Logesh Mathivathanan
YOU?
Author Swipe
View article: 2-[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-<i>N</i>′-(4-nitrobenzylidene)acetohydrazide monohydrate
2-[(5-Methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-<i>N</i>′-(4-nitrobenzylidene)acetohydrazide monohydrate Open
In the title hydrate, C 12 H 11 N 5 O 3 S 2 ·H 2 O, the dihedral angle between the aromatic rings is 9.6 (3)°. In the crystal, N—H...O and O—H...N hydrogen bonds link the components into (10 1 ) sheets.
View article: Synthesis and Crystal Structures of <i>β</i> ‐Diketonate‐Associated Aluminum Complexes as Potential Catalysts for the Ring‐Opening Polymerization of <i>ε</i> ‐Caprolactone
Synthesis and Crystal Structures of <i>β</i> ‐Diketonate‐Associated Aluminum Complexes as Potential Catalysts for the Ring‐Opening Polymerization of <i>ε</i> ‐Caprolactone Open
A couple of novel crystalline aluminum(III) derivatives containing tridentate Schiff base ligand ( HL ) and β ‐diketones (acetylacetone = acac, benzoylacetone = bnzac, and dibenzoylmethane = dbnz), namely, [Al(L)bnzac] [ Al1 ], [Al(L)dnbz]…
View article: Effect of substitution on second-order nonlinear optical properties of ferrocene appended donor–π–acceptor Y-shaped trifluoromethyl imidazole chromophores
Effect of substitution on second-order nonlinear optical properties of ferrocene appended donor–π–acceptor Y-shaped trifluoromethyl imidazole chromophores Open
Substitution of an imidazole ring creates a steric effect and restricts the intramolecular charge-transfer (ICT) process, resulting in the feeble quadratic hyperpolarizability of the chromophore.
View article: CCDC 2215557: Experimental Crystal Structure Determination
CCDC 2215557: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2215558: Experimental Crystal Structure Determination
CCDC 2215558: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288229: Experimental Crystal Structure Determination
CCDC 2288229: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Crystal Structure, Hirshfeld Analysis, and DFT Calculations of Three Trinuclear Cu(II) Polymorphs
Crystal Structure, Hirshfeld Analysis, and DFT Calculations of Three Trinuclear Cu(II) Polymorphs Open
The crystal structure of the ferromagnetically-coupled CuII3−pyrazolato complex, (Bu4N)2[Cu3(μ3-Cl)2(μ-4-NO2-pz)3Cl3] (1a, pz = pyrazolato anion), was originally determined in the triclinic P-1 space group. By varying the recrystallization…
View article: CCDC 2182643: Experimental Crystal Structure Determination
CCDC 2182643: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2182644: Experimental Crystal Structure Determination
CCDC 2182644: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2182642: Experimental Crystal Structure Determination
CCDC 2182642: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Observation and deconvolution of a unique EPR signal from two cocrystallized spin triangles
Observation and deconvolution of a unique EPR signal from two cocrystallized spin triangles Open
A 16-line pattern has been theoretically predicted, but hitherto not reported, for the Electron Paramagnetic Resonance (EPR) spectrum of antiferromagnetically coupled CuII triangles experiencing isotropic exchange of isosceles magnetic sym…
View article: Cover Feature: Origin of Ferromagnetism and Magnetic Anisotropy in a Family of Copper(II) Triangles (Chem. Eur. J. 56/2020)
Cover Feature: Origin of Ferromagnetism and Magnetic Anisotropy in a Family of Copper(II) Triangles (Chem. Eur. J. 56/2020) Open
Single-crystal electron paramagnetic resonance studies of a ferromagnetic copper(II) triangle were combined with ab initio calculations, and analyzed through a detailed multispin Hamiltonian to explain the origins of the ground state ferro…
View article: CCDC 2005301: Experimental Crystal Structure Determination
CCDC 2005301: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2005300: Experimental Crystal Structure Determination
CCDC 2005300: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Supramolecular Assemblies of Trinuclear Copper(II)-Pyrazolato Units: A Structural, Magnetic and EPR Study
Supramolecular Assemblies of Trinuclear Copper(II)-Pyrazolato Units: A Structural, Magnetic and EPR Study Open
Two anionic complexes, {[Cu3(µ3-OH)(µ-4-Ph-pz)3Cl3]2[Cu(4-Ph-pzH)4](µ-Cl)2}2− (1) and [Cu3(µ3-OH)(µ-pz)3(µ1,1-N3)2(N3)]− (2), crystallize as one-dimensional polymers, held together by weak Cu-(µ-Cl) and Cu-(µ-N3) interactions, respectively…
View article: CCDC 1945948: Experimental Crystal Structure Determination
CCDC 1945948: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Origin of Ferromagnetism and Magnetic Anisotropy in a Family of Copper(II) Triangles
Origin of Ferromagnetism and Magnetic Anisotropy in a Family of Copper(II) Triangles Open
Previously reported ferromagnetic triangles (N n Bu 4 ) 2 [Cu 3 ( μ 3 ‐Cl) 2 ( μ ‐4‐NO 2 ‐pz) 3 Cl 3 ] ( 1 ), (PPN) 2 [Cu 3 ( μ 3 ‐Cl) 2 ( μ ‐pz) 3 Cl 3 ] ( 2 ), (bmim) 2 [Cu 3 ( μ 3 ‐Cl) 2 ( μ ‐pz) 3 Cl 3 ] ( 3 ) and newly reported (PPh 4…
View article: CCDC 1948356: Experimental Crystal Structure Determination
CCDC 1948356: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1948357: Experimental Crystal Structure Determination
CCDC 1948357: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1948355: Experimental Crystal Structure Determination
CCDC 1948355: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1948354: Experimental Crystal Structure Determination
CCDC 1948354: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1948358: Experimental Crystal Structure Determination
CCDC 1948358: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1917126: Experimental Crystal Structure Determination
CCDC 1917126: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1917125: Experimental Crystal Structure Determination
CCDC 1917125: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Nitrite Reduction by Trinuclear Copper Pyrazolate Complexes: An Example of a Catalytic, Synthetic Polynuclear NO Releasing System
Nitrite Reduction by Trinuclear Copper Pyrazolate Complexes: An Example of a Catalytic, Synthetic Polynuclear NO Releasing System Open
Two trinuclear CuII pyrazolato complexes with a Cu3(μ3-E)-core (E = O2- or OH-) and terminal nitrite ligands in two coordination modes were characterized crystallographically, spectroscopically, and electrochemically. One-electron oxidatio…
View article: CCDC 1880273: Experimental Crystal Structure Determination
CCDC 1880273: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …