Mark S’ari
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View article: Washcoat Nanoparticle-Driven Microcrack Enlargement in a Coated Catalyst
Washcoat Nanoparticle-Driven Microcrack Enlargement in a Coated Catalyst Open
Nanoparticles are avoided in coating particulate filters made from microcracked ceramics like aluminum titanate (AT) to prevent thermal stress damage during manufacturing despite limited understanding of the process. This study, first in t…
View article: Large On–Off Enhancement of Au Nanocatalyst Contacts to ZnO Nanowires with Bulk and Surface Oxygen Modification
Large On–Off Enhancement of Au Nanocatalyst Contacts to ZnO Nanowires with Bulk and Surface Oxygen Modification Open
Schottky diodes have been a fundamental component of electrical circuits for many decades, and intense research continues to this day on planar materials with increasingly exotic compounds. With the birth of nanotechnology, a paradigm shif…
View article: Exploiting Organometallic Chemistry to Functionalize Small Cuprous Oxide Colloidal Nanocrystals
Exploiting Organometallic Chemistry to Functionalize Small Cuprous Oxide Colloidal Nanocrystals Open
The ligand chemistry of colloidal semiconductor nanocrystals mediates their solubility, band gap, and surface facets. Here, selective organometallic chemistry is used to prepare small, colloidal cuprous oxide nanocrystals and to control th…
View article: Lithiated porous silicon nanowires stimulate periodontal regeneration
Lithiated porous silicon nanowires stimulate periodontal regeneration Open
View article: Lithiated porous silicon nanowires stimulate periodontal regeneration
Lithiated porous silicon nanowires stimulate periodontal regeneration Open
Periodontal disease is a significant burden for oral health, causing progressive and irreversible damage to the support structure of the tooth. This complex structure, the periodontium, is composed of interconnected soft and mineralised ti…
View article: Palladium-doped hierarchical ZSM-5 for catalytic selective oxidation of allylic and benzylic alcohols
Palladium-doped hierarchical ZSM-5 for catalytic selective oxidation of allylic and benzylic alcohols Open
Hierarchical zeolites have the potential to provide a breakthrough in transport limitation, which hinders pristine microporous zeolites and thus may broaden their range of applications. We have explored the use of Pd-doped hierarchical ZSM…
View article: Characterization of Amorphous Solid Dispersions and Identification of Low Levels of Crystallinity by Transmission Electron Microscopy
Characterization of Amorphous Solid Dispersions and Identification of Low Levels of Crystallinity by Transmission Electron Microscopy Open
Amorphous solid dispersions (ASDs) are used to increase the solubility of oral medicines by kinetically stabilizing the more soluble amorphous phase of an active pharmaceutical ingredient with a suitable amorphous polymer. Low levels of a …
View article: (Hydroxy)apatite on cement: insights into a new surface treatment
(Hydroxy)apatite on cement: insights into a new surface treatment Open
We have developed a conceptual model describing the formation and mineralisation processes of hydroxyapatite during biogenic and abiotic treatment on cement surfaces.
View article: Analysis of complex, beam-sensitive materials by transmission electron microscopy and associated techniques
Analysis of complex, beam-sensitive materials by transmission electron microscopy and associated techniques Open
We review the use of transmission electron microscopy (TEM) and associated techniques for the analysis of beam-sensitive materials and complex, multiphase systems in-situ or close to their native state. We focus on materials prone to damag…
View article: Direct Visualization of Arsenic Binding on Green Rust Sulfate
Direct Visualization of Arsenic Binding on Green Rust Sulfate Open
"Green rust" (GR), a redox-active Fe(II)-Fe(III) layered double hydroxide, is a potential environmentally relevant mineral substrate for arsenic (As) sequestration in reduced, subsurface environments. GR phases have high As uptake capaciti…
View article: High‐resolution imaging of organic pharmaceutical crystals by transmission electron microscopy and scanning moiré fringes
High‐resolution imaging of organic pharmaceutical crystals by transmission electron microscopy and scanning moiré fringes Open
Summary Formulation processing of organic crystalline compounds can have a significant effect on drug properties, such as dissolution rate or tablet strength/hardness. Transmission electron microscopy (TEM) has the potential to resolve the…
View article: Multi-linear Regression Model to Predict the Electron Stability of Poorly Soluble Active Pharmaceutical Ingredients
Multi-linear Regression Model to Predict the Electron Stability of Poorly Soluble Active Pharmaceutical Ingredients Open
Journal Article Multi-linear Regression Model to Predict the Electron Stability of Poorly Soluble Active Pharmaceutical Ingredients Get access Mark S’ari, Mark S’ari University of Leeds, School of Chemical and Process Engineering, Leeds, U…
View article: Transmission Electron Microscopy of a Poorly Soluble Drug, Felodipine
Transmission Electron Microscopy of a Poorly Soluble Drug, Felodipine Open
Many drugs that are currently in development exhibit poor dissolution properties due to low solubility. To increase the solubility of these drugs different technologies have been developed including solid dispersions, nano‐crystals and lip…
View article: Analysis of Electron Beam Damage of Crystalline Pharmaceutical Materials by Transmission Electron Microscopy
Analysis of Electron Beam Damage of Crystalline Pharmaceutical Materials by Transmission Electron Microscopy Open
We have studied the impact of transmission electron microscopy (TEM) and low dose electron diffraction on ten different crystalline pharmaceutical compounds, covering a diverse chemical space and with differing physical properties. The aim…
View article: Transmission electron microscopy of a model crystalline organic, theophylline
Transmission electron microscopy of a model crystalline organic, theophylline Open
We report on the use of transmission electron microscopy (TEM) to analyse the diffraction patterns of the model crystalline organic theophylline to investigate beam damage in relation to changing accelerating voltage, sample temperature an…
View article: Prospects for High Resolution Analytical Electron Microscopy of Organic Crystalline Particles
Prospects for High Resolution Analytical Electron Microscopy of Organic Crystalline Particles Open
Journal Article Prospects for High Resolution Analytical Electron Microscopy of Organic Crystalline Particles Get access James Cattle, James Cattle Institute for Materials Research, School of Chemical and Process Engineering, University of…