Mariya Shamzhy
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View article: Stoichiometric Selective Carbonylation of Methane to Acetic Acid by Chemical Looping
Stoichiometric Selective Carbonylation of Methane to Acetic Acid by Chemical Looping Open
The conversion of methane to valuable products is one of the main challenges of modern chemistry. Acetic acid (AcOH) is a key chemical reagent in industry, produced nowadays by the carbonylation of methanol over homogeneous Rh and Ir catal…
View article: Lewis acid zeolite catalysts via chemical modification of extra-large pore germanosilicates
Lewis acid zeolite catalysts via chemical modification of extra-large pore germanosilicates Open
Lewis acid zeolites containing tetravalent metals, such as Sn or Zr, are of great interest as catalysts for variousreactions owing to their tunability, activity, and reusability. In the context of emerging trends in biomass-relatedsubstrat…
View article: Isomerization of dihydroxybenzenes over metal-zeolite catalysts through the carbonaceous deposits
Isomerization of dihydroxybenzenes over metal-zeolite catalysts through the carbonaceous deposits Open
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View article: Controlling Crystal Morphology of Anisotropic Zeolites with Elemental Composition
Controlling Crystal Morphology of Anisotropic Zeolites with Elemental Composition Open
The morphology of zeolite crystals strongly affects their textural, catalytic, and mechanical attributes. However, controlling zeolite crystal morphology without using modifiers or structure-directing agents remains a challenging task beca…
View article: Balancing Ge de-intercalation and Si re-insertion rates stabilizes hydrolytically labile germanosilicate zeolites
Balancing Ge de-intercalation and Si re-insertion rates stabilizes hydrolytically labile germanosilicate zeolites Open
Balanced deintercalation and reinsertion of framework atoms was used to stabilize water-sensitive germanosilicate zeolites. They become resistant to structural degradation and thus available for modification and use.
View article: Correlating mesoporosity/acidity with catalytic performances for surfactant-templated mesoporous FAU zeolites
Correlating mesoporosity/acidity with catalytic performances for surfactant-templated mesoporous FAU zeolites Open
A surfactant-templated synthesis results in hierarchical zeolites with controllable micropore-to-mesopore volume ratio. However, the relationships between the synthesis conditions, acidity and catalytic performance of thus prepared zeolite…
View article: ADOR zeolite with 12 × 8 × 8-ring pores derived from IWR germanosilicate
ADOR zeolite with 12 × 8 × 8-ring pores derived from IWR germanosilicate Open
Addressing the synthesis–property relations in the Assembly step of ADOR enabled to design previously unknown IPC-17 zeolite by optimization of the chemical composition and crystallite dimensions in the parent IWR germanosilicate.
View article: Strong CO2 adsorption in narrow-pore ADOR zeolites: A combined experimental and computational study on IPC-12 and related structures
Strong CO2 adsorption in narrow-pore ADOR zeolites: A combined experimental and computational study on IPC-12 and related structures Open
The ADOR method of synthesizing new zeolites has yielded a range of innovative siliceous materials featuring narrow pores, which facilitate relatively strong CO2 binding. This combined experimental and computational study investigates the …
View article: Recent Achievements in Designing Zeolite Catalysts
Recent Achievements in Designing Zeolite Catalysts Open
Zeolites are porous crystalline solid acid catalysts that are widely used in the petrochemical industry and have high potential for new catalytic applications. This paper provides an overview on recent progress in the design of zeolite cat…
View article: CSD 2237163: Experimental Crystal Structure Determination
CSD 2237163: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2203343: Experimental Crystal Structure Determination
CSD 2203343: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Catching a New Zeolite as a Transition Material during Deconstruction
Catching a New Zeolite as a Transition Material during Deconstruction Open
Zeolites are key materials in both basic research and industrial applications. However, their synthesis is neither diverse nor applicable to labile frameworks because classical procedures require harsh hydrothermal conditions, whereas post…
View article: MWW and MFI Frameworks as Model Layered Zeolites: Structures, Transformations, Properties, and Activity
MWW and MFI Frameworks as Model Layered Zeolites: Structures, Transformations, Properties, and Activity Open
Porous solids containing internal pores with sizes ranging from angstroms to nanometers are highly useful and valuable in the catalysis, separation, and storage of molecules because these materials provide large surface areas and void spac…
View article: Basolites: A type of Metal Organic Frameworks highly efficient in the one-pot synthesis of quinoxalines from α-hydroxy ketones under aerobic conditions
Basolites: A type of Metal Organic Frameworks highly efficient in the one-pot synthesis of quinoxalines from α-hydroxy ketones under aerobic conditions Open
We report here efficient synthesis of quinoxalines from ophenylendiamine
\nand -hydroxy ketones over commercial Basolites.
\nThe concentration and type of acid centres, as CUS sites, together
\nwith the porosity of the samples strongly in…
View article: The crucial role of clay binders in the performance of ZSM-5 based materials for biomass catalytic pyrolysis
The crucial role of clay binders in the performance of ZSM-5 based materials for biomass catalytic pyrolysis Open
The effect of agglomerating ZrO2/n-ZSM-5 catalyst with different clays on biomass catalytic pyrolysis is evaluated.
View article: MoO<sub>3</sub> on zeolites MCM-22, MCM-56 and 2D-MFI as catalysts for 1-octene metathesis
MoO<sub>3</sub> on zeolites MCM-22, MCM-56 and 2D-MFI as catalysts for 1-octene metathesis Open
Highly active olefin metathesis catalysts were prepared by thermal spreading MoO 3 and/or MoO 2 (acac) 2 on MWW zeolites (MCM-22, delaminated MCM-56) and on two-dimensional MFI (all in NH 4 + form). The catalysts‘ activities were tested in…
View article: Expansion of the ADOR Strategy for the Synthesis of Zeolites: The Synthesis of IPC‐12 from Zeolite UOV
Expansion of the ADOR Strategy for the Synthesis of Zeolites: The Synthesis of IPC‐12 from Zeolite UOV Open
The assembly–disassembly–organization–reassembly (ADOR) process has been used to disassemble a parent zeolite with the UOV structure type and then reassemble the resulting layers into a novel structure, IPC‐12. The structure of the materia…
View article: Expansion of the ADOR Strategy for the Synthesis of Zeolites: The Synthesis of IPC‐12 from Zeolite UOV
Expansion of the ADOR Strategy for the Synthesis of Zeolites: The Synthesis of IPC‐12 from Zeolite UOV Open
The assembly–disassembly–organization–reassembly (ADOR) process has been used to disassemble a parent zeolite with the UOV structure type and then reassemble the resulting layers into a novel structure, IPC‐12. The structure of the materia…
View article: Zeolite-derived hybrid materials with adjustable organic pillars
Zeolite-derived hybrid materials with adjustable organic pillars Open
Porous organic–inorganic materials with tunable textural characteristics were synthesized using the top-down process by intercalating silsesquioxanes and polyhedral oligomeric siloxanes of different types between crystalline zeolite-derive…