Luis Renken
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View article: Asymmetric <i>gem</i>‐Hydroboration and <i>gem</i>‐Hydrogenation of Ynamides: A New Gateway to Chiral Fischer Carbene Complexes and their Catalytic Transformations
Asymmetric <i>gem</i>‐Hydroboration and <i>gem</i>‐Hydrogenation of Ynamides: A New Gateway to Chiral Fischer Carbene Complexes and their Catalytic Transformations Open
Ynamides, when reacted with H 2 or HBpin in the presence of [Cp*RuCl] 4 , convert into chiral‐at‐metal Fischer carbenes by regioselective gem ‐hydrogenation or gem ‐hydroboration of the polarized triple bond, respectively. gem ‐Hydroborati…
View article: Asymmetric <i>gem</i>‐Hydroboration and <i>gem</i>‐Hydrogenation of Ynamides: A New Gateway to Chiral Fischer Carbene Complexes and their Catalytic Transformations
Asymmetric <i>gem</i>‐Hydroboration and <i>gem</i>‐Hydrogenation of Ynamides: A New Gateway to Chiral Fischer Carbene Complexes and their Catalytic Transformations Open
Ynamides, when reacted with H 2 or HBpin in the presence of [Cp*RuCl] 4 , convert into chiral‐at‐metal Fischer carbenes by regioselective gem ‐hydrogenation or gem ‐hydroboration of the polarized triple bond, respectively. gem ‐Hydroborati…