Luis F. Bobadilla
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View article: Boosting Hydrogen Release: Optimized C<sub>3</sub>N<sub>4</sub>‐Supported Palladium Catalysts for Formic Acid Dehydrogenation
Boosting Hydrogen Release: Optimized C<sub>3</sub>N<sub>4</sub>‐Supported Palladium Catalysts for Formic Acid Dehydrogenation Open
Carbon nitride, C 3 N 4 , was synthesized through thermal polycondensation of melamine with varying temperature and time conditions. This approach represents a cost‐effective, straightforward, and environmentally friendly synthetic method …
View article: Exploring the Synergistic Interaction between Nickel- and Ruthenium-Based Catalysts for Carbon Dioxide Methanation Reaction
Exploring the Synergistic Interaction between Nickel- and Ruthenium-Based Catalysts for Carbon Dioxide Methanation Reaction Open
The utilization of nickel-ruthenium as bimetallic catalysts is widely recognized for its efficacy in enhancing the catalytic performance in the carbon dioxide methanation reaction. The present study focuses on the synergistic interplay bet…
View article: Insights into the reactivity of Ni-La catalysts for CO2 methanation
Insights into the reactivity of Ni-La catalysts for CO2 methanation Open
View article: Computational and experimental insights into single-atom catalysts supported on g-C3N4: Unraveling the superior stability and catalytic activity of Rh in hydroformylation reactions
Computational and experimental insights into single-atom catalysts supported on g-C3N4: Unraveling the superior stability and catalytic activity of Rh in hydroformylation reactions Open
View article: Bio-aromatics: Revolutionizing the integrated biomass and plastic waste valorization for high-value aromatic hydrocarbons via bifunctional catalytic pathways of bio-syngas conversion
Bio-aromatics: Revolutionizing the integrated biomass and plastic waste valorization for high-value aromatic hydrocarbons via bifunctional catalytic pathways of bio-syngas conversion Open
Aromatic hydrocarbons play a pivotal role in various industrial applications, serving as essential building blocks to produce polymers, resins, and specialty chemicals. Traditionally, their synthesis has been reliant on fossil fuels, raisi…
View article: Influence of electronic and structural properties on Au/In2O3/ZrO2 catalysts for CO2 hydrogenation to methanol
Influence of electronic and structural properties on Au/In2O3/ZrO2 catalysts for CO2 hydrogenation to methanol Open
View article: Computational and Experimental Insights into Single-Atom Catalysts Supported on C3n4: Unraveling the Superior Stability and Catalytic Activity of Rh in Hydroformylation Reactions
Computational and Experimental Insights into Single-Atom Catalysts Supported on C3n4: Unraveling the Superior Stability and Catalytic Activity of Rh in Hydroformylation Reactions Open
View article: Navigating the Legislative Interventions, Challenges, and Opportunities in Revolutionizing Textile Upcycling/Recycling Processes for a Circular Economy
Navigating the Legislative Interventions, Challenges, and Opportunities in Revolutionizing Textile Upcycling/Recycling Processes for a Circular Economy Open
Embracing a circular economy in the textile industry represents a crucial step toward sustainability, where fashion and textile sectors contribute significantly to CO2 emissions. However, transitioning from a linear "take-make-w…
View article: Redefining the Symphony of Light Aromatic Synthesis Beyond Fossil Fuels: A Journey Navigating through a Fe-Based/HZSM-5 Tandem Route for Syngas Conversion
Redefining the Symphony of Light Aromatic Synthesis Beyond Fossil Fuels: A Journey Navigating through a Fe-Based/HZSM-5 Tandem Route for Syngas Conversion Open
The escalating concerns about traditional reliance on fossil fuels and environmental issues associated with their exploitation have spurred efforts to explore eco-friendly alternative processes. Since then, in an era where the imperative f…
View article: Exploring the impact of nanoshaped ceria in the methanol decomposition reaction pathway for clean energy production
Exploring the impact of nanoshaped ceria in the methanol decomposition reaction pathway for clean energy production Open
View article: Integrated CO2 capture and dynamic catalysis for CO2 recycling in a microbrewery
Integrated CO2 capture and dynamic catalysis for CO2 recycling in a microbrewery Open
View article: Embracing the sustainable horizons through bioenergy innovations: a path to a sustainable energy future
Embracing the sustainable horizons through bioenergy innovations: a path to a sustainable energy future Open
The urgent need for mitigating climate change necessitates a transformative shift in energy production and consumption paradigms. Amidst this challenge, bioenergy emerges as a pivotal contributor to the global energy transition, offering a…
View article: Controlling copper location on exchanged MOR-type aluminosilicate zeolites for methanol carbonylation: In situ/operando IR spectroscopic studies
Controlling copper location on exchanged MOR-type aluminosilicate zeolites for methanol carbonylation: In situ/operando IR spectroscopic studies Open
Replacing homogeneous catalytic processes by heterogeneous routes based on the utilization of solid catalysts is of great interest from an environmental point of view. Owing to their genuine pore structure, zeolites such as mordenites (MOR…
View article: Tandem catalytic approaches for CO2 enriched Fischer-Tropsch synthesis
Tandem catalytic approaches for CO2 enriched Fischer-Tropsch synthesis Open
Fischer-Tropsch Synthesis (FTS) allows the conversion of syngas to high-density liquid fuels, playing a key role in the petrochemical and global energy sectors over the last century. However, the current Global Challenges impose the need t…
View article: Integrating catalytic tandem reactions for the next generation of biofuels: A perspective
Integrating catalytic tandem reactions for the next generation of biofuels: A perspective Open
View article: CO2 Conversion via Low-Temperature RWGS Enabled by Multicomponent Catalysts: Could Transition Metals Outperform Pt?
CO2 Conversion via Low-Temperature RWGS Enabled by Multicomponent Catalysts: Could Transition Metals Outperform Pt? Open
In the context of CO 2 valorisation, the reverse water–gas shift reaction (RWGS) is gathering momentum since it represents a direct route for CO 2 reduction to CO. The endothermic nature of the reaction posses a challenge when it comes to …
View article: Reforming of biomass-derived producer gas using toluene as model tar: Deactivation and regeneration studies in Ni and K-Ni catalysts
Reforming of biomass-derived producer gas using toluene as model tar: Deactivation and regeneration studies in Ni and K-Ni catalysts Open
View article: Monitoring the influence of steam on highly-active rhodium catalyst during the combined reforming of biogas by transient and steady-state <i>operando</i> spectroscopic studies
Monitoring the influence of steam on highly-active rhodium catalyst during the combined reforming of biogas by transient and steady-state <i>operando</i> spectroscopic studies Open
The impact derived from incorporating water into CH 4 /CO 2 biogas stream for the generation of syngas was investigated over the Rh/MgAl 2 O 4 catalyst using operando steady-state and transient DRIFT spectroscopy coupled with MS.
View article: Subnanometric Pt clusters dispersed over Cs-doped TiO<sub>2</sub> for CO<sub>2</sub> upgrading <i>via</i> low-temperature RWGS: <i>operando</i> mechanistic insights to guide an optimal catalyst design
Subnanometric Pt clusters dispersed over Cs-doped TiO<sub>2</sub> for CO<sub>2</sub> upgrading <i>via</i> low-temperature RWGS: <i>operando</i> mechanistic insights to guide an optimal catalyst design Open
Cs-doped Pt/TiO 2 advanced catalysts for CO 2 conversion via low-temperature RWGS: from operando and mechanistic study to real-catalyst design to combat global warming.
View article: Mechanistic insights into methanol carbonylation to methyl acetate over an efficient organic template-free Cu-exchanged mordenite
Mechanistic insights into methanol carbonylation to methyl acetate over an efficient organic template-free Cu-exchanged mordenite Open
A new approach for determining the mechanism of methanol carbonylation to methyl acetate over a green template-free Cu-MOR solid catalyst.
View article: Enroute to the Carbon-Neutrality Goals via the Targeted Development of Ammonia as a Potential Nitrogen-Based Energy Carrier
Enroute to the Carbon-Neutrality Goals via the Targeted Development of Ammonia as a Potential Nitrogen-Based Energy Carrier Open
The reliance of a future carbon-free horizon is strongly aligned with the long-term energy storage avenues which are completely derived from renewable energy resources. Ammonia with its high energy content and density can perform as a dece…
View article: Natural hydrogen in the energy transition: Fundamentals, promise, and enigmas
Natural hydrogen in the energy transition: Fundamentals, promise, and enigmas Open
View article: Biomass gasification, catalytic technologies and energy integration for production of circular methanol: New horizons for industry decarbonisation
Biomass gasification, catalytic technologies and energy integration for production of circular methanol: New horizons for industry decarbonisation Open
View article: Impact of topology framework of microporous solids on methanol carbonylation: An operando DRIFTS-MS study
Impact of topology framework of microporous solids on methanol carbonylation: An operando DRIFTS-MS study Open
View article: Alkane metathesis over immobilized pincer-ligated iridium complexes: Effect of support nature
Alkane metathesis over immobilized pincer-ligated iridium complexes: Effect of support nature Open
In this work, catalytic alkane metathesis has been evaluated as a suitable approach to upcycle hydrocarbons (polyolefins) at moderate temperatures. To this end, a pincer-ligated iridium complex (dehydrogenation catalyst) has been combined …
View article: Low-temperature reverse water gas-shift reaction over highly efficient Cu-hydrotalcites: Mechanistic insights on the role of malachite phase
Low-temperature reverse water gas-shift reaction over highly efficient Cu-hydrotalcites: Mechanistic insights on the role of malachite phase Open
View article: MIL-100(Fe)-derived catalysts for CO2 conversion via low- and high-temperature reverse water-gas shift reaction
MIL-100(Fe)-derived catalysts for CO2 conversion via low- and high-temperature reverse water-gas shift reaction Open
View article: H2-rich syngas production from biogas reforming: Overcoming coking and sintering using bimetallic Ni-based catalysts
H2-rich syngas production from biogas reforming: Overcoming coking and sintering using bimetallic Ni-based catalysts Open
View article: Flexible NiRu Systems for CO2 Methanation: From Efficient Catalysts to Advanced Dual-Function Materials
Flexible NiRu Systems for CO2 Methanation: From Efficient Catalysts to Advanced Dual-Function Materials Open
CO2 emissions in the atmosphere have been increasing rapidly in recent years, causing global warming. CO2 methanation reaction is deemed to be a way to combat these emissions by converting CO2 into synthetic natural gas, i.e., CH4. NiRu/Ce…
View article: Unravelling the CO<sub>2</sub> capture and conversion mechanism of a NiRu–Na<sub>2</sub>O switchable dual-function material in various CO<sub>2</sub> utilisation reactions
Unravelling the CO<sub>2</sub> capture and conversion mechanism of a NiRu–Na<sub>2</sub>O switchable dual-function material in various CO<sub>2</sub> utilisation reactions Open
The mechanism of a NiRuNa/CeAl dual function material in successive cycles of CO 2 capture and conversion was investigated. Carbonyls and carbonates were formed during CO 2 capture, and a spillover mechanism occurred to form the desired pr…