Martin Lutz
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View article: Twinned <scp>L</scp> -aspartic acid
Twinned <span>L</span> -aspartic acid Open
By improving the data quality with appropriate twin handling in the intensity integration, difference-Fourier maps show indications for asymmetric double-well hydrogen bonds between the carboxylate groups of the title molecule. Refinements…
View article: 10 Judentum
10 Judentum Open
View article: 1 Einleitung
1 Einleitung Open
View article: Synthesis, Characterization, and Catalytic Activity of Gold Complexes Bearing Bicyclic Silicon and Germanium Anionic Ligands
Synthesis, Characterization, and Catalytic Activity of Gold Complexes Bearing Bicyclic Silicon and Germanium Anionic Ligands Open
Silanides ([R3Si-]) and germanides ([R3Ge-]) are attracting attention as donor ligands for transition metals, but their use as supporting ligands in catalysis is limited, often due to their high …
View article: Long-Term Biomonitoring of Selenium and Arsenic Using Three Grass Species
Long-Term Biomonitoring of Selenium and Arsenic Using Three Grass Species Open
Coal-fired power plants produce a waste stream of coal combustion residuals (CCRs) which are typically disposed of in landfills and surface impoundments that must be monitored to ensure that hazardous constituents such as arsenic (As) and …
View article: Dual Excitation and Dual Emission in a 1,4‐Diazepine Bearing an Extended π‐System
Dual Excitation and Dual Emission in a 1,4‐Diazepine Bearing an Extended π‐System Open
We present the synthesis of a benzo[b]benzo[11,12]tetracene[5,6‐ef][1,4]diazepine (BBTDZ) and a benzo[g]phenanthro[9,10,1‐cde]indazolium (BPIZ), two novel N‐heterocyclic nanographenes. Both molecules were independently isolated from 2,3‐Di…
View article: Autobiographical Narratives in Major Depression: Changes in Overgeneralization During Outpatient Psychodynamic Psychotherapy
Autobiographical Narratives in Major Depression: Changes in Overgeneralization During Outpatient Psychodynamic Psychotherapy Open
Background: Previous studies have shown that patients with depression recall less specific autobiographical memories, a phenomenon known as overgeneral autobiographical memory. This is often linked to dysfunctional emotion regulation and c…
View article: The Missing Structures of Pasteur’s Aspartates
The Missing Structures of Pasteur’s Aspartates Open
In his crystallographic research on chiral separation, Louis Pasteur reported the crystals of the sodium salts of enantiopure and racemic aspartic acid. Their atomic structure remained unknown to this day. In the present article, the two c…
View article: Addition and Oxidation Reactivity of a Pentacoordinate Nickelacyclobutane
Addition and Oxidation Reactivity of a Pentacoordinate Nickelacyclobutane Open
Nickelacyclobutanes are reactive intermediates in catalytic cycles including cyclopropanation and insertion reactions. The stoichiometric study of these intermediates has shown that their reactivity is highly influenced by the coordination…
View article: Closed-Loop Chemical Recycling of a Biobased Poly(oxanorbornene-fused γ-butyrolactone)
Closed-Loop Chemical Recycling of a Biobased Poly(oxanorbornene-fused γ-butyrolactone) Open
New polymers, properly designed for end-of-life and efficiently formed from renewable carbon, are key to the transition to a more sustainable circular plastics economy. Ring-opening polymerization (ROP) of bicyclic lactones is a promising …
View article: Probing the Reactivity of Bimetallic Alkylmagnesium Complexes Using a Rigid and Dinucleating Naphthyridine-Based Ligand
Probing the Reactivity of Bimetallic Alkylmagnesium Complexes Using a Rigid and Dinucleating Naphthyridine-Based Ligand Open
The synthesis, characterisation and reactivity of a Mg2(n-Bu)2 complex bound by a rigid and dinucleating ligand is described. Supported by calculations we detail the effects of nuclearity and coordinative saturation of Mg2(n-Bu)2 complexes…
View article: Space Group Choice for an Octahedral Zn Complex with Nalidixic Acid and (R,R)-Diaminocyclohexane as Ligands: Get the Stereochemistry Right
Space Group Choice for an Octahedral Zn Complex with Nalidixic Acid and (R,R)-Diaminocyclohexane as Ligands: Get the Stereochemistry Right Open
With this report, the space group of [Zn(Nal)(DACH)2]Cl is corrected (Nal: nalidixic acid mono-anion; DACH: diaminocyclohexane) from its wrong description in the literature. In the correct, non-centrosymmetric space group P1, the crystal s…
View article: Contents list
Contents list Open
View article: Pendulum-like hemilability in a Ti-based frustrated Lewis Trio
Pendulum-like hemilability in a Ti-based frustrated Lewis Trio Open
We describe the first experimental example of a theoretically predicted Frustrated Lewis Trio (FLT), which displays pendulum-like hemilability in heterolytic bond activation processes.
View article: CCDC 2266876: Experimental Crystal Structure Determination
CCDC 2266876: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236144: Experimental Crystal Structure Determination
CCDC 2236144: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Cooperative H2 activation at a nickel(0)–olefin centre
Cooperative H2 activation at a nickel(0)–olefin centre Open
Catalytic olefin hydrogenation is ubiquitous in organic synthesis. In most proposed homogeneous catalytic cycles, reactive M-H bonds are generated either by oxidative addition of H2 to a metal centre or by deprotonation of a non…
View article: Pendulum‐like Hemilability in a Ti‐based Frustrated Lewis Trio
Pendulum‐like Hemilability in a Ti‐based Frustrated Lewis Trio Open
We describe the first experimental example of a theoretically predicted Frustrated Lewis Trio (FLT). A tetradentate PNNP ligand is used to stabilise a highly electrophilic [TiCl3]+ fragment in a way that results in two equally long and fru…
View article: CCDC 2190239: Experimental Crystal Structure Determination
CCDC 2190239: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190237: Experimental Crystal Structure Determination
CCDC 2190237: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190238: Experimental Crystal Structure Determination
CCDC 2190238: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2126535: Experimental Crystal Structure Determination
CCDC 2126535: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2126534: Experimental Crystal Structure Determination
CCDC 2126534: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2245042: Experimental Crystal Structure Determination
CCDC 2245042: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2245041: Experimental Crystal Structure Determination
CCDC 2245041: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2245043: Experimental Crystal Structure Determination
CCDC 2245043: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2245044: Experimental Crystal Structure Determination
CCDC 2245044: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2245045: Experimental Crystal Structure Determination
CCDC 2245045: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Comment on “Crystallographic and theoretical study of the atypical distorted octahedral geometry of the metal chromophore of zinc(II) bis((1R,2R)-1,2-diaminocyclohexane) dinitrate”
Comment on “Crystallographic and theoretical study of the atypical distorted octahedral geometry of the metal chromophore of zinc(II) bis((1R,2R)-1,2-diaminocyclohexane) dinitrate” Open
We comment on the crystal structure of an enanantipure chiral zinc complex which has been described by Ivanova & Spiteller (2022) erroneously in a centrosymmetric space group with the metal on an inversion center. Subsequent information ab…
View article: CCDC 2160733: Experimental Crystal Structure Determination
CCDC 2160733: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …