Renaud
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View article: First Row Transition Metals in Olefin Metathesis: The Role of Iron and Manganese
First Row Transition Metals in Olefin Metathesis: The Role of Iron and Manganese Open
Olefin metathesis has traditionally been dominated by molybdenum and ruthenium‐based catalysts, but the pursuit of sustainable and earth‐abundant alternatives has driven interest in first‐row transition metals particularly iron. While iron…
View article: Dehydrogenative Coupling Reaction for the Synthesis of 5‐ and 6‐Heterocyclic Derivatives Catalyzed by Earth‐Abundant Metal‐Based Complexes
Dehydrogenative Coupling Reaction for the Synthesis of 5‐ and 6‐Heterocyclic Derivatives Catalyzed by Earth‐Abundant Metal‐Based Complexes Open
Heterocycle synthesis is an intense research area due to their significant importance in pharmaceutical, material chemistry and fine synthesis. Key innovations include transition metal‐based‐catalyzed heterocyclic derivatives synthesis, wh…
View article: Mechanism and optimization of ruthenium-catalyzed oxalamide synthesis using DFT
Mechanism and optimization of ruthenium-catalyzed oxalamide synthesis using DFT Open
A ruthenium pincer-catalyzed dehydrogenative coupling of ethylene glycol and amines forms oxalamides, a key motif in biologically active compounds. DFT calculations reveal the rate-determining step involves hydrogen release.
View article: Synthesis and antibacterial properties under blue LED light of conjugates between the siderophore desferrioxamine B (DFOB) and an Iridium(III) complex
Synthesis and antibacterial properties under blue LED light of conjugates between the siderophore desferrioxamine B (DFOB) and an Iridium(III) complex Open
View article: 2‐Thiophenyl–Isoquinoline Ir(III) Complex: A Promising Tool in Antipseudomonal Photodynamic Therapy under Red Irradiation
2‐Thiophenyl–Isoquinoline Ir(III) Complex: A Promising Tool in Antipseudomonal Photodynamic Therapy under Red Irradiation Open
Innovative therapeutic strategies are more than ever needed to counter the rise of antibiotic–resistant bacterial pathogens worldwide. The use of light, and especially photodynamic therapy (PDT) appears as a promising alternative or comple…
View article: [Ag(IPr)(bpy)][PF<sub>6</sub>]: brightness and darkness playing with aggregation induced phosphorescence for light-emitting electrochemical cells
[Ag(IPr)(bpy)][PF<sub>6</sub>]: brightness and darkness playing with aggregation induced phosphorescence for light-emitting electrochemical cells Open
This work continues attempts to understand the aggregation dilemma, key to design Ag( i )-based complexes that result in phosphorescent powders but dark thin-films, providing remarkable electrochemical stability in lighting devices.
View article: Hydrogen autotransfer with alcohols for alkylations
Hydrogen autotransfer with alcohols for alkylations Open
Iron/ruthenium complexes, akin to Knölker catalysts, for bond reduction and sustainable alkylation using alcohols are included in this review, along with advances in dehydrogenative coupling, hydrogen borrowing, and light-assisted catalysi…
View article: CCDC 1995019: Experimental Crystal Structure Determination
CCDC 1995019: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1995022: Experimental Crystal Structure Determination
CCDC 1995022: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1995020: Experimental Crystal Structure Determination
CCDC 1995020: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1995021: Experimental Crystal Structure Determination
CCDC 1995021: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Blue‐Light Induced Iron‐Catalyzed Synthesis of γ,δ‐Unsaturated Ketones
Blue‐Light Induced Iron‐Catalyzed Synthesis of γ,δ‐Unsaturated Ketones Open
A visible‐light‐induced iron‐catalyzed α‐alkylation of ketones with allylic and propargylic alcohols as pro‐electrophiles is reported. The diaminocyclopentadienone iron tricarbonyl complex plays a dual role by harvesting light and facilita…
View article: CCDC 2257839: Experimental Crystal Structure Determination
CCDC 2257839: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2257840: Experimental Crystal Structure Determination
CCDC 2257840: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Design Rule Hidden from The Eye in S/N‐Bridged Ancillary Ligands for Copper(I) Complexes Applied to Light‐Emitting Electrochemical Cells
Design Rule Hidden from The Eye in S/N‐Bridged Ancillary Ligands for Copper(I) Complexes Applied to Light‐Emitting Electrochemical Cells Open
Enhancing low‐energy emitting Cu(I)‐ionic transition metal complexes (iTMCs) light‐emitting electrochemical cells (LECs) is of utmost importance towards Cu(I)‐iTMC‐based white‐emitting LECs. Here, the ancillary ligand design includes (i) e…
View article: CCDC 2247200: Experimental Crystal Structure Determination
CCDC 2247200: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247202: Experimental Crystal Structure Determination
CCDC 2247202: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247199: Experimental Crystal Structure Determination
CCDC 2247199: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2247201: Experimental Crystal Structure Determination
CCDC 2247201: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Enhancement of Knölker Iron Catalysts for Imine Hydrogenation by Predictive Catalysis: From Calculations to Selective Experiments
Enhancement of Knölker Iron Catalysts for Imine Hydrogenation by Predictive Catalysis: From Calculations to Selective Experiments Open
The reductive amination reaction of imines catalyzed by Knölker-type iron complexes under hydrogen at high pressure is very interesting in synthetic terms. This type of reaction is an important catalytic challenge, since harsh conditions a…
View article: Recycling of brush polymer containing iridium photocatalyst supported on glass balls
Recycling of brush polymer containing iridium photocatalyst supported on glass balls Open
Supported Ir( iii ) photocatalyst covalently linked to glass balls surface by a brush polymer has been synthesized. The new hybrid photocatalyst has been applied in Cross dehydrogenative coupling and recycled 10 time without loss of activi…
View article: Investigation of ligand electronic effects on organometallic complexes using photoelectron spectroscopy and mass spectrometry
Investigation of ligand electronic effects on organometallic complexes using photoelectron spectroscopy and mass spectrometry Open
View article: Burning TADF solids reveals their excitons’ mobility
Burning TADF solids reveals their excitons’ mobility Open
View article: Knölker Iron Catalysts for Hydrogenation Revisited: A Nonspectator Solvent and Fine-Tuning
Knölker Iron Catalysts for Hydrogenation Revisited: A Nonspectator Solvent and Fine-Tuning Open
The reductive amination process under hydrogen at high pressure catalyzed by iron complexes is of great synthetic interest. In this work, we report Density Functional Theory (DFT) studies on the reductive amination catalyzed by a Knölker-t…
View article: Plastic scintillators with 1-phenyl-3-(mesityl)-2-pyrazoline as unique fluorophore for efficient neutron/gamma pulse shape discrimination
Plastic scintillators with 1-phenyl-3-(mesityl)-2-pyrazoline as unique fluorophore for efficient neutron/gamma pulse shape discrimination Open
View article: Novel Red‐Emitting Copper(I) Complexes with Pyrazine and Pyrimidinyl Ancillary Ligands for White Light‐Emitting Electrochemical Cells
Novel Red‐Emitting Copper(I) Complexes with Pyrazine and Pyrimidinyl Ancillary Ligands for White Light‐Emitting Electrochemical Cells Open
The synthesis, photophysical/electrochemical characterization, and implementation in light‐emitting electrochemical cells (LECs) of three novel red‐emitting heteroleptic [Cu(N ^ N)(P ^ P)]PF 6 complexes are reported. The complex design con…
View article: CCDC 2085127: Experimental Crystal Structure Determination
CCDC 2085127: Experimental Crystal Structure Determination Open
View article: CCDC 2085126: Experimental Crystal Structure Determination
CCDC 2085126: Experimental Crystal Structure Determination Open
View article: CCDC 2085125: Experimental Crystal Structure Determination
CCDC 2085125: Experimental Crystal Structure Determination Open
View article: CCDC 2085129: Experimental Crystal Structure Determination
CCDC 2085129: Experimental Crystal Structure Determination Open