Yizhak Marcus
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View article: Some Advances in Supercritical Fluid Extraction for Fuels, Bio-Materials and Purification
Some Advances in Supercritical Fluid Extraction for Fuels, Bio-Materials and Purification Open
Supercritical fluids are used for the extraction of desired ingredients from natural materials, but also for the removal of undesired and harmful ingredients. In this paper, the pertinent physical and chemical properties of supercritical w…
View article: The Entropy of Deep Eutectic Solvent Formation
The Entropy of Deep Eutectic Solvent Formation Open
The standard entropies S298°E of deep eutectic solvents (DESs), which are liquid binary mixtures of a hydrogen bond acceptor component and a hydrogen bod donor one, are calculated from their molecular volumes, derived from their densities …
View article: Extraction by Subcritical and Supercritical Water, Methanol, Ethanol and Their Mixtures
Extraction by Subcritical and Supercritical Water, Methanol, Ethanol and Their Mixtures Open
Hot, subcritical and supercritical water, methanol, ethanol and their binary mixtures have been employed to treat fuels (desulfurize coal and recover liquid fuels from coal and oil shales) and to extract valuable solutes from biomass. The …
View article: Estimation of the Critical Temperatures of Some More Deep Eutectic Solvents from Their Surface Tensions
Estimation of the Critical Temperatures of Some More Deep Eutectic Solvents from Their Surface Tensions Open
The critical temperatures of two dozen deep eutectic solvents, for only some of which these have been estimated previously, were estimated from the temperature dependences of their surface tensions and densities available in the literature…
View article: Effects of Solvent Properties on the Anion Binding of Neutral Water-Soluble Bis(cyclopeptides) in Water and Aqueous Solvent Mixtures
Effects of Solvent Properties on the Anion Binding of Neutral Water-Soluble Bis(cyclopeptides) in Water and Aqueous Solvent Mixtures Open
In this study, the anion-binding bis(cyclopeptide) 2 is introduced, which dissolves freely in water, affording up to 10 mM concentrations, thanks to triethylene glycol-derived substituents in the cyclopeptide subunits and the linker connec…
View article: Preferential Solvation of Drugs in Binary Solvent Mixtures
Preferential Solvation of Drugs in Binary Solvent Mixtures Open
The preferential solvation of many drugs in binary solvent mixtures, as derived by means of the quasi-lattice quasi-chemical and the inverse Kirkwood-Buff integrals methods from solubility and other thermodynamic data, is reviewed.The pref…