Munetaka Akita
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View article: Methane production via photocatalytic degradation of glucose on PtOx and PdOx-loaded TiO2
Methane production via photocatalytic degradation of glucose on PtOx and PdOx-loaded TiO2 Open
Sustainable production of CH 4 , an industrially important gas, from renewable resources presents a critical solution to energy security challenges. This study demonstrates photocatalytic conversion of glucose, a model biomass compound, to…
View article: Dawn of photoredox catalysis
Dawn of photoredox catalysis Open
Photoredox catalysis, which facilitates organic transformations under visible-light irradiation, including sunlight, has garnered considerable attention as a cornerstone of green chemistry. Since the early days of this field around 2010, t…
View article: Controlling Redox and Wirelike Charge-Delocalization Properties of Dinuclear Mixed-Valence Complexes with MCp*(dppe) (M = Fe, Ru) Termini Bridged by Metalloporphyrin Linkers
Controlling Redox and Wirelike Charge-Delocalization Properties of Dinuclear Mixed-Valence Complexes with MCp*(dppe) (M = Fe, Ru) Termini Bridged by Metalloporphyrin Linkers Open
Four dinuclear organometallic molecular wire complexes with diethynylmetalloporphyrin linkers 1 MM' , [5,15-bis{MCp*(dppe)ethynyl}-10,20-diarylporphinato]M' (Cp* = η5-C5Me5; dppe = 1,2-bis(diphenylphosphino)ethane; M/M' = Fe/Zn (1 FeZn ), …
View article: CCDC 2168521: Experimental Crystal Structure Determination
CCDC 2168521: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168519: Experimental Crystal Structure Determination
CCDC 2168519: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168516: Experimental Crystal Structure Determination
CCDC 2168516: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168517: Experimental Crystal Structure Determination
CCDC 2168517: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168520: Experimental Crystal Structure Determination
CCDC 2168520: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168518: Experimental Crystal Structure Determination
CCDC 2168518: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Molecule‐Electrode Interfaces Controlled by Bulky Long‐Legged Ligands in Organometallic Molecular Wires
Molecule‐Electrode Interfaces Controlled by Bulky Long‐Legged Ligands in Organometallic Molecular Wires Open
Precise control of molecule‐electrode interface is essential for molecular devices. Herein, new ruthenium acetylide molecular wires with long‐legged phosphine ligands to form a sterically controlled molecule‐electrode interface are designe…
View article: CCDC 2168677: Experimental Crystal Structure Determination
CCDC 2168677: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2103199: Experimental Crystal Structure Determination
CCDC 2103199: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2097141: Experimental Crystal Structure Determination
CCDC 2097141: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2194157: Experimental Crystal Structure Determination
CCDC 2194157: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Substrate-Rhodium cooperativity in photoinduced ortho-alkynylation of arenes
Substrate-Rhodium cooperativity in photoinduced ortho-alkynylation of arenes Open
In the realm of metallaphotocatalytic C-H activation strategy, the mode of reaction which has been mostly explored is the synergistic effect between a photocatalyst (PC) and a transition metal. In these cases, the energy and redox transfer…
View article: Acene Size‐Dependent Transition of The Radical Centers From the Metal to The Acene Parts In Monocationic Dinuclear (Diethynylacene)diyl Complexes
Acene Size‐Dependent Transition of The Radical Centers From the Metal to The Acene Parts In Monocationic Dinuclear (Diethynylacene)diyl Complexes Open
Controlling radical localization/delocalization is important for functional materials. The present paper describes synthesis and results of electrochemical, spectroscopic, and theoretical studies of diruthenium ( p ‐diethynylacene)diyl com…
View article: CCDC 1861281: Experimental Crystal Structure Determination
CCDC 1861281: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1861284: Experimental Crystal Structure Determination
CCDC 1861284: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1861282: Experimental Crystal Structure Determination
CCDC 1861282: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1861283: Experimental Crystal Structure Determination
CCDC 1861283: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1861286: Experimental Crystal Structure Determination
CCDC 1861286: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1861285: Experimental Crystal Structure Determination
CCDC 1861285: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Estimation of Electron Distribution over Dinuclear Organometallic Molecular Wires by “IR Tag” Analysis of Ancillary Acyl-Cp Ligands
Estimation of Electron Distribution over Dinuclear Organometallic Molecular Wires by “IR Tag” Analysis of Ancillary Acyl-Cp Ligands Open
Understanding the details of electronic properties of mixed-valence (MV) states of organometallic molecular wires is essential to gain insights into electron transfer phenomena. Although the field of MV chemistry is matured, there remain i…
View article: Modular Redox Switching of Dinuclear Organometallic Molecular Junctions
Modular Redox Switching of Dinuclear Organometallic Molecular Junctions Open
Molecular switch is one of the essential functional units of molecular electronics. Here, we report development of new molecular switches based on the electron-rich diruthenium complexes with the (2,5-di-R-substituted 1,4-diethynylbenzene)…
View article: Modular Redox Switching of Dinuclear Organometallic Molecular Junctions
Modular Redox Switching of Dinuclear Organometallic Molecular Junctions Open
Molecular switch is one of the essential functional units of molecular electronics. Here, we report development of new molecular switches based on the electron-rich diruthenium complexes with the (2,5-di-R-substituted 1,4-diethynylbenzene)…