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View article: Family of Quasi-Isotropic Mn<sup>II</sup> and Mn<sub>2</sub><sup>II</sup> Complexes Exhibiting Slow Relaxation of the Magnetization
Family of Quasi-Isotropic Mn<sup>II</sup> and Mn<sub>2</sub><sup>II</sup> Complexes Exhibiting Slow Relaxation of the Magnetization Open
Slow relaxation of magnetization has been studied for a family of mononuclear MnII complexes and one ferromagnetic dinuclear system, all of them presenting very weak anisotropy. Complexes with formula [{NiL1Mn(H2O)
View article: [MnIII6MnIINaI2], [MnIII3MnIINaI], and [MnIII3] Clusters Derived from Schiff Bases: Syntheses, Structures, and Magnetic Properties
[MnIII6MnIINaI2], [MnIII3MnIINaI], and [MnIII3] Clusters Derived from Schiff Bases: Syntheses, Structures, and Magnetic Properties Open
The reaction of manganese halides with polydentate Schiff bases obtained by the condensation of 3-ethoxysalicylaldehyde and different amino alcohols, resulting in a NO3 set of donors, yielded a series of manganese clusters with {MnIII6MnII…
View article: Manganese (III) Compounds Derived from R-Salicylaldoxime and 9-Anthracenecarboxylate Ligands: A Study of Their Synthesis and Structural, Magnetic, and Luminescent Properties
Manganese (III) Compounds Derived from R-Salicylaldoxime and 9-Anthracenecarboxylate Ligands: A Study of Their Synthesis and Structural, Magnetic, and Luminescent Properties Open
The reaction of Mn(II) salts in the air with different R-salicylaldehyde oximes and the sodium or cesium salts of 9-anthracenecarboxylato (9-AC) allows for the isolation of new six polynuclear compounds: [Mn3NaO(salox)3(9-AC)2(EtOH)3H2O]n·…
View article: Field-Induced Slow Relaxation of the Magnetization in Two Families of [M<sup>II</sup>Ln<sup>III</sup>] Complexes
Field-Induced Slow Relaxation of the Magnetization in Two Families of [M<sup>II</sup>Ln<sup>III</sup>] Complexes Open
A family of discrete dinuclear complexes [MIILnIII] (M = Cu, Ni and Ln = Ce, Gd, Tb, Dy, Er, Yb) has been synthesized from the use of the compartmental Schiff base ligand H4L (3,3′-((1E,1′E)-(ethane-1,2-diylbis(azaneylylidene)) bis(methane…
View article: Zn(II) and Cd(II) complexes with 3-furoic acid. Exploring the role of C H···O interactions
Zn(II) and Cd(II) complexes with 3-furoic acid. Exploring the role of C H···O interactions Open
View article: Correction to “Structural Landscape of α-Acetamidocinnamic Acid Cocrystals with Bipyridine-Based Coformers: Influence of Crystal Packing on Their Thermal and Photophysical Properties”
Correction to “Structural Landscape of α-Acetamidocinnamic Acid Cocrystals with Bipyridine-Based Coformers: Influence of Crystal Packing on Their Thermal and Photophysical Properties” Open
[This corrects the article DOI: 10.1021/acs.cgd.3c01374.].
