Jeremy M. Rawson
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View article: Ladder-Type Cu(II) Coordination Polymer with π–π Stacking of Planar Blatter Radical Ligands: Structural and Magnetic Characterization
Ladder-Type Cu(II) Coordination Polymer with π–π Stacking of Planar Blatter Radical Ligands: Structural and Magnetic Characterization Open
The synthesis of two C(2)-pyridyl derivatives of the planar Blatter radical was developed by using the tris-(trimethylsilyl)-silane (TTMSS)-assisted cyclization of appropriate iodoarenes. These monodentate paramagnetic ligands were charact…
View article: Core‐Only Calamitic Liquid Crystals: Molecular Design and Optoelectronic Properties
Core‐Only Calamitic Liquid Crystals: Molecular Design and Optoelectronic Properties Open
Thermotropic liquid crystals are typically thought of as requiring a rigid core and flexible side‐chains to exhibit liquid crystallinity, but precedent does exist for retaining liquid crystalline nature without these side‐chains in highly …
A tale of two mechanisms: The p53 modulator COTI-2 is a Zn metallochaperone Open
Mutations in, or misregulation of, Tp53 are found in approximately 50% of all cancers. p53 functions by ensuring that cells with irretrievably damaged DNA undergo apoptosis. When p53 is non-functional in cells that may also be undergoing u…
View article: Mechanochemical synthesis and <sup>35</sup>Cl NMR crystallography of ionic cocrystals of phenothiazine drugs
Mechanochemical synthesis and <sup>35</sup>Cl NMR crystallography of ionic cocrystals of phenothiazine drugs Open
Mechanochemistry was used to synthesize ionic cocrystals of phenothiazine drugs that were characterized by 35 Cl solid-state NMR and DFT calculations.
Fluorination in core-only calamitic liquid crystals: how many and where should they go? Open
Crystallization temperatures as low as 130 °C were obtained for strongly fluorescent conjugated calamitic liquid crystals by selective fluorination and without the aid of flexible side-chains.
View article: Oxidative addition chemistry of bis(4,5-dimethoxybenzo)-1,2,5,6-tetrathiocin with cyclopentadienyl metal carbonyl complexes and the mechanochemical transformation of CpCo(dmobdt) to [CpCo(dmobdt)] <sub>2</sub>
Oxidative addition chemistry of bis(4,5-dimethoxybenzo)-1,2,5,6-tetrathiocin with cyclopentadienyl metal carbonyl complexes and the mechanochemical transformation of CpCo(dmobdt) to [CpCo(dmobdt)] <sub>2</sub> Open
Microwave-promoted oxidative addition of tetrathiocin 1 to CpCo(CO) 2 affords CpCo(dmobdt) which undergoes a mechanochemical transformation to [CpCo(dmobdt)] 2 .
View article: A Spontaneous Magnetic Moment in an Organic Radical: Synthesis and Characterization of Benzodioxepinyl-1,3,2-dithiazolyl
A Spontaneous Magnetic Moment in an Organic Radical: Synthesis and Characterization of Benzodioxepinyl-1,3,2-dithiazolyl Open
The synthesis of the 1,3,2-dithiazolyl radical (1) derived from 3,4-dihydro-2H-1,5-benzodioxepine is described. Crystals of 1 were grown by vacuum sublimation and adopt the orthorhombic space group Pbca. DC SQUID magnetometry reveals Curie…
1,3-Dipolar cyclisation reactions of nitriles with sterically encumbered cyclic triphosphanes: synthesis and electronic structure of phosphorus-rich heterocycles with tunable colour Open
The acid-mediated cyclisation of sterically encumbered cyclic triphosphanes with nitriles provides access to five-membered cationic and neutral P 3 CN heterocycles with tuneable colour.
View article: CCDC 2285812: Experimental Crystal Structure Determination
CCDC 2285812: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285807: Experimental Crystal Structure Determination
CCDC 2285807: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285811: Experimental Crystal Structure Determination
CCDC 2285811: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285810: Experimental Crystal Structure Determination
CCDC 2285810: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285808: Experimental Crystal Structure Determination
CCDC 2285808: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285809: Experimental Crystal Structure Determination
CCDC 2285809: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2067482: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2067481: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214353: Experimental Crystal Structure Determination
CCDC 2214353: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2240285: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2240280: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2240282: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2240284: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2240281: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2240283: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214355: Experimental Crystal Structure Determination
CCDC 2214355: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2240278: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214354: Experimental Crystal Structure Determination
CCDC 2214354: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
CCDC 2240279: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214351: Experimental Crystal Structure Determination
CCDC 2214351: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214352: Experimental Crystal Structure Determination
CCDC 2214352: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …