Marcus W. Drover
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View article: C(sp <sup>2</sup> )─H Bond Activation with a Heterometallic Nickel–Aluminium Complex
C(sp <sup>2</sup> )─H Bond Activation with a Heterometallic Nickel–Aluminium Complex Open
Herein we present a ligand‐catalyzed bond‐breaking and making process that occurs with a Ni–Al heterometallic complex. While combinations of Ni pre‐catalysts and Al additives are known for site‐selective C─H functionalization, detailed stu…
View article: C(sp <sup>2</sup> )─H Bond Activation with a Heterometallic Nickel–Aluminium Complex
C(sp <sup>2</sup> )─H Bond Activation with a Heterometallic Nickel–Aluminium Complex Open
Herein we present a ligand‐catalyzed bond‐breaking and making process that occurs with a Ni–Al heterometallic complex. While combinations of Ni pre‐catalysts and Al additives are known for site‐selective C─H functionalization, detailed stu…
View article: Phosphine-Catalyzed C(sp2)–H Bond Activation with a Heterometallic Nickel---Aluminum Complex
Phosphine-Catalyzed C(sp2)–H Bond Activation with a Heterometallic Nickel---Aluminum Complex Open
Herein we present the discovery of a ligand-catalyzed bond breaking and making processes that occurs in the coordination sphere of a novel Ni–Al heterometallic complex. While combinations of Ni pre-catalysts and Al additives are known for …
View article: Frontispiz: CO<sub>2</sub> Reduction at a Borane‐Modified Iron Complex: A Secondary Coordination Sphere Strategy
Frontispiz: CO<sub>2</sub> Reduction at a Borane‐Modified Iron Complex: A Secondary Coordination Sphere Strategy Open
View article: Frontispiece: CO<sub>2</sub> Reduction at a Borane‐Modified Iron Complex: A Secondary Coordination Sphere Strategy
Frontispiece: CO<sub>2</sub> Reduction at a Borane‐Modified Iron Complex: A Secondary Coordination Sphere Strategy Open
View article: Hydro- and chloroelementation reactions across an iron–carbon bond using heavy group 15 reagents
Hydro- and chloroelementation reactions across an iron–carbon bond using heavy group 15 reagents Open
We report the first examples of Sb–H bond additions across a metal–carbon bond, giving heterometallic Sb–Fe complexes.
View article: Applied Organometallic Chemistry: From Foundational to Translational
Applied Organometallic Chemistry: From Foundational to Translational Open
View article: The selective and sensitive fluorogenic detection of hydrogen gas using a transition metal activator and a naphthalene-based dye
The selective and sensitive fluorogenic detection of hydrogen gas using a transition metal activator and a naphthalene-based dye Open
Hydrogen (H2(g)) is a viable green fossil fuel alternative as its combustion yields only water and energy. However, H2(g) is highly flammable, explosive, and lacks odor. These characteristics warrant sensitive and spe…
View article: A tetraanionic diphosphine borate ligand: Complexation with platinum
A tetraanionic diphosphine borate ligand: Complexation with platinum Open
Charge is a property that is inherent to most chemical phenomena. In coordination chemistry, charge can be conferred through targeted ligand design. Notwithstanding, examples of ligands containing greater than a single pendant point charge…
View article: A Blueprint for Secondary Coordination Sphere Editing: Approaches Toward Lewis‐Acid Assisted Carbon Dioxide Co‐Activation
A Blueprint for Secondary Coordination Sphere Editing: Approaches Toward Lewis‐Acid Assisted Carbon Dioxide Co‐Activation Open
Carbon dioxide (CO 2 ) is a potent greenhouse gas of environmental concern. Seeking to offer a solution to the “CO 2 ‐problem”, the chemistry community has turned a focus toward transition metal complexes which can activate, reduce, and co…
View article: CCDC 2300765: Experimental Crystal Structure Determination
CCDC 2300765: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2300763: Experimental Crystal Structure Determination
CCDC 2300763: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2300764: Experimental Crystal Structure Determination
CCDC 2300764: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Oxidatively-induced C(sp<sup>3</sup>)–C(sp<sup>3</sup>) bond formation at a tucked-in iron(<scp>iii</scp>) complex
Oxidatively-induced C(sp<sup>3</sup>)–C(sp<sup>3</sup>) bond formation at a tucked-in iron(<span>iii</span>) complex Open
Carbon–carbon (C–C) bond formation is a cornerstone of synthetic chemistry, relying on routes such as transition-metal mediated cross-coupling for the introduction of new carbon-based functionality.
View article: CCDC 2287573: Experimental Crystal Structure Determination
CCDC 2287573: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: An Investigation of Allyl‐Substituted Bis(Diphosphine) Iron Complexes: Towards Precursors for Cooperative CO<sub>2</sub> Activation
An Investigation of Allyl‐Substituted Bis(Diphosphine) Iron Complexes: Towards Precursors for Cooperative CO<sub>2</sub> Activation Open
In developing homogenous catalysts capable of CO 2 activation, interaction with a metal center is often imperative. This work provides primary efforts towards the cooperative activation of CO 2 using a Lewis acidic secondary coordination s…
View article: CCDC 2266746: Experimental Crystal Structure Determination
CCDC 2266746: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2266749: Experimental Crystal Structure Determination
CCDC 2266749: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2266747: Experimental Crystal Structure Determination
CCDC 2266747: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2266748: Experimental Crystal Structure Determination
CCDC 2266748: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Base metal chemistry and catalysis
Base metal chemistry and catalysis Open
This perspective provides an entry-level conversation concerning base metal catalysis as a green and sustainable solution in industrial and academic contexts. We establish a definition of “base metal,” challenging readers to consider the e…
View article: CCDC 2251021: Experimental Crystal Structure Determination
CCDC 2251021: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2245380: Experimental Crystal Structure Determination
CCDC 2245380: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2245379: Experimental Crystal Structure Determination
CCDC 2245379: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2245381: Experimental Crystal Structure Determination
CCDC 2245381: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Nickel Complexes of Allyl and Vinyldiphenylphosphine
Nickel Complexes of Allyl and Vinyldiphenylphosphine Open
Monodentate phosphine-ligated nickel compounds, e.g., [Ni(PPh3)4] are relevant as active catalysts across a broad range of reactions. This report expands upon the coordination chemistry of this family, offering the reactivity of allyl- and…
View article: CCDC 2239599: Experimental Crystal Structure Determination
CCDC 2239599: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2239601: Experimental Crystal Structure Determination
CCDC 2239601: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2239602: Experimental Crystal Structure Determination
CCDC 2239602: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2239600: Experimental Crystal Structure Determination
CCDC 2239600: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …