Lea Hämmerling
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Design and Experimental Validation of a Photocatalyst Recommender Based on a Large Language Model Open
Utilizing an extensive library of literature on photocatalytic transformations, we disclose the development of a machine learning (ML) model for the recommendation of photocatalysts most suitable for reactions of interest. The model is tra…
Design and Experimental Validation of a Photocatalyst Recommender Based on a Large Language Model Open
Utilizing an extensive library of literature on photocatalytic transformations, we disclose the development of a machine learning (ML) model for the recommendation of photocatalysts most suitable for reactions of interest. The model is tra…
Modular Enantioselective Photocatalysts from Privileged Pybox Scaffolds Open
Modern organic synthesis relies upon the availability of chiral catalysts to control the stereochemistry of bond-forming reactions. As the field of enantioselective catalysis has matured over the past several decades, several families of c…
Design and Experimental Validation of a Photocatalyst Recommender based on a Large Language Model Open
Utilising an extensive library of literature on photocatalytic transformations, we disclose the development of a Machine Learning model for the recommendation of photocatalysts most suitable for reactions of interest. The model is trained …
Semi-renewable Polyamides Containing Disulfide Bonds: Syn-thesis, Degradation, Self-Healing, and Triboelectric Properties Open
We report here the synthesis, degradation, and properties of polyamides containing disulfide bonds. The polyamides have been prepared using a two-step melt polycondensation process from 4,4'-dithiodibutyric acid and bio-derived Pri-amineTM…
View article: DiICz MR-TADF Emitters as Energy Transfer Photocatalysts
DiICz MR-TADF Emitters as Energy Transfer Photocatalysts Open
Photoinduced energy transfer (PEnT) reactions are a subset of photochemical reactions that involve the indirect photoactivation of substrates following an energy transfer from a photoexcited sensitizer/photocatalyst. Examples of PEnT react…
View article: DiICz MR-TADF emitters as potent energy transfer photocatalysts
DiICz MR-TADF emitters as potent energy transfer photocatalysts Open
Here we introduce a family of diindolocarbazole (DiICz) multi-resonant thermally activated delayed fluorescent (MR-TADF) compounds DiICztBu4, DiICzMes4, DiICztBuCz4, and DiICztBuDPA4, as potent energy transfer photocatalysts (PCs).
View article: The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation
The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation Open
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable explosion of interest in the design of thermally activated delayed fluorescence (TADF) compounds, particularly as emitters for organic light-emitting dio…
Building a photocatalyst library of MR-TADF compounds with tunable excited-state redox potentials Open
Funding: The authors would like to thank the European Union H2020 research and innovation program for the funding under the Marie S. Curie Grant agreement (PhotoReAct, no. 956324).
Building a Photocatalyst Library of MR-TADF Compounds with Tuneable Excited-State Redox Potentials Open
Epitomised by 4CzIPN, donor-acceptor (D-A) thermally activated delayed fluorescence (TADF) compounds based on the carbazoyl dicyanobenzene have now become widely used as they are sustainable photocatalyst alternatives to organometallic com…