Lucas W. Teunissen
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View article: 19 nm‐Thick Grafted‐To Polymer Brushes onto Optimized Poly(Dopamine)‐Coated Surfaces
19 nm‐Thick Grafted‐To Polymer Brushes onto Optimized Poly(Dopamine)‐Coated Surfaces Open
Grafting‐to polymer coatings are typically easy to apply, but the thickness of such coatings is typically limited to a few nanometers, which may hamper applications. This paper presents a grafting‐to coating approach that yields polymer br…
View article: Modular and Substrate-Independent Grafting-To Procedure for Functional Polymer Coatings
Modular and Substrate-Independent Grafting-To Procedure for Functional Polymer Coatings Open
The ability to tailor polymer brush coatings to the last nanometer has arguably placed them among the most powerful surface modification techniques currently available. Generally, the synthesis procedures for polymer brushes are designed f…
View article: Antiviral Polymer Brushes by Visible-Light-Induced, Oxygen-Tolerant Covalent Surface Coating
Antiviral Polymer Brushes by Visible-Light-Induced, Oxygen-Tolerant Covalent Surface Coating Open
This work presents a novel route for creating metal-free antiviral coatings based on polymer brushes synthesized by surface-initiated photoinduced electron transfer-reversible addition-fragmentation chain transfer (SI-PET-RAFT) polymerizat…
View article: Thermoresponsive Polymer Brushes for Switchable Protein Adsorption via Dopamine‐Assisted Grafting‐To Strategy
Thermoresponsive Polymer Brushes for Switchable Protein Adsorption via Dopamine‐Assisted Grafting‐To Strategy Open
Surface modifications using responsive polymers give access to biomedical applications that rely on switchable properties, such as smart sensors and actuator systems. In this work, thermoresponsive polymer coatings are synthesized on silic…
View article: Thermoresponsive, Pyrrolidone‐Based Antifouling Polymer Brushes
Thermoresponsive, Pyrrolidone‐Based Antifouling Polymer Brushes Open
Commonly, modification of surfaces with thermoresponsive polymers is performed using poly( N ‐isopropylacrylamide) (poly(NIPAM)). However, integration of poly(NIPAM) with a second polymer to obtain more complex copolymer structures has pro…
View article: Diblock and Random Antifouling Bioactive Polymer Brushes on Gold Surfaces by Visible‐Light‐Induced Polymerization (SI‐PET‐RAFT) in Water
Diblock and Random Antifouling Bioactive Polymer Brushes on Gold Surfaces by Visible‐Light‐Induced Polymerization (SI‐PET‐RAFT) in Water Open
Surface‐initiated photoinduced electron‐transfer‐reversible addition–fragmentation chain transfer (SI‐PET‐RAFT) is, for the first time, used for the creation of antifouling polymer brushes on gold surfaces based on three monomers: oligo(et…
View article: Antifouling Polymer Brushes via Oxygen-Tolerant Surface-Initiated PET-RAFT
Antifouling Polymer Brushes via Oxygen-Tolerant Surface-Initiated PET-RAFT Open
This work presents a new method for the synthesis of antifouling polymer brushes using surface-initiated photoinduced electron transfer-reversible addition-fragmentation chain-transfer polymerization with eosin Y and triethanolamine as cat…
View article: Iridium-catalysed primary alcohol oxidation and hydrogen shuttling for the depolymerisation of lignin
Iridium-catalysed primary alcohol oxidation and hydrogen shuttling for the depolymerisation of lignin Open
A new Ir catalysed approach for the selective cleavage of the Cα–Cβ bond in lignin β-O-4 units, allowing access to novel and tuneable monomeric product mixtures.
View article: Acceptorless Catalytic Alcohol Dehydrogenation and Depolymerization Applied to Lignin
Acceptorless Catalytic Alcohol Dehydrogenation and Depolymerization Applied to Lignin Open
A new catalytic method for the selective depolymerization of lignin via acceptorless dehydrogenation has been developed. Initially, using a Cp*-iridium bipyridonate catalyst under basic conditions, primary alcohol dehydrogenation and retro…