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View article: Pd(0)/Pd(II) Electromerism Triggered by Lewis Base Coordination to a Redox‐Active Silicon Z‐Type Ligand
Pd(0)/Pd(II) Electromerism Triggered by Lewis Base Coordination to a Redox‐Active Silicon Z‐Type Ligand Open
Electromerism (aka. valence tautomerism) corresponds to the switching of electronic distributions between redox‐active ligands and central elements. While this phenomenon is well established for several transition metals, the Pd(0)/Pd(II) …
View article: Non‐Heme‐Iron‐Mediated Selective Halogenation of Unactivated Carbon−Hydrogen Bonds
Non‐Heme‐Iron‐Mediated Selective Halogenation of Unactivated Carbon−Hydrogen Bonds Open
Oxidation of the iron(II) precursor [(L 1 )Fe II Cl 2 ], where L 1 is a tetradentate bispidine, with soluble iodosylbenzene ( s PhIO) leads to the extremely reactive ferryl oxidant [(L 1 )(Cl)Fe IV =O] + with a cis disposition of the chlor…
View article: Pathways of the Extremely Reactive Iron(IV)‐oxido complexes with Tetradentate Bispidine Ligands
Pathways of the Extremely Reactive Iron(IV)‐oxido complexes with Tetradentate Bispidine Ligands Open
The nonheme iron(IV)‐oxido complex trans‐ N3‐[(L 1 )Fe IV =O(Cl)] + , where L 1 is a derivative of the tetradentate bispidine 2,4‐di(pyridine‐2‐yl)‐3,7‐diazabicyclo[3.3.1]nonane‐1‐one, is known to have an S =1 electronic ground state and t…
View article: A Metal‐Free Direct Arene C−H Amination
A Metal‐Free Direct Arene C−H Amination Open
The synthesis of aryl amines via the formation of a C−N bond is an essential tool for the preparation of functional materials, active pharmaceutical ingredients and bioactive products. Usually, this chemical connection is only possible by …
View article: Excitation of aryl cations as the key to catalyst-free radical arylations
Excitation of aryl cations as the key to catalyst-free radical arylations Open
While Sandmeyer-type brominations/iodinations and Meerwein-type arylations are useful methodologies, they are not without their drawbacks. Here, we report an alternative catalyst- and additive-free access to Sandmeyer-type brominations/iod…
View article: CCDC 1846004: Experimental Crystal Structure Determination
CCDC 1846004: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1846005: Experimental Crystal Structure Determination
CCDC 1846005: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1846006: Experimental Crystal Structure Determination
CCDC 1846006: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1846001: Experimental Crystal Structure Determination
CCDC 1846001: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1846000: Experimental Crystal Structure Determination
CCDC 1846000: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1846003: Experimental Crystal Structure Determination
CCDC 1846003: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1846002: Experimental Crystal Structure Determination
CCDC 1846002: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1522559: Experimental Crystal Structure Determination
CCDC 1522559: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1814766: Experimental Crystal Structure Determination
CCDC 1814766: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1457024: Experimental Crystal Structure Determination
CCDC 1457024: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1457022: Experimental Crystal Structure Determination
CCDC 1457022: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1457023: Experimental Crystal Structure Determination
CCDC 1457023: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …