M.I. Arriortua
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View article: Designing Metal-Chelator-like Traps by Encoding Amino Acids in Zirconium-Based Metal–Organic Frameworks
Designing Metal-Chelator-like Traps by Encoding Amino Acids in Zirconium-Based Metal–Organic Frameworks Open
Metal chelators and porous sorbents are two of the forefront technologies applied for the recovery and separation of hazardous and/or valuable metal ions from aqueous solutions. (i.e. polluted water sources, metal-rich mining wastewaters, …
View article: Magnetoelastic Resonance Sensors: Principles, Applications, and Perspectives
Magnetoelastic Resonance Sensors: Principles, Applications, and Perspectives Open
Magnetoelastic resonators are gaining attention as an incredibly versatile and sensitive transduction platform for the detection of varied physical, chemical, and biological parameters. These sensors, based on the coupling effect between m…
View article: Modulation of the Bifunctional CrVI to CrIII Photoreduction and Adsorption Capacity in ZrIV and TiIV Benchmark Metal-Organic Frameworks
Modulation of the Bifunctional CrVI to CrIII Photoreduction and Adsorption Capacity in ZrIV and TiIV Benchmark Metal-Organic Frameworks Open
The presence of hexavalent chromium water pollution is a growing global concern. Among the currently applied technologies to remove CrVI, its adsorption and photocatalytic reduction to CrIII less mobile and toxic forms are the most appeali…
View article: Porous, lightweight, metal organic materials
Porous, lightweight, metal organic materials Open
Lightweight Metal Organic Framework adsorbents are chemically versatile and highly porous materials that have been widely tuned to enhance their affinity and capacity to capture metal ions with different chemical natures from aqueous envir…
View article: Multifunctionality of weak ferromagnetic porphyrin-based MOFs: selective adsorption in the liquid and gas phase
Multifunctionality of weak ferromagnetic porphyrin-based MOFs: selective adsorption in the liquid and gas phase Open
Ferromagnetic [Ni5(H2TCPP)2O(H2O)4]·nS exhibits selective adsorption towards cationic dyes in solution and gas separation calculations predict promising values for gas mixtures.
View article: Metal–Organic Framework Based PVDF Separators for High Rate Cycling Lithium-Ion Batteries
Metal–Organic Framework Based PVDF Separators for High Rate Cycling Lithium-Ion Batteries Open
Poly(vinylidene fluoride) (PVDF) and MOF-808-based separators for lithium-ion batteries (LIBs) have been prepared and fully characterized in terms of morphological and thermal properties, electrolyte uptake, and retention, and surface hydr…
View article: CSD 824501: Experimental Crystal Structure Determination
CSD 824501: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Chromium Speciation in Zirconium‐Based Metal–Organic Frameworks for Environmental Remediation
Chromium Speciation in Zirconium‐Based Metal–Organic Frameworks for Environmental Remediation Open
Acute Cr VI water pollution due to anthropogenic activities is an increasing worldwide concern. The high toxicity and mobility of Cr VI makes it necessary to develop dual adsorbent/ion‐reductive materials that are able to capture Cr VI and…
View article: Chromium speciation in Zr-based Metal-Organic Frameworks for environmental remediation
Chromium speciation in Zr-based Metal-Organic Frameworks for environmental remediation Open
Acute CrVI water pollution due to anthropogenic activities is an increasing worldwide concern. The high toxicity and mobility of CrVI makes necessary to develop dual adsorbent/ion-reductive materials able to capture CrVI and transform it e…
View article: Metal Organic Framework based PVDF-separators for high rate cycling lithium-ion batteries
Metal Organic Framework based PVDF-separators for high rate cycling lithium-ion batteries Open
Poly(vinylidene fluoride) (PVDF) and MOF-808 based separators for lithium-ion batteries (LIBs) have been prepared and fully characterized in terms of morphological and thermal properties, electrolyte uptake and retention, and surface hydro…
View article: Study of the versatility of CuBTC@ IL-derived materials for heterogeneous catalysis
Study of the versatility of CuBTC@ IL-derived materials for heterogeneous catalysis Open
The versatility of CuBTC (or HKUST-1) MOF material to be functionalized to tune its catalytic activity performance was evaluated. The MOF was functionalized with ionic liquids (IL) to give rise to catalysts able to adsorb CO2 and react wit…
View article: Study of Zr-based metal-organic frameworks for water remediation
Study of Zr-based metal-organic frameworks for water remediation Open
MOFs are a class of crystalline inorganicorganic hybrid porous materials which show large surface areas, high porosity and easy chemical tunability. The MOFs are produced by a coordination reaction between metal clusters and organic ligand…
View article: Exploring new hydrated delta type vanadium oxides for lithium intercalation
Exploring new hydrated delta type vanadium oxides for lithium intercalation Open
The interlayer spacing of novel double layered vanadium oxides is modulated by the difference in water contents and alkali pillars. The capacity retention of the active phases is strongly dependent on the vacuum-drying treatment of the ele…
View article: CCDC 1955020: Experimental Crystal Structure Determination
CCDC 1955020: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1955019: Experimental Crystal Structure Determination
CCDC 1955019: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Ionothermal Synthesis of Cadmium Coordination Polymers: Ionic Liquid Effects on the Synthesis, Structural, and Thermal Characterization
Ionothermal Synthesis of Cadmium Coordination Polymers: Ionic Liquid Effects on the Synthesis, Structural, and Thermal Characterization Open
Ionothermal synthesis is a little used method for the preparation of coordination polymers. By this method, two cadmium compounds were synthesized, 1, with formula Cd3(ox)F2(Ina)2 (Ina = isonicotinate) and 2, Cd(NO3)2(4,4′-Bpy) (4,4′-Bpy =…
View article: Structural Transformations in the Thermal Dehydration of [Cu2(bpa)(btec)(H2O)4]n Coordination Polymer
Structural Transformations in the Thermal Dehydration of [Cu2(bpa)(btec)(H2O)4]n Coordination Polymer Open
Reactions between pyridinic ligands such as 1,2-bis(4-pyridyl)ethane (bpa) and transition metal cations are a very widespread technique to produce extended coordination polymers such as Metal-Organic Frameworks. In combination with a secon…
View article: CSD 1886578: Experimental Crystal Structure Determination
CSD 1886578: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CCDC 1910261: Experimental Crystal Structure Determination
CCDC 1910261: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Thermal activation of charge carriers in ionic and electronic semiconductor β-Ag<sup>I</sup>V<sup>V</sup>O<sub>3</sub> and β-Ag<sup>I</sup>V<sup>V</sup>O<sub>3</sub>@V<sup>V</sup><sub>1.6</sub>V<sup>IV</sup><sub>0.4</sub>O<sub>4.8</sub> composite xerogels
Thermal activation of charge carriers in ionic and electronic semiconductor β-Ag<sup>I</sup>V<sup>V</sup>O<sub>3</sub> and β-Ag<sup>I</sup>V<sup>V</sup>O<sub>3</sub>@V<sup>V</sup><sub>1.6</sub>V<sup>IV</sup><sub>0.4</sub>O<sub>4.8</sub> composite xerogels Open
Assembly of SVO and slightly reduced VO nanoribbons in inorganic hydrogels enables the formation of proton conductor and electron conductor xerogels depending on the SVO/VO ratio. Thermal charge carrier activation results in enhanced condu…
View article: CSD 1886577: Experimental Crystal Structure Determination
CSD 1886577: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Synthesis of new Ln<sub>4</sub>(Al<sub>2</sub>O<sub>6</sub>F<sub>2</sub>)O<sub>2</sub> (Ln = Sm, Eu, Gd) phases with a cuspidine-related structure
Synthesis of new Ln<sub>4</sub>(Al<sub>2</sub>O<sub>6</sub>F<sub>2</sub>)O<sub>2</sub> (Ln = Sm, Eu, Gd) phases with a cuspidine-related structure Open
The first fluorination of the cuspidine-related phases of Ln 4 (Al 2 O 7 □)O 2 (where Ln = Sm, Eu, Gd) is reported. A low-temperature reaction with poly(vinylidene difluoride) lead to the fluorine being substituted in place of oxygen and i…
View article: Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)
Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs) Open
Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few…