View article: Structure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligands
Structure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligands Open
View article: When Unsuspected Crystallinity Ruins Biological Testing in Early Discovery: A Case Study
When Unsuspected Crystallinity Ruins Biological Testing in Early Discovery: A Case Study Open
The impact of the crystalline or amorphous structure of a solid on the solubility and pharmacokinetic properties of a drug candidate is always considered by the pharmaceutical industry during the development of a new drug; however, it is n…
View article: Structural Landscape of α-Acetamidocinnamic Acid Cocrystals with Bipyridine-Based Coformers: Influence of Crystal Packing on Their Thermal and Photophysical Properties
Structural Landscape of α-Acetamidocinnamic Acid Cocrystals with Bipyridine-Based Coformers: Influence of Crystal Packing on Their Thermal and Photophysical Properties Open
Controlling the supramolecular synthon outcome in systems with different functionalities has been a key factor for the design of supramolecular materials, which also affected their physicochemical properties. In this contribution, we have …
View article: When an Unsuspected Crystallinity Can Ruin Your Biological Testing in Early Discovery: An Example Case
When an Unsuspected Crystallinity Can Ruin Your Biological Testing in Early Discovery: An Example Case Open
The impact of the crystalline or amorphous structure of a solid on the solubility and pharmacokinetic properties of a drug candidate is always considered by the pharmaceutical industry during the development of a new drug, however, it is n…
View article: Direct, Stereodivergent, and Catalytic Michael Additions of Thioimides to α,β‐Unsaturated Aldehydes – Total Synthesis of Tapentadol
Direct, Stereodivergent, and Catalytic Michael Additions of Thioimides to α,β‐Unsaturated Aldehydes – Total Synthesis of Tapentadol Open
Direct and stereodivergent Michael additions of N ‐acyl 1,3‐thiazinane‐2‐thiones to α,β‐unsaturated aldehydes catalyzed by chiral nickel(II) complexes are reported. The reactions proceed with a remarkable regio‐, diastereo‐, and enantiosel…
View article: Dinuclear enantiopure Ln<sup>3+</sup> complexes with (<i>S</i>-) and (<i>R</i>-) 2-phenylbutyrate ligands. Luminescence, CPL and magnetic properties
Dinuclear enantiopure Ln<sup>3+</sup> complexes with (<i>S</i>-) and (<i>R</i>-) 2-phenylbutyrate ligands. Luminescence, CPL and magnetic properties Open
Eighteen chiral compounds derivated from the ( R )-(−) or ( S )-(+)-2-phenylbutyric acid with formula [Ln 2 (μ- R / S -2-PhBut) 4 ( R / S -2PhBut) 2 (Bphen) 2 ] are presented. Magnetic and luminescence studies, including CPL spectra of the…
View article: Contents list
Contents list Open
View article: Slow magnetic relaxation and luminescence properties in β-diketonate lanthanide(<scp>iii</scp>) complexes. Preparation of Eu(<scp>iii</scp>) and Yb(<scp>iii</scp>) OLED devices
Slow magnetic relaxation and luminescence properties in β-diketonate lanthanide(<span>iii</span>) complexes. Preparation of Eu(<span>iii</span>) and Yb(<span>iii</span>) OLED devices Open
Six β-diketonate compounds [Ln(btfa) 3 (4,4′-dinonylbipy)] Ln = Sm, Eu, Tb, Dy, Er and Yb are reported. Magnetic and Luminescence study is also filed. The Eu and Yb complexes were successfully used as emitters in multilayer vacuum-deposite…
View article: New series of mononuclear β-diketonate cerium(<scp>iii</scp>) field induced single-molecule magnets
New series of mononuclear β-diketonate cerium(<span>iii</span>) field induced single-molecule magnets Open
Five new [Ce(Btfa) 3 L] complexes, Btfa- = 4,4,4-trifluoro-1-phenyl-1,3-butanedionate, are presented. A comprehensive magnetic analysis highlights the significance of different spin relaxation mechanisms that must be considered for a Ce 3+…
View article: Structure Directing Factors and Photophysical Properties of Five Cu(I)-Iodide Materials with N-Donor Heteroaromatic Ligands
Structure Directing Factors and Photophysical Properties of Five Cu(I)-Iodide Materials with N-Donor Heteroaromatic Ligands Open
View article: CCDC 2265153: Experimental Crystal Structure Determination
CCDC 2265153: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265152: Experimental Crystal Structure Determination
CCDC 2265152: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Slow Magnetic Relaxation in Silver(II) Macrocyclic Systems
Slow Magnetic Relaxation in Silver(II) Macrocyclic Systems Open
The spin-lattice relaxation time has been studied trough alternating-current susceptometry and ultralow-frequency Raman spectroscopy in a family of silver(II)-derived molecular systems with spin 1/2 and formulas [Ag
View article: CCDC 2298952: Experimental Crystal Structure Determination
CCDC 2298952: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2298951: Experimental Crystal Structure Determination
CCDC 2298951: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2298953: Experimental Crystal Structure Determination
CCDC 2298953: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2222770: Experimental Crystal Structure Determination
CCDC 2222770: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2222774: Experimental Crystal Structure Determination
CCDC 2222774: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2222769: Experimental Crystal Structure Determination
CCDC 2222769: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2222768: Experimental Crystal Structure Determination
CCDC 2222768: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2222771: Experimental Crystal Structure Determination
CCDC 2222771: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2222773: Experimental Crystal Structure Determination
CCDC 2222773: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2222772: Experimental Crystal Structure Determination
CCDC 2222772: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267802: Experimental Crystal Structure Determination
CCDC 2267802: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …