Luomo Li
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View article: Pre-electrolysis of LiClO<sub>4</sub> in Acetonitrile: Electrochemically Induced Protolytic Carbon–Carbon Bond Formation of Benzylic Ethers and Acetals with Allyl Trimethylsilane and Other Carbon Nucleophiles
Pre-electrolysis of LiClO<sub>4</sub> in Acetonitrile: Electrochemically Induced Protolytic Carbon–Carbon Bond Formation of Benzylic Ethers and Acetals with Allyl Trimethylsilane and Other Carbon Nucleophiles Open
The pre-electrolysis of LiClO4 in acetonitrile in an undivided cell applying only "catalytic" amounts of current (e.g., 0.05 F) led to the formation of a strong acidic medium for the activation of benzylic ethers and acetals. The activated…
View article: Recent Advances in Ionic Transfer Reactions
Recent Advances in Ionic Transfer Reactions Open
In recent years, a series of novel organic reactions, named "ionic transfer reaction", has received much attention.This kind of reaction has a characteristic mechanism and avoids the use of inflammable, explosive, highly toxic and other di…
View article: Indium‐Catalysed Transfer Hydrogenation for the Reductive Cyclisation of 2‐Alkynyl Enones towards Trisubstituted Furans
Indium‐Catalysed Transfer Hydrogenation for the Reductive Cyclisation of 2‐Alkynyl Enones towards Trisubstituted Furans Open
Indium tribromide catalysed the transfer hydrogenation from dihydroaromatic compounds, such as the commercially available γ‐terpinene, to enones, which resulted in the cyclisation to trisubstituted furan derivatives. The reaction was initi…
View article: Indium Tribromide‐Catalysed Transfer‐Hydrogenation: Expanding the Scope of the Hydrogenation and of the Regiodivergent DH or HD Addition to Alkenes
Indium Tribromide‐Catalysed Transfer‐Hydrogenation: Expanding the Scope of the Hydrogenation and of the Regiodivergent DH or HD Addition to Alkenes Open
The transfer‐hydrogenation as well as the regioselective and regiodivergent addition of H−D from regiospecific deuterated dihydroaromatic compounds to a variety of 1,1‐di‐ and trisubstituted alkenes was realised with InBr 3 in dichloro(m)e…