Leah M. Stateman
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View article: Catalytic β C–H amination <i>via</i> an imidate radical relay
Catalytic β C–H amination <i>via</i> an imidate radical relay Open
An iodine-catalyzed strategy for β C–H amination of alcohols is enabled by a chemo-, regio-, and stereo-selective H-atom transfer mechanism.
View article: δ C–H (hetero)arylation<i>via</i>Cu-catalyzed radical relay
δ C–H (hetero)arylation<i>via</i>Cu-catalyzed radical relay Open
A radical relay strategy has been developed to enable selective δ C–H arylation. The approach employs a chiral copper catalyst, which serves the dual roles of generating an N-centered radical to promote intramolecular H-atom transfer, and …
View article: Remote C–H Functionalization via Selective Hydrogen Atom Transfer
Remote C–H Functionalization via Selective Hydrogen Atom Transfer Open
The selective functionalization of remote C–H bonds via intramolecular hydrogen atom transfer (HAT) is transformative for organic synthesis. This radical-mediated strategy provides access to novel reactivity that is complementary to closed…
View article: CCDC 1401369: Experimental Crystal Structure Determination
CCDC 1401369: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1401371: Experimental Crystal Structure Determination
CCDC 1401371: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1401370: Experimental Crystal Structure Determination
CCDC 1401370: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …