Marharyta Kosiuha
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View article: From <i>gem</i>‐Dichlorocyclobutenones to Cyclobutenols: Unveiling a Ruthenium‐Catalyzed Allylic Reduction‐Asymmetric Transfer Hydrogenation Cascade
From <i>gem</i>‐Dichlorocyclobutenones to Cyclobutenols: Unveiling a Ruthenium‐Catalyzed Allylic Reduction‐Asymmetric Transfer Hydrogenation Cascade Open
Cyclobutenones constitute an appealing class of substrates in catalytic asymmetric transformations leading to diversely substituted enantioenriched four‐membered carbocycles, which are eliciting a growing interest in medicinal chemistry. W…
View article: Asymmetric Transfer Hydrogenation of <i>gem</i>-Difluorocyclopropenyl Ketones: The Synthesis and Functionalization of Enantioenriched <i>cis gem</i>-Difluorocyclopropyl Ketones
Asymmetric Transfer Hydrogenation of <i>gem</i>-Difluorocyclopropenyl Ketones: The Synthesis and Functionalization of Enantioenriched <i>cis gem</i>-Difluorocyclopropyl Ketones Open
The asymmetric transfer hydrogenation of gem-difluorocyclopropenyl ketones, catalyzed by a Noyori-Ikariya ruthenium complex, was developed to access substituted optically enriched cis-disubstituted gem-difluorocyclopro…