Lutz H. Gade
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View article: Flexible n-Channel Organic Transistors with Low Contact Resistance
Flexible n-Channel Organic Transistors with Low Contact Resistance Open
Three promising small-molecule organic semiconductors, namely, 2,9-bis(heptafluoropropyl)-4,7,11,14-tetrabromo-1,3,8,10-tetraazaperopyrene (TAPP-Br4), N,N'-bis(2,2,3,3,4,4,4-fluorobutyl)-(1,7 and 1,6)-dicyano-perylene-tetracarboxylic diimi…
View article: Dynamics and Conformational Stability of Chiral <i>Bay</i> ‐Phenolate‐Substituted Twisted Octaazaperopyrenedioxides (OAPPDOs)
Dynamics and Conformational Stability of Chiral <i>Bay</i> ‐Phenolate‐Substituted Twisted Octaazaperopyrenedioxides (OAPPDOs) Open
Configurationally stable chiral octaazaperopyrene dioxide (OAPPDO) derivatives were obtained by nucleophilic substitution of chiral BINOL and related fragments as bridging units onto the bay position. The addition of these phenolate deriva…
View article: Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals
Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals Open
Dinuclear M(I)–M(I) complexes (M = Ni, Pd) may serve as stable reservoir forms for highly reactive mononuclear metalloradicals, which are of interest as potential catalytic species. However, their dissociation dynamics as well as the facto…
View article: Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals
Dynamics of Metal–Metal Bond Dissociation in Pd–Pd and Ni–Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals Open
Dinuclear M(I)–M(I) complexes (M = Ni, Pd) may serve as stable reservoir forms for highly reactive mononuclear metalloradicals, which are of interest as potential catalytic species. However, their dissociation dynamics as well as the facto…
View article: T‐shaped 14 Electron Rhodium Complexes: Potential Active Species in C−H Activation
T‐shaped 14 Electron Rhodium Complexes: Potential Active Species in C−H Activation Open
Two T‐shaped 14‐electron rhodium complexes 2 a and 2 b , “framed” and thus stabilized by PNP pincer ligands have been synthesized. The bis( t ‐butyl)phosphine derived PNP t Bu ‐rhodium complex 2 a was isolated from pentane as the more stab…
View article: Carbon‐Carbon Bond Activation at Chromium(I): An 11‐Electron Complex Cleaving Dialkynes
Carbon‐Carbon Bond Activation at Chromium(I): An 11‐Electron Complex Cleaving Dialkynes Open
An 11‐electron T‐shaped chromium(I) complex was obtained by reduction of a PNP‐supported chromium(II) iodide complex. Its d 5 high‐spin electronic structure was characterized employing paramagnetic NMR, EPR, UV/Vis and magnetic measurement…
View article: Radicalizing CO by Mononuclear Palladium(I)
Radicalizing CO by Mononuclear Palladium(I) Open
A mononuclear, T‐shaped palladium(I) d 9 metalloradical ( 3 ), stabilized by a bulky carbazole‐based PNP‐ligand, was obtained by reduction of palladium chloride or thermal Pd−C bond homolysis of the corresponding neopentyl complex. Pressur…
View article: Bay-substituted octaazaperopyrenedioxides as solid-state emitters for strong light-matter coupling
Bay-substituted octaazaperopyrenedioxides as solid-state emitters for strong light-matter coupling Open
Organic solid-state emitters based on a twisted octaazaperopyrenedioxide core can be processed from solution into smooth and highly fluorescent thin films and are integrated directly into optical microcavities for strong light-matter coupl…
View article: Two-photon laser printing of 3D multicolor emissive polymer microstructures
Two-photon laser printing of 3D multicolor emissive polymer microstructures Open
Multicolor 3D microstructures are printed using two-photon laser printing from formulations containing photopolymerizable dyes exhibiting red, green, and blue emission.
View article: CCDC 2290321: Experimental Crystal Structure Determination
CCDC 2290321: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2290320: Experimental Crystal Structure Determination
CCDC 2290320: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2255864: Experimental Crystal Structure Determination
CCDC 2255864: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2260664: Experimental Crystal Structure Determination
CCDC 2260664: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2260666: Experimental Crystal Structure Determination
CCDC 2260666: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2260667: Experimental Crystal Structure Determination
CCDC 2260667: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2260665: Experimental Crystal Structure Determination
CCDC 2260665: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Tetraazacoronenes and Their Dimers, Trimers and Tetramers
Tetraazacoronenes and Their Dimers, Trimers and Tetramers Open
Tetraazacoronenes were synthesized from bay ‐functionalized tetraazaperylenes by Zr‐mediated cyclization and four‐fold Suzuki–Miyaura cross coupling. In the Zr‐mediated approach, an η 4 ‐cyclobutadiene‐zirconium(IV) complex was isolated as…
View article: CCDC 2195473: Experimental Crystal Structure Determination
CCDC 2195473: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2195489: Experimental Crystal Structure Determination
CCDC 2195489: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2195488: Experimental Crystal Structure Determination
CCDC 2195488: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2195474: Experimental Crystal Structure Determination
CCDC 2195474: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154826: Experimental Crystal Structure Determination
CCDC 2154826: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154823: Experimental Crystal Structure Determination
CCDC 2154823: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154825: Experimental Crystal Structure Determination
CCDC 2154825: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2154824: Experimental Crystal Structure Determination
CCDC 2154824: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Peri‐Functionalized Tetraazaperylenes: Strong Emitters for Molecular Polaritonics
Peri‐Functionalized Tetraazaperylenes: Strong Emitters for Molecular Polaritonics Open
The functionalization of the peri position of the bay chlorinated tetraazaperylene was investigated by varying the donor behavior of the substituents to assess the resulting photophysical and electrochemical properties. To accomplish this,…
View article: Induced Fit and Mobility of Cycloalkanes within Nanometer-Sized Confinements at 5 K
Induced Fit and Mobility of Cycloalkanes within Nanometer-Sized Confinements at 5 K Open
Host-guest architectures provide ideal systems for investigating site-specific physical and chemical effects. Condensation events in nanometer-sized confinements are particularly interesting for the investigation of intermolecular and mole…
View article: <i>Peri</i>‐Decoration of a Tetraazaperylene with Urea Units: Chiral Octaazaperopyrenedioxides (OAPPDOs) and Their Optical and Chiroptical Properties
<i>Peri</i>‐Decoration of a Tetraazaperylene with Urea Units: Chiral Octaazaperopyrenedioxides (OAPPDOs) and Their Optical and Chiroptical Properties Open
Octaazaperopyrenedioxides (OAPPDOs) are a new class of fluorescent polycyclic aromatic hydrocarbons based on a tetraazaperylene core that is formally condensed with N‐substituted urea units in the two opposite peri positions. Here, we repo…
View article: CCDC 2130535: Experimental Crystal Structure Determination
CCDC 2130535: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2130537: Experimental Crystal Structure Determination
CCDC 2130537: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …