Marcel Eilers
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View article: Fluctuating Behavior and Ligand-Dependent Reactivity of Isocyanates with Bis(pentafulvene)titanium Complexes
Fluctuating Behavior and Ligand-Dependent Reactivity of Isocyanates with Bis(pentafulvene)titanium Complexes Open
Reactions of bis(π-η5:σ-η1-pentafulvene)titanium complexes with isocyanates result in selective insertions of either one or two equivalents of RN═C═O into the two frustrated Ti-Cexo bonds under mild conditions. Depending on the pentafulven…
View article: Synthesis of Titanium ĸ<sup>1</sup><i>S</i>‐Thioamidato Complexes from Reactions of Bis(pentafulvene)complexes with Isothiocyanates
Synthesis of Titanium ĸ<sup>1</sup><i>S</i>‐Thioamidato Complexes from Reactions of Bis(pentafulvene)complexes with Isothiocyanates Open
As part of the activation of small molecules by transition metal complexes, reactions of bis(π‐η 5 :σ‐η 1 ‐pentafulvene)titanium complexes with various isothiocyanates are performed. Despite the presence of two double bonds, only the CS b…
View article: Synthesis, characterization and functionalization of titanium κ <sup>1</sup> <i>N</i> amidinato complexes from carbodiimides
Synthesis, characterization and functionalization of titanium κ <sup>1</sup> <i>N</i> amidinato complexes from carbodiimides Open
A series of titanium amidinato complexes were synthesized by stoichiometric insertion reactions of carbodiimides into bis(π–η 5 :σ–η 1 -pentafulvene)titanium complexes.
View article: Syntheses and Characterization of Ti(III)/Ti(IV) Triazenido Complexes
Syntheses and Characterization of Ti(III)/Ti(IV) Triazenido Complexes Open
The syntheses of side‐on Ti(III) triazenido complexes via the ethylene complexes Cp*Ti(η 2 ‐C 2 H 4 )(η 5 ‐C 5 H 4 CR 2 H) and side‐on Ti(IV) triazenido complexes via bis(π‐η 5 : σ‐η 1 ‐pentafulvene) titanium complexes are reported. The de…
View article: CCDC 2299399: Experimental Crystal Structure Determination
CCDC 2299399: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2184362: Experimental Crystal Structure Determination
CCDC 2184362: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2184359: Experimental Crystal Structure Determination
CCDC 2184359: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2184363: Experimental Crystal Structure Determination
CCDC 2184363: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2184361: Experimental Crystal Structure Determination
CCDC 2184361: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2184358: Experimental Crystal Structure Determination
CCDC 2184358: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2184360: Experimental Crystal Structure Determination
CCDC 2184360: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2220414: Experimental Crystal Structure Determination
CCDC 2220414: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2220413: Experimental Crystal Structure Determination
CCDC 2220413: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Niobium Bis‐ and Mono(Pentafulvene) Complexes: E−H Bond Cleavage and Insertion Reactions (E=C, N, O)
Niobium Bis‐ and Mono(Pentafulvene) Complexes: E−H Bond Cleavage and Insertion Reactions (E=C, N, O) Open
Bis( η 5 : η 1 ‐(di‐ para ‐tolyl)pentafulvene)niobium chloride ( 1 ) reacts with methyl lithium via salt metathesis to the methylated bis(pentafulvene)niobium complex 2 , and with lithium 2,6‐diisopropylanilide addition and subsequent N−H …