Majji Shankar
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View article: WCN25-1590 PARAPROTEIN RELATED KIDNEY DISEASE – A STUDY FROM TERTIARY CARE CENTER IN INDIA
WCN25-1590 PARAPROTEIN RELATED KIDNEY DISEASE – A STUDY FROM TERTIARY CARE CENTER IN INDIA Open
View article: Lentiviral Gene Therapy with CD34+ Hematopoietic Cells for Hemophilia A
Lentiviral Gene Therapy with CD34+ Hematopoietic Cells for Hemophilia A Open
Gene therapy for hemophilia A with the use of lentiviral vector-transduced autologous HSCs resulted in stable factor VIII expression, with factor VIII activity correlating to vector copy number in the peripheral blood. (Funded by the Minis…
View article: Interception and Synthetic Application of Diradical and Diene Forms of Dual-Nature Azabicyclic o-Quinodimethanes Generated by 6pi-Azaelectrocyclization
Interception and Synthetic Application of Diradical and Diene Forms of Dual-Nature Azabicyclic o-Quinodimethanes Generated by 6pi-Azaelectrocyclization Open
We demonstrate that 2-alkenylarylaldimines and ketimines undergo thermal 6pi-azaelectrocyclization to generate a wide range of azabicyclic o-quinodimethanes (o-QDMs). These o-QDMs exist as a hybrid of a diene and a benzylic diradical. The …
View article: CCDC 2224825: Experimental Crystal Structure Determination
CCDC 2224825: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2224828: Experimental Crystal Structure Determination
CCDC 2224828: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2224826: Experimental Crystal Structure Determination
CCDC 2224826: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Photosensitized O <sub>2</sub> enables intermolecular alkene cyclopropanation by active methylene compounds
Photosensitized O <sub>2</sub> enables intermolecular alkene cyclopropanation by active methylene compounds Open
Cyclopropanes are key features in many preclinical, clinical, and commercial drugs, as well as natural products. The most prolific technique for their synthesis is the metal-catalyzed reaction of an alkene with a diazoalkane, a highly ener…
View article: CCDC 2201028: Experimental Crystal Structure Determination
CCDC 2201028: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2201027: Experimental Crystal Structure Determination
CCDC 2201027: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2201031: Experimental Crystal Structure Determination
CCDC 2201031: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2201032: Experimental Crystal Structure Determination
CCDC 2201032: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2201030: Experimental Crystal Structure Determination
CCDC 2201030: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2201029: Experimental Crystal Structure Determination
CCDC 2201029: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2088890: Experimental Crystal Structure Determination
CCDC 2088890: Experimental Crystal Structure Determination Open
View article: CCDC 1917354: Experimental Crystal Structure Determination
CCDC 1917354: Experimental Crystal Structure Determination Open
View article: CCDC 1846555: Experimental Crystal Structure Determination
CCDC 1846555: Experimental Crystal Structure Determination Open
View article: CCDC 1917355: Experimental Crystal Structure Determination
CCDC 1917355: Experimental Crystal Structure Determination Open
View article: CCDC 2109210: Experimental Crystal Structure Determination
CCDC 2109210: Experimental Crystal Structure Determination Open
View article: Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Pd(II)-MPAA Catalyzed C-H Arylation and Olefination
Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Pd(II)-MPAA Catalyzed C-H Arylation and Olefination Open
A direct Pd(II)-catalyzed kinetic resolution of heteroaryl-enabled sulfoximines through an ortho-C-H alkenylation/arylation of arenes has been developed for the first time. The coordination of sulfoximine pyridyl-motif and the chiral amino…
View article: Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Pd(II)-MPAA Catalyzed C-H Arylation and Olefination
Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Pd(II)-MPAA Catalyzed C-H Arylation and Olefination Open
A direct Pd(II)-catalyzed kinetic resolution of heteroaryl-enabled sulfoximines through an ortho-C-H alkenylation/arylation of arenes has been developed for the first time. The coordination of sulfoximine pyridyl-motif and the chiral amino…
View article: CCDC 2045977: Experimental Crystal Structure Determination
CCDC 2045977: Experimental Crystal Structure Determination Open
View article: CCDC 2045975: Experimental Crystal Structure Determination
CCDC 2045975: Experimental Crystal Structure Determination Open
View article: CCDC 2045976: Experimental Crystal Structure Determination
CCDC 2045976: Experimental Crystal Structure Determination Open
View article: Sulfur Versus Nitrogen Chelation in C-H Activation: Cobalt(III)-Catalyzed Unsymmetrical Double Annulation of Thioamides
Sulfur Versus Nitrogen Chelation in C-H Activation: Cobalt(III)-Catalyzed Unsymmetrical Double Annulation of Thioamides Open
An unconventional cobalt(III)-catalyzed one-pot domino double annulation of aryl thioamides with unactivated alkynes is presented. Sulfur (S), nitrogen (N), and o,o'-C-H bonds of aryl thioamides are involved in this reaction, enabling acce…
View article: Sulfur Versus Nitrogen Chelation in C-H Activation: Cobalt(III)-Catalyzed Unsymmetrical Double Annulation of Thioamides
Sulfur Versus Nitrogen Chelation in C-H Activation: Cobalt(III)-Catalyzed Unsymmetrical Double Annulation of Thioamides Open
An unconventional cobalt(III)-catalyzed one-pot domino double annulation of aryl thioamides with unactivated alkynes is presented. Sulfur (S), nitrogen (N), and o,o'-C-H bonds of aryl thioamides are involved in this reaction, enabling acce…
View article: Kinetic resolution of sulfur-stereogenic sulfoximines by Pd( <scp>ii</scp> )–MPAA catalyzed C–H arylation and olefination
Kinetic resolution of sulfur-stereogenic sulfoximines by Pd( <span>ii</span> )–MPAA catalyzed C–H arylation and olefination Open
A Pd/MPAA catalysed KR of heteroaryl substituted sulfoximines through C–H alkenylation and arylation (up to >99% ee) is developed. In-depth DFT studies uncover the salient features.
View article: Harnessing sulfur and nitrogen in the cobalt(<scp>iii</scp>)-catalyzed unsymmetrical double annulation of thioamides: probing the origin of chemo- and regio-selectivity
Harnessing sulfur and nitrogen in the cobalt(<span>iii</span>)-catalyzed unsymmetrical double annulation of thioamides: probing the origin of chemo- and regio-selectivity Open
A Co-catalyzed one-pot double annulation of sulfoximine bearing thioamides with alkynes for the synthesis of [6,6]-fused thiopyrano-isoquinolines is disclosed. The annulation involves a 6π-electrocyclization of 7-membered S-chelated cobalt…
View article: CCDC 1979335: Experimental Crystal Structure Determination
CCDC 1979335: Experimental Crystal Structure Determination Open
View article: CCDC 1979334: Experimental Crystal Structure Determination
CCDC 1979334: Experimental Crystal Structure Determination Open
View article: CCDC 1979336: Experimental Crystal Structure Determination
CCDC 1979336: Experimental Crystal Structure Determination Open