Marcos Flores‐Álamo
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View article: Quantum-Classical Separation in Bounded-Resource Tasks Arising from Measurement Contextuality
Quantum-Classical Separation in Bounded-Resource Tasks Arising from Measurement Contextuality Open
The prevailing view is that quantum phenomena can be harnessed to tackle certain problems beyond the reach of classical approaches. Quantifying this capability as a quantum-classical separation and demonstrating it on current quantum proce…
View article: Exceptional luminescence lifetime and distinct photoluminescence of Eu3+ and Tb3+ in a novel Cd-MOF
Exceptional luminescence lifetime and distinct photoluminescence of Eu3+ and Tb3+ in a novel Cd-MOF Open
View article: Rational Modulation of Excited‐State Intramolecular Proton Transfer, Aggregation‐Induced Emission, and Intramolecular Motion on Polysubstituted Imidazoles
Rational Modulation of Excited‐State Intramolecular Proton Transfer, Aggregation‐Induced Emission, and Intramolecular Motion on Polysubstituted Imidazoles Open
In this study, it is investigated how the N ‐substitution pattern modulates the excited‐state intramolecular proton transfer (ESIPT) in polysubstituted imidazoles, a class of compounds with promising photophysical properties. The selective…
View article: MHAT-driven copper-catalyzed hydrosilylation of alkenes: a new radical pathway for a less explored regioselectivity
MHAT-driven copper-catalyzed hydrosilylation of alkenes: a new radical pathway for a less explored regioselectivity Open
View article: Mechanochemical Synthesis, Spectroscopic Characterization and Molecular Structure of Piperidine–Phenytoin Salt
Mechanochemical Synthesis, Spectroscopic Characterization and Molecular Structure of Piperidine–Phenytoin Salt Open
Phenytoin is an anticonvulsant drug that suffers from low aqueous solubility. The formation of phenytoin salts is a strategy employed to address this issue. A phenytoin–piperidine salt (PPD–PNT) was synthesized by solvent-assisted grinding…
View article: Synthesis, phase transition, and band gap analysis of MorpH3PbI5 perovskite
Synthesis, phase transition, and band gap analysis of MorpH3PbI5 perovskite Open
View article: DNA Binding with Dipyrromethene Ruthenium(II) Complexes
DNA Binding with Dipyrromethene Ruthenium(II) Complexes Open
Four new arene–ruthenium(II) complexes [(η6-p-cymene)RuCl(dpm)], where dpm are hexa-(L3–L5) and meso-substituted (L6) dipyrromethene ligands, were synthesized. These ligands and the corresponding complexes were thoroughly characterized by …
View article: Conjugated 1,8 and 1,6 Addition of Bis<i>-</i>Trimethylsilylketene Acetal to Activated <i>p</i>-Quinone Methides via Trifluoromethanesulfonic Anhydride
Conjugated 1,8 and 1,6 Addition of Bis<i>-</i>Trimethylsilylketene Acetal to Activated <i>p</i>-Quinone Methides via Trifluoromethanesulfonic Anhydride Open
In this work, we studied the conjugated additions of bis-trimethylsilylacetalketene acetals (bis-TMSKA) to para-quinone methides (p-QMs), which are one of the most explored molecules for the study of conjugated additions and …
View article: Palladium‐Catalyzed Three‐Component Reaction of Enol Ethers, Salicylaldehyde, and Trimethyl Orthoformate: A Fast Synthesis of Tetrahydro‐<scp>2H</scp>,<scp>5H</scp>‐Pyrano[2,3‐b]Chromenes
Palladium‐Catalyzed Three‐Component Reaction of Enol Ethers, Salicylaldehyde, and Trimethyl Orthoformate: A Fast Synthesis of Tetrahydro‐<span>2H</span>,<span>5H</span>‐Pyrano[2,3‐b]Chromenes Open
The Pd‐catalyzed three‐component reaction of enol ethers, methyl orthoformate, and salicylaldehyde is described. Both steroid and non‐steroid enol ethers are compatible. This reaction allows the construction of tetrahydro‐2H,5H‐pyrano[2,3‐…
View article: Solid‐State NMR‐Assisted Dynamic Characterization of two Isostructural Solvates of 5α‐Bromo‐6β,19‐Epoxy‐Androstan‐3β,17β‐Diol Diacetate
Solid‐State NMR‐Assisted Dynamic Characterization of two Isostructural Solvates of 5α‐Bromo‐6β,19‐Epoxy‐Androstan‐3β,17β‐Diol Diacetate Open
The study reports on the rotational dynamics of acetone‐ d 6 (Form II ) and DMSO‐ d 6 (Form III ) within the crystalline structures of two solvates of 5α‐bromo‐6β,19‐epoxy‐androstan‐3β,17β‐diol diacetate (Compound 1 ) by means of solid‐sta…
View article: Electrocatalytic CO2 reduction with calix[8]arene/base metal platforms
Electrocatalytic CO2 reduction with calix[8]arene/base metal platforms Open
View article: Synthesis and cytotoxic activity of morpholino- <i>s</i> -triazine derivatives of POCOP-Ni( <scp>ii</scp> ) pincers
Synthesis and cytotoxic activity of morpholino- <i>s</i> -triazine derivatives of POCOP-Ni( <span>ii</span> ) pincers Open
Six new POCOP-Ni( ii ) pincer complexes were synthesized and evaluated in vitro and in silico against six cancerous cell lines, highlighting the effect of the morpholino- s -triazine moiety.
View article: Influence of cis-2,4,5-tri(pyridine-2-yl)-imidazoline chelating ligand on coordination geometry and photophysical properties of Eu3+ and Tb3+ mononuclear complexes for lighting applications
Influence of cis-2,4,5-tri(pyridine-2-yl)-imidazoline chelating ligand on coordination geometry and photophysical properties of Eu3+ and Tb3+ mononuclear complexes for lighting applications Open
View article: Electrocatalytic water oxidation with bioinspired cubane-type Co <sup>II</sup> complexes
Electrocatalytic water oxidation with bioinspired cubane-type Co <sup>II</sup> complexes Open
Synthesis, characterization, and electrocatalytic water oxidation studies of the cubane-type complexes [(μ 3 - L 1 O )CoCl(MeOH)] 4 (1) and [(μ 3 - L 2 O )CoCl(MeOH)] 4 (2) are herein reported.
View article: Synthesis, Electromagnetic Characterization and Antioxidant Activity of Cu and Co Dipicolinic Acid Complexes
Synthesis, Electromagnetic Characterization and Antioxidant Activity of Cu and Co Dipicolinic Acid Complexes Open
View article: Exceptional Luminescence Lifetime and Distinct Photoluminescence of Eu³⁺ and Tb³⁺ in a Novel Cd-Mof
Exceptional Luminescence Lifetime and Distinct Photoluminescence of Eu³⁺ and Tb³⁺ in a Novel Cd-Mof Open
View article: POCOP-Ni(II) pincer compounds derived from phloroglucinol. Cytotoxic and antioxidant evaluation
POCOP-Ni(II) pincer compounds derived from phloroglucinol. Cytotoxic and antioxidant evaluation Open
POCOP-Ni(II) pincer compounds have primarily been explored as catalysts, but their potential biological activity has been scarcely studied. To address this gap, we evaluated the anticancer and antioxidant potential of four POCOP-Ni(II) com…
View article: Molecular structure and selective theophylline complexation by conformational change of diethyl <i>N</i>,<i>N</i>′-(1,3-phenylene)dicarbamate
Molecular structure and selective theophylline complexation by conformational change of diethyl <i>N</i>,<i>N</i>′-(1,3-phenylene)dicarbamate Open
The receptor ability of diethyl N , N ′-(1,3-phenylene)dicarbamate ( 1 ) to form host–guest complexes with theophylline (TEO) and caffeine (CAF) by mechanochemistry was evaluated. The formation of the 1 –TEO complex (C 12 H 16 N 2 O 4 ·C 7…
View article: 2-Ferrocenyl-2-[(2-ferrocenylethenyl)(morpholin-4-yl)methyl]-1,3-dithiolane
2-Ferrocenyl-2-[(2-ferrocenylethenyl)(morpholin-4-yl)methyl]-1,3-dithiolane Open
The molecular structure of 2-ferrocenyl-2-[(2-ferrocenylethenyl)(morpholin-4-yl)methyl]-1,3-dithiolane, [Fe 2 (C 5 H 5 ) 2 (C 19 H 21 NOS 2 )] or C 29 H 31 Fe 2 NOS 2 , has the ferrocenyl fragments in a trans disposition with respect to th…
View article: Monocopper model of Cu<sub>B</sub> site of pMMO in N4‐environment oxidizes C−H bonds
Monocopper model of Cu<sub>B</sub> site of pMMO in N4‐environment oxidizes C−H bonds Open
Discrepancies regarding the coordination environment, donor atoms, nuclearity, and oxidation state of the active site of particulate methane monooxygenase (pMMO), a copper‐dependent enzyme capable of activating the strong C−H bond of metha…
View article: Effects of the tetravanadate [V4O12]4− anion on the structural, magnetic, and biological properties of copper/phenanthroline complexes
Effects of the tetravanadate [V4O12]4− anion on the structural, magnetic, and biological properties of copper/phenanthroline complexes Open
View article: Electrocatalytic Co2 Reduction with Calix[8]Arene/Base Metal Platforms
Electrocatalytic Co2 Reduction with Calix[8]Arene/Base Metal Platforms Open
View article: Elemental Metal-Catalyzed Dimerization of 2,3-Diaryl and 2,3-Diferrocenyl-Cyclopropenones: Electrochemistry, X-Ray and Biological Evaluation
Elemental Metal-Catalyzed Dimerization of 2,3-Diaryl and 2,3-Diferrocenyl-Cyclopropenones: Electrochemistry, X-Ray and Biological Evaluation Open
View article: New mononuclear Cu(<scp>i</scp>) compounds: synthesis, characterization, and application to the electroreduction of CO<sub>2</sub>
New mononuclear Cu(<span>i</span>) compounds: synthesis, characterization, and application to the electroreduction of CO<sub>2</sub> Open
We disclose the preparation and complete characterization of four new copper-based compounds used in the selective electrocatalytic activation of CO 2 to produce oxalate. Additionally, key mechanistic insights are included.
View article: CCDC 2223464: Experimental Crystal Structure Determination
CCDC 2223464: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2260462: Experimental Crystal Structure Determination
CCDC 2260462: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264531: Experimental Crystal Structure Determination
CCDC 2264531: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2264530: Experimental Crystal Structure Determination
CCDC 2264530: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2251649: Experimental Crystal Structure Determination
CCDC 2251649: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2251647: Experimental Crystal Structure Determination
CCDC 2251647: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …