Liwu Zhang
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View article: Machine-learning-enhanced understanding of haze formation: Rapid sulfate formation driven by abnormal aerosol interfacial effects
Machine-learning-enhanced understanding of haze formation: Rapid sulfate formation driven by abnormal aerosol interfacial effects Open
View article: Airborne microplastics: An unexpected source of atmospheric brown carbon
Airborne microplastics: An unexpected source of atmospheric brown carbon Open
Microplastics are increasingly recognized as emergent atmospheric contaminants1,2, yet they are generally presumed to be inert constituents that rarely participate in chemical reactions of importance due to their strong resistance to react…
View article: Inverse and nonlinear relationships between Life’s Essential 8 metrics and gout risk: A cross-sectional study
Inverse and nonlinear relationships between Life’s Essential 8 metrics and gout risk: A cross-sectional study Open
This study investigated the relationship between Life’s Essential 8 (LE8), a recently updated measure of cardiovascular health, and the prevalence of gout among adults in the United States. This study analyzed National Health and Nutrition…
View article: Substantially improved efficiency and selectivity of carbon dioxide reduction by superior hydrated electron in microdroplet
Substantially improved efficiency and selectivity of carbon dioxide reduction by superior hydrated electron in microdroplet Open
The photochemical conversion of CO 2 into valuable fuels faces challenges of low efficiency and poor selectivity. Hydrated electrons (e aq − ), with their extremely negative reduction potential, are promising CO 2 -reducing agents, yet the…
View article: Fresh tire wear particles from moving vehicles: Dispersion dynamics, exposure, and prevention strategy
Fresh tire wear particles from moving vehicles: Dispersion dynamics, exposure, and prevention strategy Open
Tire Wear Particles (TWPs) have emerged as a significant source of non-exhaust emissions, posing potential exposure risks due to increased vehicle ownership and the advent of new energy vehicles. However, the dispersion and flow dynamics o…
View article: MPs Entering Human Circulation through Infusions: A Significant Pathway and Health Concern
MPs Entering Human Circulation through Infusions: A Significant Pathway and Health Concern Open
Human uptake of microplastic particles (MPs) is causing increasing health concerns, and there is mounting pressure to evaluate the associated risks. While MPs can be ingested, breathed in, or drank in, a very direct entrance channel is ava…
View article: Carbonate radical ion as a key driver of rapid atmospheric sulfate formation
Carbonate radical ion as a key driver of rapid atmospheric sulfate formation Open
Carbonate radical anion ( $${{\rm{CO}}}_{{3}^{.-}}$$ CO 3 . − ) is generally considered as a marginal intermediate that rarely regulates atmospheric-relevant reactions of significance. Unexpectedly, in this work, employing a suit of the in…
View article: Does deformation of immobilization devices impact treatment accuracy in thoracic cancer radiotherapy?
