Mark D. Smith
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View article: A low-temperature, one-step synthesis for monazite can transform monazite into a readily usable advanced nuclear waste form
A low-temperature, one-step synthesis for monazite can transform monazite into a readily usable advanced nuclear waste form Open
It has been demonstrated that monazite-type materials are excellent candidates for nuclear waste forms, and hence, their facile synthesis is of great importance for the needed sequestration of existing nuclear waste. The synthesis of monaz…
View article: Kinetic Control and Trapping in the Supramolecular Polymerization of <i>m</i>‐Terphenyl Bis‐Urea Macrocycles
Kinetic Control and Trapping in the Supramolecular Polymerization of <i>m</i>‐Terphenyl Bis‐Urea Macrocycles Open
Herein, we examine pathway complexity in the supramolecular polymerization of a novel m ‐terphenyl bis‐urea macrocycle. Designed to induce kinetically metastable states, the macrocycle‘s concentration‐dependent aggregation was studied via …
View article: Stimuli-responsive photoswitch–actinide binding: a match made in MOFs
Stimuli-responsive photoswitch–actinide binding: a match made in MOFs Open
Photochromic radionuclide-based “claw machines” characterized via a combination of isothermal titration calorimetry and spectroscopic analysis unlock a pathway for on demand radionuclide capture and release.
View article: Non-spectator behavior of a neutral phosphine ligand driven by a redox-active boron cluster
Non-spectator behavior of a neutral phosphine ligand driven by a redox-active boron cluster Open
A new concept of ligand ambiphilicity that relies on the redox behavior of the indirectly coordinated boron cluster scaffold instead of the direct involvement of a single center in a ligand is introduced.
View article: Solvent attenuation of dispersion interactions quantified in polar and nonpolar media using rigid CH–π balances
Solvent attenuation of dispersion interactions quantified in polar and nonpolar media using rigid CH–π balances Open
Solvent attenuation of dispersion interactions was quantified using a new class of rigid intramolecular CH–π molecular balances.
View article: Friends or Foes: Fundamental Principles of Th-Organic Scaffold Chemistry Using Zr-Analogs as a Guide
Friends or Foes: Fundamental Principles of Th-Organic Scaffold Chemistry Using Zr-Analogs as a Guide Open
The fundamental interest in actinide chemistry, particularly for the development of thorium-based materials, is experiencing a renaissance owing to the recent and rapidly growing attention to fuel cycle reactors, radiological daughters for…
View article: Carolina Currents, Studies in South Carolina Culture
Carolina Currents, Studies in South Carolina Culture Open
Introducing an annual collection of essays devoted to South Carolina history and culture. From the Piedmont to the Lowcountry, South Carolina is the site of countless engaging stories. The contributors to Carolina Currents share those stor…
View article: Examination of photoinduced radicals in two crystal forms of triphenylamine bis-urea macrocycles
Examination of photoinduced radicals in two crystal forms of triphenylamine bis-urea macrocycles Open
The structures and photoinduced radical (PIR) percentages of two crystalline solvates of unsubstituted triphenylamine bis-urea macrocycles are compared. Upon activation, both afford similar structures with higher PIR %.
View article: CCDC 2283039: Experimental Crystal Structure Determination
CCDC 2283039: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Breaking the photoswitch speed limit
Breaking the photoswitch speed limit Open
The forthcoming generation of materials, including artificial muscles, recyclable and healable systems, photochromic heterogeneous catalysts, or tailorable supercapacitors, relies on the fundamental concept of rapid switching between two o…
View article: CSD 2284021: Experimental Crystal Structure Determination
CSD 2284021: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284019: Experimental Crystal Structure Determination
CSD 2284019: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284036: Experimental Crystal Structure Determination
CSD 2284036: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284032: Experimental Crystal Structure Determination
CSD 2284032: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284034: Experimental Crystal Structure Determination
CSD 2284034: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284026: Experimental Crystal Structure Determination
CSD 2284026: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284033: Experimental Crystal Structure Determination
CSD 2284033: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284024: Experimental Crystal Structure Determination
CSD 2284024: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284022: Experimental Crystal Structure Determination
CSD 2284022: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284030: Experimental Crystal Structure Determination
CSD 2284030: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284031: Experimental Crystal Structure Determination
CSD 2284031: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284025: Experimental Crystal Structure Determination
CSD 2284025: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284028: Experimental Crystal Structure Determination
CSD 2284028: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2284020: Experimental Crystal Structure Determination
CSD 2284020: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…