Malcolm L. H. Green
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View article: Agostic interactions in transition metal compounds
Agostic interactions in transition metal compounds Open
The impact of agostic interactions (i.e., 3-center–2-electron M H C bonds) on the structures and reactivity of organotransition metal compounds is reviewed.
View article: Complement activation and protein adsorption by carbon nanotubes
Complement activation and protein adsorption by carbon nanotubes Open
As a first step to validate the use of carbon nanotubes as novel vaccine or drug delivery devices, their interaction with a part of the human immune system, complement, has been explored. Haemolytic assays were conducted to investigate the…
View article: Hydrogen/deuterium exchange in alkyl-hydride derivatives of ansa-tungstenocene compounds
Hydrogen/deuterium exchange in alkyl-hydride derivatives of ansa-tungstenocene compounds Open
The higher n-alkyl hydrides [W{(η-C5H4)CMe2(η-C5H4)}(R)H](R = {(CH2)nCH3}, n = 1–4) and the isotopically labelled analogues [W(η-C5D4)C(CD3)2(η-C5D4)}(R)D], (R = {(CH2)nCH3} (n = 1–4) and [W{(η-C5H4)CMe2(η-C5H4)}{CD2CD3}H] have been prepar…
View article: Synthesis, structure and density functional study of the ansa-rhenocene complex [Re{(η-C5H4)CMe2(η-C5H4)}Cl] †
Synthesis, structure and density functional study of the ansa-rhenocene complex [Re{(η-C5H4)CMe2(η-C5H4)}Cl] † Open
The ansa-rhenocene compound [Re{(η-C5H4)CMe2(η-C5H4)}Cl] 1 has been prepared by reaction of ReCl5 with[K2(C5H4)CMe2(C5H4)]. X-Ray crystallography shows the molecular structure to be unsymmetrical, with the angle defined by the Re-bridgehea…