Does deformation of immobilization devices impact treatment accuracy in thoracic cancer radiotherapy? Open
Background Immobilization devices are essential for maintaining accurate and repeatable patient positioning in radiotherapy. This study aimed to evaluate the setup errors and dosimetric deviation induced by the deformation of immobilizatio…
View article: Chirality conferral enables the observation of hyper-Raman optical activity
Chirality conferral enables the observation of hyper-Raman optical activity Open
Chirality conferral is fundamental for understanding the origin of life, and it is of direct importance for synthesizing new pharmaceuticals in the face of growing antibiotic resistance. Human-made, self-assembling nanostructures replicate…
View article: Nanoplastics Detected in Commercial Sea Salt
Nanoplastics Detected in Commercial Sea Salt Open
People of all ages consume salt every day, but is it really just salt? Plastic nanoparticles [nanoplastics (NPs)] pose an increasing environmental threat and have begun to contaminate everyday salt in consumer goods. Herein, we developed a…
View article: Investigation of Mold Flux Entrapment in Deep Oscillation Mark of Interstitial-Free Steel Shell Using Mold Simulator
Investigation of Mold Flux Entrapment in Deep Oscillation Mark of Interstitial-Free Steel Shell Using Mold Simulator Open
The slag entrapment defect has become a big issue for the IF steel casting process. In this study, the mechanism of mold flux entrapment in deep oscillation mark of an IF steel shell was studied by a high-temperature mold simulator. Result…
View article: Efficient V-Shaped Substrate for Surface and Volume Enhanced Raman Spectroscopic Analysis of Bioaerosol: Prevention from Potential Health Risk
Efficient V-Shaped Substrate for Surface and Volume Enhanced Raman Spectroscopic Analysis of Bioaerosol: Prevention from Potential Health Risk Open
Bioaerosols pose a great threat to human life and health, and developing highly efficient and accurate identification and analysis methodologies for bioaerosols provides prerequisite knowledge to evaluate their toxicity on human health. In…
View article: The missing small microplastics: easily generated from weathered plastic pieces in labs but hardly detected in natural environments
The missing small microplastics: easily generated from weathered plastic pieces in labs but hardly detected in natural environments Open
Plentiful small microplastics and nanoplastics can easily generate from weathered plastics, but few small microplastics and no nanoplatics could be detected in surrounding sediments, possibly due to a lack of suitable detection approach.
View article: Prebiotic synthesis of mineral-bearing microdroplet from inorganic carbon photoreduction at air–water interface
Prebiotic synthesis of mineral-bearing microdroplet from inorganic carbon photoreduction at air–water interface Open
The origin of life on Earth is an enigmatic and intricate conundrum that has yet to be comprehensively resolved despite recent significant developments within the discipline of archaeology and geology. Chemically, metal-sulfide minerals ar…
View article: Sunlight Induces the Production of Atmospheric Volatile Organic Compounds (VOCs) from Thermokarst Ponds
Sunlight Induces the Production of Atmospheric Volatile Organic Compounds (VOCs) from Thermokarst Ponds Open
Ground subsidence caused by permafrost thawing causes the formation of thermokarst ponds, where organic compounds from eroding permafrost accumulate. We photolyzed water samples from two such ponds in Northern Quebec and discovered the emi…
View article: High enrichment of heavy metals in fine particulate matter through dust aerosol generation
High enrichment of heavy metals in fine particulate matter through dust aerosol generation Open
Dust is a major source of atmospheric aerosols. Its chemical composition is often assumed to be similar to the parent soil. However, this assumption has not been rigorously verified. Here, we generated dust aerosols from soils to determine…
View article: Key Factors Determining the Formation of Sulfate Aerosols Through Multiphase Chemistry—A Kinetic Modeling Study Based on Beijing Conditions
Key Factors Determining the Formation of Sulfate Aerosols Through Multiphase Chemistry—A Kinetic Modeling Study Based on Beijing Conditions Open
Severe haze in Beijing is characterized by the rapid formation of sulfate via the multiphase oxidation of SO 2 . While many factors, including aerosol oxidants and atmospheric variables, were discovered and investigated, their relative imp…
View article: Fast detection and 3D imaging of nanoplastics and microplastics by stimulated Raman scattering microscopy
Fast detection and 3D imaging of nanoplastics and microplastics by stimulated Raman scattering microscopy Open
Nanoplastic pollution represents an increasing concern for the scientific community. However, the identification of tiny nano-/microplastics (smaller than 5 μm) is still a huge challenge. Herein, we report rapid detecting and 3D imaging of…
View article: Dense Arrays of Nanohelices: Raman Scattering from Achiral Molecules Reveals the Near‐Field Enhancements at Chiral Metasurfaces (Adv. Mater. 34/2023)
Dense Arrays of Nanohelices: Raman Scattering from Achiral Molecules Reveals the Near‐Field Enhancements at Chiral Metasurfaces (Adv. Mater. 34/2023) Open
Nanohelices In article number 2209282, Daniel Wolverson, Ventsislav K. Valev, and co-workers reveal how, upon illumination with green circularly polarized light, achiral crystal violet molecules within dense arrays of silver nanohelices yi…
View article: Imaging of pH distribution inside individual microdroplet by stimulated Raman microscopy
Imaging of pH distribution inside individual microdroplet by stimulated Raman microscopy Open
Aerosol microdroplets as microreactors for many important atmospheric reactions are ubiquitous in the atmosphere. pH largely regulates the chemical processes within them; however, how pH and chemical species spatially distribute within an …
View article: Comment on acp-2022-802
Comment on acp-2022-802 Open
Abstract. Dust is a major source of atmospheric aerosols. Its chemical composition is often assumed to be similar to the parent soil. However, this assumption has not been rigorously verified. Here, we generated dust aeros…
View article: Measurement report: Volatile organic compound characteristics of the different land-use types in Shanghai: spatiotemporal variation, source apportionment and impact on secondary formations of ozone and aerosol
Measurement report: Volatile organic compound characteristics of the different land-use types in Shanghai: spatiotemporal variation, source apportionment and impact on secondary formations of ozone and aerosol Open
Volatile organic compounds (VOCs) have important impacts on air quality, atmospheric chemistry and human health. In order to identify the spatiotemporal variations, sources and ozone (O3) and secondary organic aerosol (SOA) formation poten…
View article: High Enrichment of Heavy Metals in Fine Particulate Matter through Dust Aerosol Generation
High Enrichment of Heavy Metals in Fine Particulate Matter through Dust Aerosol Generation Open
Dust is a major source of atmospheric aerosols. Its chemical composition is often assumed to be similar to the parent soil. However, this assumption has not been rigorously verified. Here, we generated dust aerosols from soils to determine…
View article: Supplementary material to "High Enrichment of Heavy Metals in Fine Particulate Matter through Dust Aerosol Generation"
Supplementary material to "High Enrichment of Heavy Metals in Fine Particulate Matter through Dust Aerosol Generation" Open
View article: Dense Arrays of Nanohelices: Raman Scattering from Achiral Molecules Reveals the Near‐Field Enhancements at Chiral Metasurfaces
Dense Arrays of Nanohelices: Raman Scattering from Achiral Molecules Reveals the Near‐Field Enhancements at Chiral Metasurfaces Open
Against the background of the current healthcare and climate emergencies, surface enhanced Raman scattering (SERS) is becoming a highly topical technique for identifying and fingerprinting molecules, e.g., within viruses, bacteria, drugs, …
View article: Heterogeneous Oxidation of So2 Over Key Mineral Dust Component Tio2 in the Presence of Co2: Effect of Relative Humidity and Irradiation Intensity
Heterogeneous Oxidation of So2 Over Key Mineral Dust Component Tio2 in the Presence of Co2: Effect of Relative Humidity and Irradiation Intensity Open
View article: Nanoplastics Detected in Commercial Sea Salt
Nanoplastics Detected in Commercial Sea Salt Open
People of all ages consume salt every day, but is it really just salt? Plastic nanoparticles (nanoplastics) polluting the oceans and the atmosphere are posing an increasing environmental threat and have begun to contaminate everyday salt i…
View article: Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface
Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface Open
The importance of dust heterogeneous oxidation in the removal of atmospheric SO2 and formation of sulfate aerosols is not adequately understood. In this study, the Fe-, Ti-, and Al-bearing components, Na+, Cl−, K+, and Ca2+ of the dust sur…
View article: Significant Acceleration of Photocatalytic CO2 Reduction to HCOOH at Gas-Liquid Interface
Significant Acceleration of Photocatalytic CO2 Reduction to HCOOH at Gas-Liquid Interface Open
Solar‐driven CO2 reduction reaction (CO2RR) is largely constrained by the sluggish mass transfer and fast combination of photogenerated charge carriers. Herein, we find that the photocatalysis CO2RR efficie…
View article: A protocol to study microdroplet photoreaction at an individual droplet level using in situ micro-Raman spectroscopy
A protocol to study microdroplet photoreaction at an individual droplet level using in situ micro-Raman spectroscopy Open